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This study presents new zircon LA-ICP-MS U–Pb ages, zircon Hf isotopes, and whole-rock geochemical compositions for Late Palaeozoic–Early Mesozoic intrusive rocks from the Erguna Massif, Northeast China. Zircon U–Pb dating results indicate that the intrusive rocks were emplaced during the Late Permian–Middle Triassic (ca. 256–234 Ma) and Late Triassic (ca. 210 Ma) in the western and eastern parts of the Erguna Massif, respectively. The Late Permian gabbros and quartz monzodiorites display enrichment in Rb and K, but are depleted in Nb, Ta, and Ti. Their εHf(t) values (+5.1 to +9.1 and −0.2 to +3.7, respectively) and one-stage Hf model ages (TDM1 = 544–704 Ma and 764–889 Ma, respectively) indicate that they might be derived from the reworking of the Neoproterozoic lithospheric mantle that was metasomatised by subduction-related fluids. The Late Permian–Early Middle Triassic quartz monzonites, monzogranites, and syenogranites display variable enrichment of rare earth elements (REEs) and large ion lithophile elements (LILEs). They have εHf(t) values varying from −5.7 to +2.7 with two-stage Hf model ages (TDM2) of 1.09–1.69 Ga, implying that they possibly originated from the Mesoproterozoic continental crust. The Late Triassic syenogranites show geochemical signatures of A2-type granites with various enrichment in LILEs and LREEs and depletion in Nb, Ta, and Ti. Combined with regional geological evidence, we conclude that Late Permian to Late Triassic igneous rocks on both sides of the Mongol–Okhotsk suture belt record an active continental margin environment associated with the ongoing bidirectional subduction of the Mongol–Okhotsk Ocean. The eastern Erguna Massif and Xing'an Massif were likely located in a back-arc setting at least since ca. 216 Ma, with long-term southward subduction of the Mongol–Okhotsk oceanic slab spanning from the Late Permian–Early Jurassic. [ABSTRACT FROM AUTHOR]

• A Late Jurassic porphyry Cu-Mo deposit in the Erguna Block is reported. • Ore-bearing rocks were derived from the partial melting of the oceanic slab. • Petrogenesis of ore-related rocks related to a flat-slab subduction. The genesis of igneous rocks associated with the newly discovered Xiaokele porphyry Cu-Mo deposit, located in the eastern Erguna Block, NE China, can give insights into the regional geodynamic evolution during the Late Mesozoic. Several ore-bodies have been identified in a granodiorite porphyry stock, which intruded the rhyolite and was subsequently intruded by diorite porphyry and granite porphyry. The U–Pb ages of zircons from rhyolite, mineralized granodiorite porphyry, diorite porphyry and granite porphyry associated with the Xiaokele deposit are 152.5 ± 1.7, 150.0 ± 1.6, 147.9 ± 1.3, and 123.2 ± 1.7 Ma, respectively. The rhyolite and granite porphyry have high SiO 2 and low MgO, Cr, Co, and Ni contents. Their isotopic data show negative ε Nd (t) values of −4.76 to −0.87, initial 87Sr/86Sr ratios of 0.7066 to 0.7134 and positive zircon ε Hf (t) values of 0.33–5.56, indicating that they were derived from a basaltic lower continental crust. The mineralized granodiorite porphyry is characterized by high Sr/Y values and low Y (3.7–8.0) contents, showing adakite affinity. The low K 2 O/Na 2 O (0.51–0.7) ratios, high CaO contents, weakly negative ε Nd (t) (−1.17 to −0.27), and low zircon ε Hf (t) (1.49–5.4) values from the adakitic samples indicate that they were derived from the partial melting of an altered oceanic slab together with assimilation of mantle peridotite and crustal materials. The 148 Ma diorite porphyry has high Mg# (51–58), weakly negative and positive ε Nd (t) (−0.09 to 0.01) values, and lower (87Sr/86Sr) i (0.7055–0.7057) ratios, suggesting an enriched mantle wedge source. Considering the late Mesozoic regional tectonic evolution of the Erguna Block and adjacent area, we propose that the formation of the Xiaokele deposit is linked to the southward flat-slab subduction of the Mongol–Okhotsk oceanic plate during the Later Jurassic-Early Cretaceous. [ABSTRACT FROM AUTHOR]

