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We present a systematic study of mid-infrared spectra of galaxies including star-forming galaxies and active galactic nuclei observed with JWST MIRI-MRS and NIRSpec-IFU. We focus on the relative variations of the 3.3, 6.2, 7.7, 11.3, 12.7, and 17 |$\mu$| m polycyclic aromatic hydrocarbon (PAH) features within spatially resolved regions of galaxies including NGC 3256, NGC 7469, VV 114, II Zw96, and NGC 5728. Using theoretical PAH models and extending our earlier work, we introduce a new PAH diagnostic involving the 17 |$\mu$| m PAH feature. To determine the drivers of PAH band variations in galaxies, we compare observed PAH spectral bands to predictions from theoretical PAH models. We consider extinction, dehydrogenation, and PAH size and charge as possible drivers of PAH band variations. We find a surprising uniformity in PAH size distribution among the spatially resolved regions of the galaxies studied here, with no evidence for preferential destruction of the smallest grains, contrary to earlier findings. Neither extinction nor dehydrogenation play a crucial role in setting the observed PAH bands. Instead, we find that PAH charge plays a significant role in PAH inter-band variations. We find a tight relation between PAH charge and the intensity of the radiation field as traced by the [Ne  iii ] |$/$| [Ne  ii ] maps. In agreement with recent JWST results, we find a predominance of neutral PAH molecules in the nuclei of active galaxies and their outflows. Ionized PAHs are the dominant population in star-forming galaxies. We discuss the implications of our findings for the use of PAHs as ISM tracers in high redshift galaxies. [ABSTRACT FROM AUTHOR]

We present new calculations of the Clumpy AGN Tori in a 3D geometry (CAT3D) clumpy torus models, which now include a more physical dust sublimation model as well as active galactic nucleus (AGN) anisotropic emission. These new models allow graphite grains to persist at temperatures higher than the silicate dust sublimation temperature. This produces stronger near-infrared emission and bluer mid-infrared (MIR) spectral slopes. We make a statistical comparison of the CAT3D model MIR predictions with a compilation of subarcsecond resolution ground-based MIR spectroscopy of 52 nearby Seyfert galaxies (median distance of 36 Mpc) and 10 quasars. We focus on the AGN MIR spectral index αMIR and the strength of the 9.7 μm silicate feature SSil. As with other clumpy torus models, the new CAT3Dmodels do not reproduce the Seyfert galaxies with deep silicate absorption (SSil <−1). Excluding those, we conclude that the new CAT3D models are in better agreement with the observed αMIR and SSil of Seyfert galaxies and quasars. We find that Seyfert 2 are reproduced with models with low photon escape probabilities, while the quasars and the Seyfert 1-1.5 require generally models with higher photon escape probabilities. Quasars and Seyfert 1-1.5 tend to show steeper radial cloud distributions and fewer clouds along an equatorial line of sight than Seyfert 2. Introducing AGN anisotropic emission besides the more physical dust sublimation models alleviates the problem of requiring inverted radial cloud distributions (i.e. more clouds towards the outer parts of the torus) to explain the MIR spectral indices of type 2 Seyferts. [ABSTRACT FROM AUTHOR]

We present high-angular (0.17-0.35 arcsec) resolution imaging polarimetric observations of Mrk 231 in the 3.1 µm filter using MMT-Pol on the 6.5-m MMT, and in the 8.7, 10.3, and 11.6 μm filters using CanariCam on the 10.4-m Gran Telescopio CANARIAS. In combination with already published observations, we compile the 1-12 μm total and polarized nuclear spectral energy distribution (SED). The total flux SED in the central 400 pc is explained as the combination of (1) a hot (731 ± 4 K) dusty structure, directly irradiated by the central engine, which is at 1.6 ± 0.1 pc away and attributed to be in the pc-scale polar region, (2) an optically-thick, smooth and disc-like dusty structure ('torus') with an inclination of 48° ± 23° surrounding the central engine, and (3) an extinguished (AV = 36 ± 5 mag) starburst component. The polarized SED decreases from 0.77 ± 0.14 per cent at 1.2 μm to 0.31 ± 0.15 per cent at 11.6 μm and follows a power-law function, λ ~0.57. The polarization angle remains constant (~108°) in the 1-12 μm wavelength range. The dominant polarization mechanism is explained as scattering-off hot dust grains in the pc-scale polar regions. [ABSTRACT FROM AUTHOR]

