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Oxovanadium(IV) 2-ethylhexanoate was established as a new primary drier for alkyd-based paints. A series of experiments has demonstrated an excellent drying activity toward solvent-borne alkyd resins of different oil length at considerably lower metal concentration than optimal for commercial cobalt(II) 2-ethylhexanoate. The behavior in real paint was simulated on formulations bearing inhibitor of autooxidation. The detailed studies of the drying process have shown that the relatively slow initial step of autooxidation reaction, when compared with cobalt compounds, is compensated for by the absence of the induction times. Furthermore, the active oxovanadium(IV) species are not consumed during the drying processes as evidenced by EPR spectroscopic measurements. [ABSTRACT FROM AUTHOR]

Oxovanadium(IV) compounds, [VO( O , O -R 1 COCHCOR 2 ) 2 ] (R 1 = R 2 = Me; R 1 = Me, R 2 = Ph; R 1 = R 2 = Ph), were established as a new class of environmentally friendly primary driers for solvent-borne alkyd binder. The performed experiments clearly show that the catalytic activity of oxovanadium compounds is, in some terms, considerably higher than observed for commercial cobalt-based drier ( Co-Nuodex ). The detailed study of the drying process reveals several differences in mechanism of autoxidation. The enhanced activity at low concentrations together with very low overall toxicity imply the oxovanadium compounds as promising catalysts of autoxidation reactions implying a great perspective in paint-producing industry. [ABSTRACT FROM AUTHOR]

High solid (HS) alkyd resins with low amount of volatile organic compounds (VOC) were developed as the result of new VOC solvent directive that limit the amount of VOC in decorative paints. Due to specific chemical structure of HS alkyd resins and possible deterioration of some applicative properties the optimal combination of driers is an important subject of research. In our present work we studied the influence of Fe bispidon (Fe drier) and Co ethylhexanoate (Co drier) surface driers with Sr carboxylate (Sr drier) through drier on the film formation of HS alkyd coatings. The kinetics of autoxidation was analysed using FT-IR spectroscopy. Further, applicative properties like drying time and film hardness were examined. In the end, electrochemical impedance spectroscopy (EIS) was used to evaluate the quality of cured HS alkyd coating films after exposure in the humidity chamber. It was established that the addition of the Sr drier to surface driers accelerates the autoxidation process. As higher amounts of the Sr drier were added, final drying times were reduced and film hardness increased. The lowest diffusivity of ions through cured HS alkyd coating films was observed for Co/Sr and Fe/Sr drier combination at 1:1 concentration ratio. [ABSTRACT FROM AUTHOR]

Highlights: [•] Molybdenum-based catalyst was used as alkyd drier. [•] Drying activity was established. [•] Mechanism of drying process was studied by infrared spectroscopy. [ABSTRACT FROM AUTHOR]

Abstract: Metallocene complexes are for their properties very closely examined in recent years. These complexes, which are used for coatings drying, were not examined from industrial point of view, nor were they examined from research point of view. Both ferrocene and its methyl derivatives were synthesized and consequently observed with FTIR spectroscopy. The influence of methyl groups on ferrocene on the process of drying of ethyl linoleate used as a model system is the issue of this paper. [Copyright &y& Elsevier]