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In a global context, trace element pollution assessment in complex multi-aquifer groundwater systems is important, considering the growing concerns about water resource quality and sustainability worldwide. This research addresses multiple objectives by integrating spatial, chemometric, and indexical study approaches, for assessing trace element pollution in the multi-aquifer groundwater system of the Al-Hassa Oasis, Saudi Arabia. Groundwater sampling and analysis followed standard methods. For this purpose, the research employed internationally recognized protocols for groundwater sampling and analysis, including standardized techniques outlined by regulatory bodies such as the United States Environmental Protection Agency (USEPA) and the World Health Organization (WHO). Average values revealed that Cr (0.041) and Fe (2.312) concentrations surpassed the recommended limits for drinking water quality, posing serious threats to groundwater usability by humans. The trace elemental concentrations were ranked as: Li < Mn < Co < As < Mo < Zn < Al < Ba < Se < V < Ni < Cr < Cu < B < Fe < Sr. Various metal(loid) pollution indices, including degree of contamination, heavy metal evaluation index, heavy metal pollution index, and modified heavy metal index, indicated low levels of groundwater pollution. Similarly, low values of water pollution index and weighted arithmetic water quality index were observed for all groundwater points, signifying excellent groundwater quality for drinking and domestic purposes. Spatial distribution analysis showed diverse groundwater quality across the study area, with the eastern and western parts displaying a less desirable quality, while the northern has the best, making water users in the former more vulnerable to potential pollution effects. Thus, the zonation maps hinted the necessity for groundwater quality enhancement from the western to the northern parts. Chemometric analysis identified both human activities and geogenic factors as contributors to groundwater pollution, with human activities found to have more significant impacts. This research provides the scientific basis and insights for protecting the groundwater system and ensuring efficient water management., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

Fluoride and nitrate contamination of groundwater is a major environmental issue in the world's arid and semiarid regions. This issue is severe in both developed and developing countries. This study aimed at assessing the concentration levels, contamination mechanisms, toxicity, and human health risks of NO 3 - in the groundwater within the coastal aquifers of the eastern part of Saudi Arabia using a standard integrated approach. Most of the tested physicochemical properties of the groundwater exceeded their standard limits. The water quality index and synthetic pollution index evaluated the suitability of the groundwater and showed that all the samples have poor and unsuitable quality for drinking. The toxicity of F - in the groundwater within the coastal aquifers of the eastern part of Saudi Arabia using a standard integrated approach. Most of the tested physicochemical properties of the groundwater exceeded their standard limits. The water quality index and synthetic pollution index evaluated the suitability of the groundwater and showed that all the samples have poor and unsuitable quality for drinking. The toxicity of F - was estimated to be higher than NO 3 - . Also, the health risk assessment revealed higher risks due to F - than NO 3 - . Younger populations had higher risks than elderly populations. For both F - and NO 3 . Na-Cl and Ca-Mg-Cl water types predominate in the area. Pearson's correlation analysis, principal component analysis, regression models, and graphical plots were used to determine the possible sources of the water contaminants and their enrichment mechanisms. Geogenic and geochemical processes had greater impact he groundwater chemistry than anthropogenic activities. For the first time, these findings provide public knowledge on the overall water quality of the coastal aquifers and could help the inhabitants, water management authorities, and researchers to identify the groundwater sources that are most desirable for consumption and the human populations that are vulnerable to non-carcinogenic health risks.