We investigate the evolutionary connection between local IR-bright galaxies (log LIR ≥ 11.4 L⊙) and quasars. We use high angular resolution (∼ 0.3-0.4 arcsec∼ few hundred parsecs) 8 − 13 μm ground-based spectroscopy to disentangle the AGN mid-IR properties from those of star formation. The comparison between the nuclear 11.3 μm PAH feature emission and that measured with Spitzer/IRS indicates that the star formation is extended over a few kpc in the IR-bright galaxies. The AGN contribution to the total IR luminosity of IR-bright galaxies is lower than in quasars. Although the dust distribution is predicted to change as IR-bright galaxies evolve to IR-bright quasars and then to optical quasars, we show that the AGN mid-IR emission of all the quasars in our sample is not significantly different. In contrast, the nuclear emission of IR-bright galaxies with low AGN contributions appears more heavily embedded in dust although there is no clear trend with the interaction stage or projected nuclear separation. This suggests that the changes in the distribution of the nuclear obscuring material may be taking place rapidly and at different interaction stages washing out the evidence of an evolutionary path. When compared to normal AGN, the nuclear star formation activity of quasars appears to be dimming whereas it is enhanced in some IR-bright nuclei, suggesting that the latter are in an earlier star-formation dominated phase. [ABSTRACT FROM AUTHOR]

We present subarcsecond 7.5-13 µm imaging- and spectro-polarimetric observations of NGC 1068 using CanariCam on the 10.4-m Gran Telescopio CANARIAS. At all wavelengths, we find: (1)A90?60 pc extended polarized feature in the northern ionization cone, with a uniform ~44? polarization angle. Its polarization arises from dust and gas emission in the ionization cone, heated by the active nucleus and jet, and further extinguished by aligned dust grains in the host galaxy. The polarization spectrum of the jet-molecular cloud interaction at ~24 pc from the core is highly polarized, and does not show a silicate feature, suggesting that the dust grains are different from those in the interstellar medium. (2) A southern polarized feature at ~9.6 pc from the core. Its polarization arises from a dust emission component extinguished by a large concentration of dust in the galaxy disc. We cannot distinguish between dust emission from magnetically aligned dust grains directly heated by the jet close to the core, and aligned dust grains in the dusty obscuring material surrounding the central engine. Silicate-like grains reproduce the polarized dust emission in this feature, suggesting different dust compositions in both ionization cones. (3) An upper limit of polarization degree of 0.3 per cent in the core. Based on our polarization model, the expected polarization of the obscuring dusty material is ≲0.1 per cent in the 8-13 µm wavelength range. This low polarization may be arising from the passage of radiation through aligned dust grains in the shielded edges of the clumps. [ABSTRACT FROM AUTHOR]

We present far-infrared (FIR) 70-500?μm imaging observations obtained with Herschel/Photodetector Array Camera (PACS) and Spectral and Photometric Imaging REceiver (SPIRE) of 33 nearby (median distance of 30 Mpc) Seyfert galaxies from the Revised Shapley-Ames (RSA) catalogue. We obtain the FIR nuclear (r = 1?kpc and r = 2?kpc) and integrated spectral energy distributions (SEDs). We estimate the unresolved nuclear emission at 70?μm and we fit the nuclear and integrated FIR SEDs with a grey body model. We find that the integrated FIR emission of the RSA Seyferts in our sample is dominated by emission from the host galaxy, with dust properties similar to those of normal galaxies (non-AGN). We use four criteria to select galaxies whose nuclear 70?μm emission has a significant AGN contribution: (1) elevated 70/160?μm flux ratios, (2) spatially resolved, high dust temperature gradient, (3) 70?μm excess emission with respect to the fit of the FIR SEDs with a grey body, and (4) excess of nuclear SFR obtained from 70?μm over SFR from mid-infrared indicators. 16 galaxies (48 per cent of the initial sample) satisfy at least one of these conditions, whereas 10 satisfy half or more. After careful examination of these, we select six bona fide candidates (18 per cent of the initial sample) and estimate that ~40-70 per cent of their nuclear (r = 1-2?kpc) 70?μm emission is contributed by dust heated by the AGN. [ABSTRACT FROM AUTHOR]

