Search

A water distribution system must maintain water quality throughout the entire network to guarantee public health. Although several studies have focused on changes in water quality along distribution systems, very few have evaluated the entire process from the water source to household containers. The aim of this study was to evaluate the effectiveness of bacteriological control and to determine the critical points of potential contamination along the distribution system in Cancún, Mexico. We addressed three aspects: 1) physicochemical and bacteriological analysis of water, 2) biochemical oxygen demand (BOD5) and nitrate-nitrite associated with organic matter, and 3) trihalometanes (THMs) as chlorine by-products from the disinfection process. The results showed that the water supply met the required quality standards in most parts of the distribution system but that there are critical points that could increase the risk of recontamination, specifically the geological setting and the critical aspects in irregular urban development in the area of water extraction. Mexico and any other country that relies on groundwater as a drinking water source must review and reinforce the regulations to protect areas with extraction wells and encourage the maintenance of containers to ensure water quality.

Herbicides are used to increase the yield of crops and pastures. The herbicide 2, 4-D has high leaching potential in karstic environments because it is water soluble, which causes that the herbicide has been found in groundwater and submerged caves in the Yucatan Peninsula. We detected the presence of the herbicide in groundwater in agricultural non-agricultural zones in the northeaster of the Yucatán Peninsula by using the UV spectrum obtained from HPLC-DAD as qualitative indicator. This finding supports the notion that application of 2, 4-D before and during the wet season promotes the presence of the herbicide in groundwater.

The hydrogen and oxygen isotopic composition of water is a very important tool to estimate water balance, groundwater recharge, and evaporation. Water isotopes have been used to increase our understanding of the distribution and amounts of renewable and non-renewable groundwater. Isotopic data from precipitation and groundwater is available in much of Mexico but there is little information from the Peninsula of Yucatan, an area heavily relying in groundwater in which current estimates of groundwater availability are uncertain. In this paper, we compiled published and unpublished δ2H and δ18O data in meteoric (waters derived from precipitation), ground- and pore-waters, to obtain a regional meteoric water line (RMWL) expressed by the equation δ2H = 8.1846 δ18O + 10.289. The data suggest that precipitation originates in convective systems, low-pressure events, moisture from frontal events, and from re-condensed moisture. The evaporation lines from groundwater suggest mixing of water with different isotopic composition, but also provide clues to recent meteoric water rapid recharge, likely from rain events of great intensity. We present a groundwater isoscape of the Peninsula of Yucatan and finally address the lack of conciliation between hydrogeology and groundwater management.

Microbial community composition in selected karst groundwater sites in the Yucatan Peninsula, Mexico, was assessed to determine the environmental variables influencing groundwater microbial diversity. The karst aquifer system is a groundwater-dependent ecosystem and is the world’s second largest underwater karst cave system. The area’s geology allows precipitation to infiltrate into the groundwater system and prevents accumulation of surface water; as such, groundwater is the only source of fresh water on the peninsula. The sampling locations consisted of three karst sinkholes that extend through the freshwater zone into the saline water, and an abandoned drinking water well of an ocean-side resort, during the dry and rainy seasons. The analysis showed that highly diverse microbial communities are present in the Yucatan groundwater, sustained by permanently warm temperatures and high nutrient input from human activity. Proximity to densely populated areas, such as tourist resorts, is the most important factor influencing both the diversity and presence of fecal bacteria and the antibiotic resistance profile.

The Yalahau region, located in the northeastern portion of the Yucat&aacute, n Peninsula, hosts a series of elongated depressions trending north/south in the direction of Isla Holbox, identified as the Holbox Fracture Zone. Previous studies have explored the geomorphology and various hydrologic characteristics of the Yucat&aacute, n Peninsula, however, there is a paucity of data concerning the interior region where the fractures are located. Strontium isotope ratios and major ion geochemistry data of the surface water and groundwater of this region serve as a hydrogeochemical fingerprint, aiding in constraining the hydrological boundaries, determining flow paths, and characterizing hydrogeochemical processes that impact the composition of the groundwater within the region. 87Sr/86Sr isotope ratios indicate a different signature than the surrounding bedrock Sr ratio, suggesting that the flow throughout the Yalahau region is moving through channels faster than that of much of the Yucat&aacute, n. Through major ion geochemistry and 87Sr/86Sr isotope ratios, we were able to delineate at least two flow paths within the Yalahau region and identify a point of saline intrusion at least 35 km from the coast. Gaining an understanding of the hydrogeochemistry and water flow regions is crucial in determining the impact of various activities (e.g., extensive tourism, drinking water withdrawal, wastewater discharge/injection) that occur within the Yucat&aacute, n Peninsula.

The Yucatan Peninsula of Mexico hosts a karst aquifer system that is the only source of freshwater for the area; however, it is vulnerable to human-mediated contamination. Pepper mild mottle virus (PMMoV) is one of the most abundant RNA viruses associated with human feces, making it a viable indicator for tracking fecal pollution in aquatic environments, including groundwater. In this study, groundwater samples collected from a karst aquifer from fresh and brackish water locations were analyzed for fecal indicator bacteria, somatic and male F+ specific coliphages, and PMMoV during the rainy and dry seasons. Total coliform bacteria were detected at all sites, whereas Escherichia coli were found at relatively low levels40 MPN/100 ml. The highest average concentrations of somatic and male F+ specific coliphages were 920 and 330 plaque forming units per 100 ml, respectively, detected in freshwater during the rainy season. PMMoV RNA was detected in 85% of the samples with gene sequences sharing 99-100% of nucleotide identity with PMMoV sequences available in GenBank. Quantification of PMMoV genome copies (GC) by quantitative real-time PCR indicated concentrations ranging from 1.7 × 10

Five inorganic geochemical data sets with ion balances less than or equal to 5% (for different hydrogeologic basins in Mexico) were used to construct specific conductance (SC) vs. total dissolved solids (TDS) curves for each aquifer. These curves allow one to proxy the specific conductance for inorganic water quality. The data from these five curves were integrated to form a “global” curve for Mexico. The equation that defines the line is SC = 1.40 TDS + 18. We propose that, in addition to allowing ground water monitoring, establishing a SC vs. TDS curve may be implemented to monitor drinking water supplies such as wells and reservoirs. If anomalously high values are observed, this would warrant detailed geochemical sampling.