- , the order of health risk was Infants > Children > Adults. Most of the samples posed medium to high chronic risks due to F - and NO 3 - ingestion. However, negligible health risks were obtained for potential dermal absorption of NO 3 - . Na-Cl and Ca-Mg-Cl water types predominate in the area. Pearson's correlation analysis, principal component analysis, regression models, and graphical plots were used to determine the possible sources of the water contaminants and their enrichment mechanisms. Geogenic and geochemical processes had greater impact he groundwater chemistry than anthropogenic activities. For the first time, these findings provide public knowledge on the overall water quality of the coastal aquifers and could help the inhabitants, water management authorities, and researchers to identify the groundwater sources that are most desirable for consumption and the human populations that are vulnerable to non-carcinogenic health risks., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper, (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The growing increase in groundwater (GW) salinization in the coastal aquifers has reached an alarming socio-economic menace in Saudi Arabia and various places globally due to several natural and anthropogenic activities. Hence, evaluating the GW salinization is paramount to safeguarding the water resources planning and management. This study presents three different scenarios viz.: real field investigation, experimental laboratory analysis (using ion chromatography (IC) and inductively coupled plasma mass spectrometry (ICP-MS), etc.), and artificial intelligence (AI) based metaheuristic optimization (MO) algorithms in Saudi Arabia. The main purpose of this study is to validate the obtained experimental-based analysis using hybrid MO techniques comprising of adaptive neuro-fuzzy inference system (ANFIS) hybridized with genetic algorithm (GA), particle swarm optimization (PSO), and biogeography-based optimization (BBO) for identification of GW salinization in the coastal region of eastern Saudi Arabia. Additionally, ArcGIS 10.3 software generates the prediction map based on ANFIS-GA, ANFIS-PSO, and ANFIS-BBO. Feature selection was assessed using the PSO algorithm, and four indices evaluated the estimated models, namely, root mean square error (RMSE), mean absolute error (MAE), mean absolute percentage error (MAPE), and standard deviation (SD). The simulated results are based on three variable input combinations, which showed that the ANFIS-PSO (MAE = 0.00439) algorithm had the highest accuracy (99 %), followed by the ANFIS-GA (MAE = 0.00767) and ANFIS-BBO (MAE = 0.0132) algorithms. Besides, Ca 2+ , Na + , Mg 2+ , and Cl - were the most influential parameters. The accuracy also demonstrated the potential reliability of MO algorithms based on spatial distribution mapping. The employed approach proved to be merit and reliable tool for water resources decision-makers in the coastal aquifer of Saudi Arabia. This approach is believed to improve water scarcity as one of the essential targets for Goal 6 of Sustainable Development Vision 2030 and the Kingdom in general., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Seawater intrusion (SWI) is the main threat to fresh groundwater (GW) resources in coastal regions worldwide. Early identification and delineation of such threats can help decision-makers plan for suitable management measures to protect water resources for coastal communities. This study assesses seawater intrusion (SWI) and GW salinization of the shallow and deep coastal aquifers in the Al-Qatif area, in the eastern region of Saudi Arabia. Field hydrogeological and hydrochemical investigations coupled with laboratory-based hydrochemical and isotopic analyses ( 18 O and 2 H) were used in this integrated study. Hydrochemical facies diagrams, ionic ratio diagrams, and spatial distribution maps of GW physical and chemical parameters (EC, TDS, Cl - , Br - ), and seawater fraction ( f sw ) were generated to depict the lateral extent of SWI. Hydrochemical facies diagrams were mainly used for GW salinization source identification. The results show that the shallow GW is of brackish and saline types with EC, TDS, Cl - , Br - concentration, and an increasing f sw trend seaward, indicating more influence of SWI on shallow GW wells located close to the shoreline. On the contrary, deep GW shows low f sw and EC, TDS, Cl - , and Br - , indicating less influence of SWI on GW chemistry. Moreover, the shallow GW is enriched in 18 O and 2 H isotopes compared with the deep GW, which reveals mixing with recent water. In conclusion, the reduction in GW abstraction in the central part of the study area raised the average GW level by three meters. Therefore, to protect the deep GW from SWI and salinity pollution, it is recommended to implement such management practices in the entire region. In addition, continuous monitoring of deep GW is recommended to provide decision-makers with sufficient data to plan for the protection of coastal freshwater resources., Competing Interests: The authors declare no conflict of interest.

