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Mineral dust can indirectly affect the climate by supplying bioavailable iron (Fe) to the ocean. Here, we present the records of dissolved Fe (DFe) and total Fe (TDFe) in North Greenland Eemian Ice Drilling (NEEM) ice core over the past 110 kyr BP. The Fe records are significantly negatively correlated with the carbon-dioxide (CO2) concentrations during cold periods. The results suggest that the changes in Fe fluxes over the past 110 kyr BP in the NEEM ice core are consistent with those in Chinese loess records because the mineral-dust distribution is controlled by the East Asian deserts. Furthermore, the variations in the dust input on a global scale are most likely driven by changes in solar radiation during the last glacial–interglacial cycle in response to Earth's orbital cycles. In the last glacial–interglacial cycle, the DFe/TDFe ratios were higher during the warm periods (following the post-Industrial Revolution and during the Holocene and last interglacial period) than during the main cold period (i.e. the last glacial maximum (LGM)), indicating that the aeolian input of iron and the iron fertilization effect on the oceans have a non-linear relationship during different periods. Although the burning of biomass aerosols has released large amounts of DFe since the Industrial Revolution, no significant responses are observed in the DFe and TDFe variations during this period, indicating that severe anthropogenic contamination has no significant effect on the DFe (TDFe) release in the NEEM ice core. [ABSTRACT FROM AUTHOR]

We conducted a 2 m snow pit study in July 2017 at the East GRIP (Greenland Ice-Core Project; northeastern Greenland) deep ice-coring site. We collected snow samples at intervals of 0.05 m and analyzed their iron (Fe) and rare earth element (REE) concentrations. Pronounced seasonal variations in trace elements were observed during 2012–2017. The results indicated that the dissolved Fe (DFe), total dissolved Fe (TDFe), and total dissolved REEs (TDREEs) largely originated from mineral dust, which peaked in winter to early spring. In particular, the 2014–2015 Holuhraun eruption (31 August 2014 to 27 February 2015) can be clearly observed in the data at a depth of 90–125 cm. This event not only provided abundant acidic material (sulphate), but also released a large amount of DFe. Therefore, these results provide a possible way to use Greenland deep ice core data to construct a much longer history and better understand the relationship between eruptions and the release of iron in future studies. [ABSTRACT FROM AUTHOR]