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Extensive studies have shown that doping can enhance the properties of graphene, but the application to real industrial wastewater treatment and theoretical calculations are limited. In this study, the hybrid nanoadsorbent Cu, N co-doped graphene (Cu@NG) was successfully synthesized via green route using carbon rods from waste dry batteries, human urine and copper nitrate, then multiple characterizations, detailed density functional theory (DFT) theoretical calculations and comprehensive actual wastewater tests are performed in environmental applications to investigate the adsorption properties and mechanism. The results showed that Cu@NG surface is mesoporous, decorated with CuO crystals and doped with N atoms. The isotherms and kinetics were simulated by Langmuir and pseudo-second-order models, respectively. The theoretical maximum sorption for MB and CV on Cu@NG is 116.28 mg·g -1 and CV is 86.96 mg·g -1 , respectively. Pilot tests with Cu@NG on real textile wastewater showed that COD, BOD and color were removed by 54.2%, 55.2% and 86.4%, respectively. The desorption rate of Cu@NG is approximately above 90% for both MB and CV on Cu@NG after six cycles of treatment. The DFT calculations confirmed the experimental results as MB is more reactive than CV molecules. Besides, interactions have been systematically investigated via topology and natural bond orbital (NBO) analyses. The process mechanism involved mainly electrostatic adsorption, π-π stacking interactions and H-bonding interactions and ion exchange., (© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

A facile, feasible, and green synthesis via an electrochemical exfoliation process was applied to synthesize nitrogen-doped MgO/graphene nanocomposite (N-MgO/G). The N-MgO/G nanocomposite was characterized by several analytical techniques including X-ray photoelectron spectroscopy, X-ray powder diffraction, transmission electron microscopy, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, selected area electron diffraction, and elemental mapping analysis. N-MgO/G nanocomposite was then applied to adsorb lead metal ions (Pb 2+ ) from aqueous solutions. The N-MgO/G nanocomposite demonstrated a remarkably high Langmuir maximum adsorption capacity (294.12 mg/g) for Pb 2+ ions under the optimum experimental conditions at a pH of 5.13, time of 35 min, dose of 0.025 g, the concentration of 400 mg/L, and a temperature of 36 °C. Adsorption kinetics results fitted with a pseudo-second-order model and a thermodynamic study showed that Pb 2+ adsorption is an endothermic process. The practical application of N-MgO/G was also investigated to test its applicability in real water samples collected from different sources such as deionized water, tap water, wastewater, and river water.