8 results on '"Kalina, Lukáš"'
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2. Correlating Hydration of Alkali-Activated Slag Modified by Organic Additives to the Evolution of Its Properties.
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Bílek Jr., Vlastimil, Kalina, Lukáš, Dvořák, Richard, Novotný, Radoslav, Švec, Jiří, Másilko, Jiří, and Šoukal, František
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SLAG cement , *ULTRASONIC testing , *SLAG , *HYDRATION , *HYDRATION kinetics - Abstract
This study investigates the relationships between the hydration kinetics of waterglass-activated slag and the development of its physical-mechanical properties, as well as its color change. To modify the calorimetric response of alkali-activated slag, hexylene glycol was selected from various alcohols for in-depth experiments. In presence of hexylene glycol, the formation of initial reaction products was restricted to the slag surface, which drastically slowed down the further consumption of dissolved species and slag dissolution and consequently delayed the bulk hydration of the waterglass-activated slag by several days. This allowed to show that the corresponding calorimetric peak is directly related to the rapid evolution of the microstructure and physical-mechanical parameters and to the onset of a blue/green color change recorded as a time-lapse video. Workability loss was correlated with the first half of the second calorimetric peak, while the most rapid increase in strengths and autogenous shrinkage was related to the third calorimetric peak. Ultrasonic pulse velocity increased considerably during both the second and third calorimetric peak. Despite the modified morphology of the initial reaction products, the prolonged induction period, and the slightly reduced degree of hydration induced by hexylene glycol, the overall mechanism of alkaline activation remained unchanged in the long-term perspective. It was hypothesized that the main issue of the use of organic admixtures in alkali-activated systems is the destabilizing effect of these admixtures on soluble silicates introduced into the system with an activator. [ABSTRACT FROM AUTHOR]
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- 2023
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3. Effect of Alkali Salts on the Hydration Process of Belite Clinker.
- Author
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Iliushchenko, Valeriia, Kalina, Lukáš, Sedlačík, Martin, Cába, Vladislav, Másilko, Jiří, and Novotný, Radoslav
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CRYSTALLIZATION kinetics , *HYDRATION , *X-ray powder diffraction , *DIFFERENTIAL thermal analysis , *HYDRATION kinetics , *CEMENT , *POWDERS - Abstract
Belite-rich cement is a low carbon footprint binder. However, its use is accompanied by a low initial rate of hydration. This can be partially eliminated by grinding to a high specific surface or through the addition of admixtures (mineralizators or activators). The influence of alkaline activators CaSO4, Na2SO4 and Na2CO3 (in the amount of 5 wt.% related to the clinker weight) on the hydration course, as well as the quantity of hydration products in belite-rich cements, were investigated in this paper. Belite-rich clinker was laboratory-synthetized and ground together with activators to prepare various belite-rich cements. Next, the hydration kinetics and the hydrated phase assemblage were investigated using isothermal calorimetry, X-ray powder diffraction and thermogravimetric and differential thermal analyses. The use of selected admixtures allowed us to obtain belite-rich cements with higher hydraulic activity in the initial period. [ABSTRACT FROM AUTHOR]
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- 2022
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4. Effect of Cement Kiln Bypass Dust on Properties and Hydration of Akali-Activated Slag Mixtures
- Author
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Bílek Vlastimil, Kalina Lukáš, Novotný Radoslav, Másilko Jiří, and Šoukal František
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Cement kiln bypass dust ,alkaline activation ,hydration ,calorimetry ,X-ray diffraction ,volume change - Abstract
During recent decades, alkali-activated slag (AAS) systems have attracted great scientific interest around the world. Despite many efforts its severe shrinkage and cracking is still a delicate issue. The aim of this work was to partially replace slag by cement kiln bypass dust (CBPD) which, on the basis of its mineralogical composition, would act as an expansive agent (EA) and thus compensate AAS shrinkage. It was observed that volume changes of AAS/CBPD mixtures strongly depended on CBPD dose since low slag replacement levels did not significantly reduce autogenous shrinkage while around 50% of CBPD or more led to severe expansion. Based on X-ray diffraction, this expansion is related to hydrocalumite-type phase formation. The presence of CBPD also totally modified calorimetric response of AAS pastes., This outcome has been achieved with financial support of the Czech Science Foundation (GAČR) under the project No 18-12289Y.
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- 2019
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5. Polyethylene glycol molecular weight as an important parameter affecting drying shrinkage and hydration of alkali-activated slag mortars and pastes.
- Author
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Bílek, Vlastimil, Kalina, Lukáš, and Novotný, Radoslav
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POLYETHYLENE glycol , *HYDRATION , *MORTAR , *DRYING , *MOLECULAR weights , *SLAG - Abstract
The aim of this study was to explore the influence of ethylene glycol in a wide range of polymerization degree, i.e. from monomer (EG) up to polyethylene glycol (PEG) with molecular weight of about 35,000, on properties of alkali-activated slag mortars. Changes in molecular weight and dose of all tested glycols had only minor effect on compressive strength, while drying shrinkage was significantly affected by both these factors. EG had negligible impact on drying shrinkage, but other tested glycols reduced it significantly with PEG2000 and PEG10000 being the most effective. Such different shrinkage behavior was attributed to the changes in surface tension and pore structure. All tested glycols reduced the total heat released during the hydration and interestingly modified the heat flow depending on their molecular weight. [ABSTRACT FROM AUTHOR]
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- 2018
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6. Some Issues of Shrinkage-Reducing Admixtures Application in Alkali-Activated Slag Systems.
