1. CRONUS-Earth calibration samples from the Huancané II moraines, Quelccaya Ice Cap, Peru.
- Author
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Phillips, Fred M., Kelly, Meredith A., Hudson, Adam M., Stone, John O.H., Schaefer, Joerg, Marrero, Shasta M., Fifield, L. Keith, Finkel, Robert, and Lowell, Thomas
- Subjects
SURFACE of the earth ,COSMOGENIC nuclides ,ICE caps ,CALIBRATION ,CHRONOLOGY ,RADIOCARBON dating - Abstract
The Huancané II moraines deposited by the Quelccaya Ice Cap in southern Peru were selected by the CRONUS-Earth Project as a primary site for evaluating cosmogenic-nuclide scaling methods and for calibrating production rates. The CRONUS-Earth Project is an effort to improve the state of the art for applications of cosmogenic nuclides to earth-surface chronology and processes. The Huancané II moraines are situated in the southern Peruvian Andes at about 4850 m and ∼13.9°S, 70.9°W. They are favorable for cosmogenic-nuclide calibration because of their low-latitude and high-elevation setting, because their age is very well constrained to 12.3 ± 0.1 ka by 34 radiocarbon ages on peat bracketing the moraines, and because boulder coverage by snow or soil is thought to be very unlikely. However, boulder-surface erosion by granular disintegration is observed and a ∼4% correction was applied to measured concentrations to compensate. Samples from 10 boulders were analyzed for 10 Be, 26 Al, and 36 Cl. Interlaboratory bias at the ∼5% level was the largest contributor to variability of the 10 Be samples, which were prepared by three laboratories (the other two nuclides were only prepared by one laboratory). Other than this issue, variability for all three nuclides was very low, with standard deviations of the analyses only slightly larger than the analytical uncertainties. The site production rates (corrected for topographic shielding, erosion, and radionuclide decay) at the mean site elevation of 4857 m were 45.5 ± 1.6 atoms 10 Be (g quartz) −1 yr −1 , 303 ± 15 atoms 26 Al (g quartz) −1 yr −1 , and 1690 ± 100 atoms 36 Cl (g K) −1 yr −1 . The nuclide data from this site, along with data from other primary sites, were used to calibrate the production rates of these three nuclides using seven global scaling methods. The traditional Lal formulation and the new Lifton-Sato-Dunai calibrations yield average ages for the Huancané samples that are in excellent-to-good agreement with the radiocarbon age control (within 0.7% for 10 Be and 36 Cl and 6% for 26 Al). However, all of the neutron-monitor-based methods yielded ages that were too young by about 20%. The nuclide production ratios at this site are 6.74 ± 0.34 for 26 Al/ 10 Be in quartz and 37.8 ± 2.3 (atoms 36 Cl (g K) −1 ) (atom 10 Be (g SiO 2 ) −1 ) −1 for 36 Cl/ 10 Be, in sanidine and quartz, respectively. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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