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Hydrogen is rapidly turning into one of the essential energy carriers for future sustainable energy systems. The main reason for this is the possibility of off-peak excess power production and storage of renewable stations such as wind farms, photovoltaic plants, etc. For hydrogen (itself) or its sub-productions methanol, ammonia, etc. Such energy systems are so-called power2X technologies. For hydrogen and other biogases, using a fuel cell is a promising method for returning the fuel to the power grid or electric cars in the form of electricity. In this paper, a novel hybrid energy system consisting of a molten carbonate fuel cell (MCFC) and different options to generate hydrogen from the waste heat of the MCFC is investigated. The system consists of two scenarios of weather using proton exchange membrane electrolyzer (PEME) of vanadium chloride (VCL) cycle. The article presents a comprehensive thermodynamic, economic, and environmental analysis of the system optimized by tri-objective optimization (as an innovative optimization) methods. The aim of the optimization task here is to minimize the costs and emissions while maximizing efficiency. A parametric study is conducted to see the effect of different design parameters on the system's performance. Results demonstrate that fuel utilization factor, stack temperature, and current density have the most critical effect on the system performance. In addition, the system coupled with the VCL cycle exhibits better performance than the system with PEME. In addition, at the optimized point, the efficiency, cost rate, and emission become 69.28%, 3.73 ($/GJ), and 1.16 kg/kWh, respectively. In addition, the produced hydrogen in VCL and PEME are 585 kg/day and 293 kg/day respectively. • The hybrid system based on gasifier and MCFC is modeled from 4E perspectives. • The cutting-edge tri-objective optimization is considered to minimize cost and emission and maximize the efficiency. • Two novel methods of producing hydrogen from waste heat is presented and analyzed in detail. • In optimum conditions, the exegetic efficiency and unit product cost become 69.28% and 3.73 ($/GJ) respectively. [ABSTRACT FROM AUTHOR]

In this present research study a multi-generation energy system which is coupled with CO 2 capture unit which is based on Rankine cycle, organic Rankine cycle, ejector cooling system and absorption chiller has been analyzed via energy, exergy, exergy-economic aspects by developing MATLAB, also to achieve the optimum operating condition genetic algorithm has been applied for system optimization. The objective of this study is to propose an optimized efficient integrated energy system to recycle the energy waste of a typical industrial factory. The optimization has been illustrated on a Pareto frontier to achieve the optimum scheme of the multi-generation system regarding technical and economic viewpoints. Results indicate the optimal condition of this system has occurred at 0.37 exergy efficiency with 0.03 $/s. Furthermore, by surging the mass flow rate of waste gases up to 70 kg/s, net power output augmented up to 7500 kW. Besides, hydrogen production and produced desalinated water rise up to 8.5 g/s and 16 kg/s, respectively. • Design a waste heat recovery system for a steel production factory. • Perform exergy, exergo-economic and optimization of suggested system. • The produced hydrogen can be reach 8.5 gr/s. • Optimization results indicate that the exergy efficiency can improve up to 37%. [ABSTRACT FROM AUTHOR]