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Your search keyword '"Selva Ganesan Subramaniapillai"' showing total 3 results
Start Over Author "Selva Ganesan Subramaniapillai" Topic green synthesis
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3. Exploring the influence of designer surfactant hydrophobicity in key C[sbnd]C/C[sbnd]N bond forming reactions.

Author

Reddy, Singarajanahalli Mundarinti Krishna, Kothandapani, Jagatheeswaran, Sengan, Megarajan, Veerappan, Anbazhagan, and Selva Ganesan, Subramaniapillai

Subjects
*SURFACE active agents, *ANILINE, *AQUEOUS solutions, *RING formation (Chemistry), *CHAIN length (Chemistry)
Abstract

[Display omitted] • Designer surfactants with C8 to C18 chain length designed, synthesized & studied. • Relationship between product yield, surfactant hydrophobicity and CMC identified • Key Intra/Inter C C & C N bond forming reactions performed. Designer micellar medium was explored for the transformation of diverse anilines to the corresponding densely substituted biologically relevant skatole derivatives in an aqueous medium via 5-exo-trig cyclization reaction. The scope of the reaction was extended to intermolecular Csp2-Csp2 and Csp2-N bond forming reactions in water. Systematic investigations revealed that altering hydrophobicity of surfactant influences the yield of both C C and C N bond forming reactions in water. [ABSTRACT FROM AUTHOR]

Published
2019
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