We present an atlas of mid-infrared (mid-IR) ~7.5-13 μm spectra of 45 local active galactic nuclei (AGN) obtained with CanariCam on the 10.4 m Gran Telescopio CANARIAS (GTC) as part of an ESO/GTC large programme. The sample includes Seyferts and other lowluminosity AGN (LLAGN) at a median distance of 35 Mpc and luminous AGN, namely PG quasars, (U)LIRGs, and radio galaxies (RG) at a median distance of 254 Mpc. To date, this is the largest mid-IR spectroscopic catalogue of local AGN at sub-arcsecond resolution (median 0.3 arcsec). The goal of this work is to give an overview of the spectroscopic properties of the sample. The nuclear 12 μm luminosities of the AGN span more than four orders of magnitude, vL12μm ~ 3 × 1041-1046 erg s-1. In a simple mid-IR spectral index versus strength of the 9.7 μm silicate feature diagram most LLAGN, Seyfert nuclei, PG quasars, and RGs lie in the region occupied by clumpy torus model tracks. However, the mid-IR spectra of some might include contributions from other mechanisms. Most (U)LIRG nuclei in our sample have deeper silicate features and flatter spectral indices than predicted by these models suggesting deeply embedded dust heating sources and/or contribution from star formation. The 11.3 μm polycyclic aromatic hydrocarbon (PAH) feature is clearly detected in approximately half of the Seyfert nuclei, LLAGN, and (U)LIRGs. While the RG, PG quasars, and (U)LIRGs in our sample have similar nuclear vL12μm, we do not detect nuclear PAH emission in the RGs and PG quasars. [ABSTRACT FROM AUTHOR]

The 9.7-μm silicate absorption profile in the interstellar medium (ISM) provides important information on the physical and chemical composition of interstellar dust grains. Measurements in the Milky Way have shown that the profile in the diffuse ISM is very similar to the amorphous silicate profiles found in circumstellar dust shells around late M stars, and narrower than the silicate profile in denser star-forming regions. Here, we investigate the silicate absorption profile towards the very heavily obscured nucleus of NGC 4418, the galaxy with the deepest known silicate absorption feature, and compare it to the profiles seen in the Milky Way. Comparison between the 8-13 μm spectrum obtained with Thermal-Region Camera Spectrograph on Gemini and the larger aperture spectrum obtained from the Spitzer archive indicates that the former isolates the nuclear emission, while Spitzer detects low surface brightness circumnuclear diffuse emission in addition. The silicate absorption profile towards the nucleus is very similar to that in the diffuse ISM in the Milky Way with no evidence of spectral structure from crystalline silicates or silicon carbide grains. [ABSTRACT FROM AUTHOR]

We present Gran Telescopio CANARIAS CanariCam 8.7 μm imaging and 7.5–13 μm spectroscopy of six local systems known to host an active galactic nucleus (AGN) and have nuclear star formation. Our main goal is to investigate whether the molecules responsible for the 11.3 μm polycyclic aromatic hydrocarbon (PAH) feature are destroyed in the close vicinity of an AGN. We detect 11.3 μm PAH feature emission in the nuclear regions of the galaxies as well as extended PAH emission over a few hundred parsecs. The equivalent width (EW) of the feature shows a minimum at the nucleus but increases with increasing radial distances, reaching typical star-forming values a few hundred parsecs away from the nucleus. The reduced nuclear EWs are interpreted as due to increased dilution from the AGN continuum rather than destruction of the PAH molecules. We conclude that at least those molecules responsible for the 11.3 μm PAH feature survive in the nuclear environments as close as 10 pc from the AGN and for Seyfert-like AGN luminosities. We propose that material in the dusty tori, nuclear gas discs, and/or host galaxies of AGN is likely to provide the column densities necessary to protect the PAH molecules from the AGN radiation field. [ABSTRACT FROM PUBLISHER]