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Start Over Author "He, Ya-Mei" Topic imines
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1. New formation of imines of C19-diterpenoid alkaloids by heating with DMSO.

Author

He YM, Zou CL, Chen QH, and Wang FP

Subjects
Spectrometry, Mass, Electrospray Ionization, Alkaloids chemistry, Dimethyl Sulfoxide chemistry, Diterpenes chemistry, Imines chemical synthesis
Abstract

Treatment of some C(19)-diterpenoid alkaloids (3, 6, 10 and 12) with anhydrous DMSO at 100-170 degrees C for 3-7 h led to the formation of the corresponding imines (4, 7/8, 11, 13/14) in 65-83% yield, respectively. This is a new simpler formation of the imines of the C(19)-diterpenoid alkaloids.

Published
2007
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