Jia, Zhenggang, Zhang, Xuexi, Qian, Mingfang, Ma, Siyao, Jin, Yingmin, and Xiong, Yueping
The shuttling of polysulfide intermediates and volume distortion during cycling make it challenging for the applications of MoS 2 at high current densities without capacity fading. In order to improve the cycle life and rate capability of lithium-ion batteries, introducing a porous matrix is a viable strategy. Here, MoS 2 with 3D porous graphene prepared by low-temperature hydrothermal (160 °C) and low-energy ultrasound-assisted (40 W for 120 s) methods shows no impurities, large layer thickness (0.94 nm, 54 % increase) and no bare MoS 2 , resulting in smaller volume expansion (34 % in Li 4 MoS 2), higher lithium stability (0.66 eV of adsorption energy) and more convenient ion transport channels. The first-principles calculations show that more lithium can be inserted without destroying the layered structure by forming a lithium metal layer between the MoS 2 layers. The encapsulation of graphene not only hinders the shuttle effect of sulfur, but also improves the adsorption energy of lithium atoms in the electrode. In addition, electrochemical analysis shows that the clear drop in charge transfer resistance (Rct) in the first 300 cycles also indicates the improvement of the reaction pathway by graphene. As a result, the as-prepared rGO/MoS 2 still maintains a specific capacity of 1008 mAh·g−1 with a very low capacity decay rate (0.03 % per cycle) at a current density of 1 A·g−1 after 500 cycles as an electrode material for lithium-ion batteries. [Display omitted] • rGO/MoS 2 prepared by low-temperature hydrothermal and low-energy ultrasound. • Large layer thickness (0.94 nm) and no bare MoS 2 in graphene-encapsulated MoS 2. • A lithium metal layer forming between the MoS 2 layers to reduce volume expansion (34 % in Li 4 MoS 2). • Higher adsorption energy of lithium atoms (0.66 eV). • The clear drop in charge transfer resistance (Rct) in the first 300 cycles. • A specific capacity (1008 mAh·g−1) with low capacity decay rate (0.03 % per cycle) after 500 cycles. [ABSTRACT FROM AUTHOR]