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Abstract: The ablated surface morphology feature of plasma sprayed Cr2O3 coatings on heat-resistant steel irradiated by high-intensity pulsed ion beam (HIPIB) at an ion current density of 300–500A/cm2 with a shot number of 1–10 was investigated by using scanning electron microscopy, X-ray diffractometry, microhardness testers, respectively, in order to explore the modification mechanism of HIPIB onto coatings. HIPIB irradiation caused a melting and ablating of Cr2O3 coating surface and formed a thin remelted Cr2O3 layer with compact structure. At the low ion current density of 300A/cm2, the splat melting and cavity sealing caused a partially compact surface with several microcracks. And a discontinuous remelted Cr2O3 layer on the compact matrix coating was obtained. With increasing the ion current density to 500A/cm2, the reformed splats by serious splat melting and sufficient cavity sealing induced a more compact surface with a continuous and thicker remelted layer, companying with a slight increase of microcracks. The enlarged splats reformed by serious splats remelting and sufficient cavities sealing induced a gradually compact and smooth surface on the irradiated Cr2O3 coatings with increasing the shot number and a more uniform and smooth surface with compact structure was obtained by the agglomeration of the enlarged splats after 10 shots. It is found that the change in microhardness of the compact remelted layer was consistent with the sealing feature on the irradiated surface. [Copyright &y& Elsevier]

Surface integrity and interface structure of coating materials play a key role in tribological and corrosion behaviors in harsh working environments in nuclear power plants. In this work, we focus on the investigations of tribological behaviors in air and seawater of CrN/TiN superlattice coatings deposited by the combined deep oscillation magnetron sputtering with pulsed dc magnetron sputtering, which were irradiated by high-intensity pulsed ion beam (HIPIB) with ion energy density of 1–3 J/cm2 and shot number of 1–5. At 1 J/cm2, the increased shot number leads to a broaden (111) peak of face-centered cubic crystal structure, indicating grain size refinement. At 3 J/cm2, the increased shot number results in the coarsening grain, and superlattice structure gradually disappeared at 2 shots, finally the coatings fell off from substrate at 5 shots. The highest hardness (H), H/E* (E*, effective Young's modulus) and H3/E*2 of the coatings irradiated at 1 J/cm2 and 5 shots are achieved at 38.7 GPa, 0.1 and 0.387, respectively. The increased ion energy density and shot number result in the decrease in Rockwell C HF adhesion level from HF1 to HF6. At 1 Jcm−2 and 1 shot, tribological behavior of irradiated coatings in air was dominated by oxidative wear with coefficient of friction (COF) of 0.51 and specific wear rate of 4.2 × 10−7mm3N−1m−1. The irradiated coatings show excellent tribocorrosion properties in seawater with high open circuit potential of 0.32 V, low COF of 0.14 and specific tribocorrosion rate of 6.1 × 10−8mm3N−1m−1 without pitting corrosion under moderate HIPIB irradiation due to high surface integrity and stability of well-defined interfaces and dense microstructure. With an increase of energy density and shot number, wear mechanism in air changes to severe adhesive and oxidative wear, while tribocorrosion mechanism is gradually dominated by plough wear coupled with pitting corrosion. [ABSTRACT FROM AUTHOR]