Abstract Multistage igneous rocks identified in the newly discovered Fukeshan porphyry Cu Mo deposit, NE China give new insights into the late-stage southwards subduction of the Mongol-Okhotsk oceanic slab (MOOS) and Cu Mo mineralization during the late Mesozoic. The U Pb ages of zircons from medium-grained monzogranite, coarse-grained monzogranite, ore-related quartz diorite porphyry, quartz monzonite, ganodiorite porphyry, diorite porphyry and andesitic porphyry associated with the Fukeshan deposit are 192.7 ± 1.9, 192.2 ± 2.7, 148.7 ± 0.8, 148.8 ± 0.9, 144.1 ± 1.1, 144.9 ± 0.9, and 144.8 ± 1.3 Ma, respectively. The Early Jurassic coarse-grained monzogranite, Late Jurassic quartz monzonite and quartz diorite porphyry, and Early Cretaceous granodiorite porphyry are characterized by low Yb and Y contents, and high Sr/Y ratios, indicating adakite affinities. The whole-rock geochemistry, and Sr Nd and zircon Hf isotopic features of the coarse-grained monzogranite and granodiorite porphyry indicate they were derived from the partial melting of a thickened basaltic lower crust. On the other hand, the quartz monzonite and quartz diorite porphyry probably originated from the melting of oceanic crust together with assimilation of enriched mantle and continental crust. The medium-grained monzogranites were possibly derived from a basaltic lower crust at shallower depths, and the diorite porphyry and andesitic porphyry probably originated from a metasomatized mantle source. Considering the Early Jurassic–Early Cretaceous magmatism and regional tectonic evolution of the Erguna Block, we propose that the MOOS was subducted towards the south during the Early Jurassic (195–170 Ma), slab retreat occurred during the early Late Jurassic (165–155 Ma), oceanic ridge subduction took place during the Late Jurassic (150–147 Ma). The final closure of the Mongol-Okhotsk Ocean occurred during the Early Cretaceous (145–143 Ma). The southwards subduction of a ridge on the MOOS provided a favorable tectonic setting for Cu Mo mineralization, and this is accordance with the discovery of many Late Jurassic–Early Cretaceous porphyry Cu Mo deposits in the eastern part of the Erguna Block. Highlights • Multiple episodes of magmatism during Mesozoic indicated by zircon geochronology • The rocks show different sources: oceanic slab, lower crust and enriched mantle. • The slab-derived rocks indicate a Late Jurassic ridge subduction of the MOOS. • The ridge subduction dominated the generation of porphyry Cu Mo deposits. [ABSTRACT FROM AUTHOR]

Magmatic rocks carry key information to understand the processes of material cycling in the Earth's interior and record crucial clues to reconstruct the important tectonic evolution of the Earth. Therefore, it is of great importance to constrain the magma source (such as origin from crust or mantle, oceanic crust or continental crust, lower or upper continental crust) accurately, which however remains to be unraveled because of the variety magmatic sources and complex magmatic processes. High-precision stable isotopic analyses provide new tools to decipher the genesis of igneous rocks and to reconstruct their associated tectonic settings. Here, we report a pioneering work using integrated O-Hg-Hf-Nd isotopes to understand the genesis of the Early Cretaceous A-type granites and rhyolites from the Paleozoic-Mesozoic accretionary orogen in NE China. Low δ18O zircon values (3.2–5.7‰) of the A-type rocks reveal a magma source affected by meteoric fluids. Their whole-rock negative Δ199Hg values (−0.24 to −0.01‰), which are similar with the terrestrial systems but clearly different from the marine systems, indicate that hydrothermal alteration took place in the continental setting. Positive zircon ε Hf (t) (4.2–10.7) and mainly positive whole-rock ε Nd (t) (−0.5 to 2.4, mean = 1.2 ± 1.0, 1SD) values indicate that the magma source was dominated by juvenile crustal materials. This study suggests an elevated geothermal gradient due to the lithospheric thinning triggered by rollback and foundering of a Paleo-oceanic slab. The specific thermal anomaly caused the remelting of the altered upper continental crust, resulting in the formation of the A-type granites and rhyolites, with the characters of low-δ18O and negative-Δ199Hg values. Our study shows that Hg isotope, coupled with O and Nd Hf isotopes, is a promising tool for petrogenetic studies. [ABSTRACT FROM AUTHOR]