Global groundwater resources have been threatened by both climate change and anthropogenic activities. Both factors could lead to groundwater depletion that might seriously threaten the living environment and food security. As one of the world's most water-stressed countries, Saudi Arabia has experienced long-term groundwater depletion due to excessive groundwater abstraction to meet the irrigation water demand. Moreover, rainfall and groundwater recharge are considered extremely low in most places in the Kingdom. Hence, a comprehensive assessment of groundwater risk in Saudi Arabia is necessary to avoid a worse scenario. The main objective of this study is to use the composite index to evaluate the groundwater risk in the Arabian Basin in Saudi Arabia. To achieve the objective, multiple variables, such as groundwater storage variations, groundwater reserves, total cropland area, and cropland expansion were integrated. The integration between physical hydrogeological assessment and anthropogenic factors is assumed to be a comprehensive risk measurement. Based on the final score, results demonstrated that Jouf and Najran could be classified as high-risk (17/100) and low-risk areas (71/100), respectively. The groundwater risk status was affected mainly by anthropogenic factors. Results of this study could serve as a diagnostic tool for decision-makers to prioritize and develop sustainable schemes, especially in high-risk areas. [ABSTRACT FROM AUTHOR]

The degradation of groundwater (GW) quality due to seawater intrusion (SWI) is a major water security issue in water-scarce regions. This study aims to delineate the impact of SWI on the GW quality of a multilayered aquifer system in the eastern coastal region of Saudi Arabia. The physical and chemical properties of the GW were determined via field investigations and laboratory analyses. Irrigation indices (electrical conductivity (EC), potential salinity (PS), sodium adsorption ratio (SAR), Na%, Kelly's ratio (KR), magnesium adsorption ratio (MAR), and permeability index (PI)) and a SWI index (fsea) were obtained to assess the suitability of GW for irrigation. K-mean clustering, correlation analysis, and principal component analysis (PCA) were used to determine the relationship between irrigation hazard indices and the degree of SWI. The tested GW samples were grouped into four clusters (C1, C2, C3, and C4), with average SWI degrees of 15%, 8%, 5%, and 2%, respectively. The results showed that the tested GW was unsuitable for irrigation due to salinity hazards. However, a noticeable increase in sodium and magnesium hazards was also observed. Moreover, increasing the degree of SWI (fsea) was associated with increasing salinity, sodium, and magnesium, with higher values observed in the GW samples in cluster C1, followed by clusters C2, C3, and C4. The correlation analysis and PCA results illustrated that the irrigation indices, including EC, PS, SAR, and MAR, were grouped with the SWI index (fsea), indicating the possibility of using them as primary irrigation indices to reflect the impact of SWI on GW quality in coastal regions. The results of this study will help guide decision-makers toward proper management practices for SWI mitigation and enhancing GW quality for irrigation. [ABSTRACT FROM AUTHOR]

Groundwater (GW) is a critical freshwater resource for billions of individuals worldwide. Rapid anthropogenic exploitation has increasingly deteriorated GW quality and quantity. Reliable estimation of complex hydrochemical properties of GW is crucial for sustainable development. Real field and experimental studies in an agricultural area from the significant sandstone aquifers (Wajid Aquifer) were conducted. For the modelling purpose, three types of computational models, including the emerging Hammerstein–Wiener (HW), back propagation neural network (BPNN), and statistical multi-variate regression (MVR), were developed for the multi-station estimation of total dissolved solids (TDS) (mg/L) and total hardness (TH) (mg/L). A geographic information system (GIS) was used for the spatial variability assessment of 32 hydrochemical and physical properties of the GW aquifer. A comprehensive visualized literature review spanning several decades was conducted in order to gain an understanding of the existing research and debates relevant to a particular GW and artificial intelligence (AI) study. The experimental data, pre-processing, and feature selection were conducted to determine the most dominant variables for AI-based modelling. The estimation results were evaluated using determination coefficient (DC), mean bias error (MBE), mean square error (MSE), and root mean square error (RMSE). The outcomes proved that TDS (mg/L) and TH (mg/L) correlated more than 90% and 70–85% with Ca2+, Cl−, Br−, NO3−, and Fe, and Na+, SO42−, Mg2+, and F− combinations, respectively. HW-M1 justified promising among all the models with MBE = 1.41 × 10−11, 1.14 × 10−14, and MSE = 7.52 × 10−2, 3.88 × 10−11 for TDS (mg/L), TH (mg/L), respectively. The accuracy proved merit for the overall development of and practical estimation of hydrochemical variables (TDS, TH) (mg/L) and decision-making benchmarks. [ABSTRACT FROM AUTHOR]