Search

The presence of fermentative hotspots in municipal waste dumps has been reported for several decades, but no study has focused on their size and shape. The uncontrolled landfill of Soub Sekt, covering an area of about 8 hectares in the Tadla plain in Morocco, is the source of a permanent pollution plume in the groundwater, detected by self-potential (SP) measurements. The study aims to detect and characterize these hotspots as well as the leachates that form within them. These hotspots are typically circular and smaller than 3 m in size, and they are concentrated within recent waste deposits. Intense electron transfer activities, particularly during redox reactions leading to metal solubilization, result in very low SP values (down to −60 mV), facilitating their detection. Several successive field campaigns suggest that they are active for 2–3 weeks. Due to the low permeability of the soils, highly mineralized leachates (average Electrical Conductivity 45 mS cm−1) rich in organic ions accumulate on the soil surface at the base of the waste windrows. There, they evolve by concentration due to evaporation and oxidation due to slow diffusion of atmospheric O2. Despite the small size of the hotspots generating the leachates, the accumulation of leachates in ponds and the low soil permeability limits the percolation rate, resulting in moderate but permanent groundwater pollution.

The number and diversity of groundwater bodies (GWBs) in large French administrative regions pose challenges to their monitoring and protection by regional health agencies. To overcome this obstacle, we propose, for the Auvergne-Rhône-Alpes region (about 70,000 km2), a grouping of GWBs into homogeneous groups based on the sources of variability within a large dataset of groundwater physico-chemical and bacteriological characteristics (8078 observations and 13 parameters). This grouping involved a dimensional reduction in the data hyperspace by principal component analysis (PCA) and a clustering based on the mean values of each GWB on the factorial axes. The information lost when clustering from the sample point scale to the GWB scale and then to that of the GWB group was quantified by analysis of variance and showed that grouping GWBs is accompanied by a small loss of information. A discriminant analysis confirmed the high spatial and temporal variability within the dataset, as well as the effectiveness of the proposed method for establishing homogeneous sets. Some roadmaps for more targeted monitoring of water resources were briefly proposed.

In many parts of the world, the impact of open landfills on soils, biosphere, and groundwater has become a major concern. These landfills frequently generate pollution plumes, the contours of which can be delineated by non-intrusive geophysical measurements, but in arid environments, the high soils resistivity is usually an obstacle, which results in the low number of studies that have been carried out there. In addition, such prospecting using geophysical techniques do not provide information on the intensity of the processes occurring in the water table. This study was carried out on an uncontrolled landfill in the arid Tadla plain, Morocco’s main agricultural region. A survey based on geo-referenced spontaneous potential measurements was combined with measurements of anoxic conditions (Eh-pH and O2 equilibrating partial pressure) in the groundwater and leachates, in order to highlight a pollution plume and its geometry. The range of spontaneous potential measurement is wide, reaching 155 mV. Ponds of leachate with high electrical conductivity (20 to 40 mS cm−1) form within the landfill, and present very reducing conditions down to sulphate reduction and methanisation. The plume is slowly but continuously supplied with these highly reducing and organic carbon-rich leachates from the landfill. Its direction is towards N-NW, stable throughout the season, and consistent with local knowledge of groundwater flow. The fast flow of the water table suggests pollution over long distances that should be monitored in the future. The results obtained are spatially contrasting and stable, and show that such techniques can be used on a resistive medium of arid environments.

The main landfill in the city of Rabat (Morocco) is based on sandy material containing the shallow Mio-Pliocene aquifer. The presence of a pollution plume is likely, but its extent is not known. Measurements of spontaneous potential (SP) from the soil surface were cross-referenced with direct measurements of the water table and leachates (pH, redox potential, electrical conductivity) according to the available accesses, as well as with an analysis of the landscape and the water table flows. With a few precautions during data acquisition on this resistive terrain, the results made it possible to separate the electrokinetic (~30%) and electrochemical (~70%) components responsible for the range of potentials observed (70 mV). The plume is detected in the hydrogeological downstream of the discharge, but is captured by the natural drainage network and does not extend further under the hills.

In France, the data resulting from monitoring water intended for human consumption are integrated into a national database called SISE-Eaux, a useful and relevant tool for studying the quality of raw and distributed water. A previous study carried out on all the data from the Provence-Alpes-Côte d’Azur (PACA) region in south-eastern France (1061 sampling points, 5295 analyses and 15 parameters) revealed that the dilution of the information in a heterogeneous environment constitutes an obstacle to the analysis of ongoing processes that are sources of variability. In this article, cross-referencing this information with the compartmentalization into groundwater bodies (MESO) provides a hydrogeological constraint on the dataset that can help to better define more homogeneous subsets and improve the interpretation. The approach involves three steps: (1) A principal component analysis conducted on the whole dataset aimed at eliminating information redundancy; (2) an unsupervised grouping of groundwater bodies having similar sources of variability; (3) a principal component analysis carried out within the main groups and sub-groups identified, aiming to define and prioritize the sources of variability and the associated processes. The results supported by discriminant analysis and machine learning show that the grouping of MESO is the best-suited scale to study ongoing processes due to greater homogeneity. One of the eight main groups identified in PACA, corresponding to the accompanying aquifers of the main rivers, is analyzed by way of illustration. Water–rock interactions, redox processes and their effects on the release of metals, arsenic and fecal contamination along different pathways were specifically identified with varying impacts according to the subgroups. We discussed both the significance of the principal components and the mean values of the bacteriological parameters, which provide information on the causes and on the state of contamination, respectively. Based on the results from two different groups of MESO, some guidelines in terms of a strategy for resource quality monitoring are proposed.

The SISE-Eaux database of water intended for human consumption, archived by the French Regional Health Agency (ARS) since 1990, is a rich source of information. However, more or less regular monitoring over almost 30 years and the multiplication of parameters lead to a sparse matrix (observations × parameters) and a large dimension of the hyperspace of data. These characteristics make it difficult to exploit this database for a synthetic mapping of water quality, and to identify of the processes responsible for its diversity in a complex geological context and anthropized environment. A 10-year period (2006−2016) was selected from the Provence-Alpes- Côte d’Azur region database (PACA, southeastern France). We extracted 5,295 water samples, each with 15 parameters. A treatment by principal component analysis (PCA) followed with orthomax rotation allows for identifying and ranking six principal components (PCs) totaling 75% of the initial information. The association of the parameters with the principal components, and the regional distribution of the PCs make it possible to identify water-rock interactions, bacteriological contamination, redox processes and arsenic occurrence as the main sources of variability. However, the results also highlight a decrease of useful information, a constraint linked to the vast size and diversity of the study area. The development of a relevant tool for the protecting and managing of water resources will require identifying of subsets based on functional landscape units or the grouping of groundwater bodies.