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Bílek Jr., Vlastimil, Kalina, Lukáš, Novotný, Radoslav, Tkacz, Jakub, and Pařízek, Ladislav
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ALKALIES , *SLAG , *POLYPROPYLENE oxide , *SCANNING electron microscopy , *HYDRATION - Abstract
Significant drying shrinkage is one of the main limitations for the wider utilization of alkali-activated slag (AAS). Few previous works revealed that it is possible to reduce AAS drying shrinkage by the use of shrinkage-reducing admixtures (SRAs). However, these studies were mainly focused on SRA based on polypropylene glycol, while as it is shown in this paper, the behavior of SRA based on 2-methyl-2,4-pentanediol can be significantly different. While 0.25% and 0.50% had only a minor effect on the AAS properties, 1.0% of this SRA reduced the drying shrinkage of waterglass-activated slag mortar by more than 80%, but it greatly reduced early strengths simultaneously. This feature was further studied by isothermal calorimetry, mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). Calorimetric experiments showed that 1% of SRA modified the second peak of the pre-induction period and delayed the maximum of the main hydration peak by several days, which corresponds well with observed strength development as well as with the MIP and SEM results. These observations proved the certain incompatibility of SRA with the studied AAS system, because the drying shrinkage reduction was induced by the strong retardation of hydration, resulting in a coarsening of the pore structure rather than the proper function of the SRA. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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7. Doubts over capillary pressure theory in context with drying and autogenous shrinkage of alkali-activated materials.
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Kalina, Lukáš, Bílek, Vlastimil, Bartoníčková, Eva, Kalina, Michal, Hajzler, Jan, and Novotný, Radoslav
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EXPANSION & contraction of concrete , *SURFACE tension , *DRYING , *AMINO alcohols , *SCANNING electron microscopy , *SURFACE active agents , *PRESSURE - Abstract
• Amino alcohol surfactants reduced the surface tension of AAS pore solutions. • Surfactants had a minor effect on autogenous shrinkage. • Drying shrinkage was reduced mainly thanks to hydration retardation caused by surfactants. • Decrease in surface tension does not necessarily lead to decrease in shrinkage. • Adsorption of surfactants on slag particles were observed. One of the most important technological problems associated with alkali-activated materials is high shrinkage. In this study, shrinkage reducing admixtures (SRAs) based on amino alcohols were used in alkali-activated slag (AAS) as strong surfactants that should, in terms of capillary pressure theory, decrease shrinkage via the decrease in surface tension. Although the surface tension of the pore solution was reduced by SRAs, autogenous shrinkage was not affected in the long run, while drying shrinkage was noticeably reduced and simultaneous weight changes were dramatically increased. The expected retardation effect of SRAs on hydration was confirmed using isothermal calorimetry, strength development, mercury intrusion porosimetry and scanning electron microscopy. The obtained results suggest that the observed effect of SRAs on drying shrinkage was caused by coarser pore structure rather than by a decrease in surface tension of the pore solution. Since the decrease in surface tension does not necessarily lead to decrease in shrinkage, the application of capillary pressure theory in AAS can sometimes be an issue. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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8. Philosophy of rational mixture proportioning of alkali-activated materials validated by the hydration kinetics of alkali-activated slag and its microstructure.
- Author
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Bílek, Vlastimil, Novotný, Radoslav, Koplík, Jan, Kadlec, Martin, and Kalina, Lukáš
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HYDRATION kinetics , *SLAG , *MOLARITY , *MICROSTRUCTURE , *POTASSIUM hydroxide - Abstract
There are many highly variable approaches to mix proportioning of alkali-activated materials (AAMs), which considerably contribute to their great complexity and often incomparability of the obtained results. Therefore, this paper suggests one specific approach, based on the molarity of the activator and the volume fraction of the precursor. First, an inherently simple calculation procedure is introduced to obtain the weights of the raw materials required to prepare a desired volume of AAM paste and possibly mortar or concrete. Second, the rationale for this approach is demonstrated using calorimetric experiments conducted on alkali-activated slag pastes, activated with sodium and potassium hydroxides, waterglasses, and carbonates in wide ranges of molarities. Third, the applicability and impact of the presented approach are discussed in-depth, considering practical applications. The overall outcome is a complex set of information emphasizing the importance of molarity, precursor volume fraction, and space-filling ability of the reaction products for different activators. • Mix designing of AAM based on activator molarity and precursor volume fraction • Space-filling ability of products for each activator also considered • Reaction kinetics of AAS mapped over the concentrations of six common activators • Molarity of 2 to 4 M Na+ or K+ recommended for slag activation • Impact of the presented approach and data discussed in a wide practical and scientific context [ABSTRACT FROM AUTHOR]
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- 2023
- Full Text
- View/download PDF
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