Search

We present Mo isotope data for molybdenite from the Ekomédion U-Mo prospect, SW Cameroon, a Late Neoproterozoic granite-pegmatite-quartz vein system. Disseminated and veinlet-controlled molybdenite in granite and pegmatitic pods yields a narrow range of δ98Mo values from - 0.06 to + 0.24 ‰, with two overlapping populations of + 0.03 ± 0.07 ‰ (n = 4) in granite, and slightly heavier of + 0.11 ± 0.10 ‰ (n = 5) in pegmatite. By contrast, molybdenite from a quartz-muscovite vein has an isotopically heavy δ98Mo value of + 1.61 ‰. We interpret this trend from granite through pegmatite to vein system towards isotopically heavy Mo to reflect the fractionation of an evolving magmatic-hydrothermal system. Furthermore, the LREE-enriched bulk-rock patterns with largely negative Eu anomalies and the overall enrichment of HREE in zircon indicate plagioclase fractionation as the dominant petrogenetic process during melt evolution. Furthermore, the presence of accessory ilmenite indicates relatively reducing conditions of the melt system, unfavorable for significant Mo accumulation. Therefore, the Ekomédion granite system seems to have limited economic potential for molybdenum despite the advanced degree of magmatic evolution. [ABSTRACT FROM AUTHOR]

Hydrothermally altered granitoids in the Batouri district host gold mineralization. Gold and associated metals occur as disseminated, stockwork and veins. The granitoids range from quartz-alkali granitoids sensu stricto to diorite with various types of wallrock alterations including K-feldspar alteration, sericitization, silicification, and sulphidation/ferruginization. Most gold-bearing samples are extensively brecciated. Gold mineralization is accompanied with sericitization, silicification, and sulphidation/ferruginization alterations. Gold concentrations reach a high of 103.7 ppm. The granitic rocks are sub-alkaline. They show enrichment in the LREE, a negative Eu anomaly and a depletion in the HREE reflecting the breakdown and mobility of the initial plagioclase feldspar bearing HREE during fluid-rock interaction. On multielement variation diagrams, spikes at K, Ba, Pb, and Th are depicted resulting from selective enrichment during alteration. Mass gains/losses during alteration calculated using the immobile element method indicate, amongst others, gains in SiO2 (silicification), K2O (K-feldspar alteration), SO3 and Fe2O3 (sulphidation/ferruginization) with losses in Na2O linked to sericitization. The samples show Pd and Pt as high as 2 ppm. Gold mineralization is associated with wallrock alteration zones with elevated contents of As-Ba-Cu-Pb-Rb-Sr-Zn and Zr due to the neominerals developed during hydrothermal alteration. Au-Ag-Zn defines a potential pathfinder element cluster in the Batouri district. [ABSTRACT FROM AUTHOR]

Lode‐gold mineralization in the Bétaré Oya gold district is related to a series of quartz–sulphide veins that define a steeply dipping NNE–SSW‐trending brittle–ductile shear zone. The veins transect metasedimentary sequences in the vicinity of small granitic intrusions. Quartz veins range from barren (massive quartz) to mineralized with textures that vary from foliated, sheared, vuggy, fractured, and sugary to brecciated with inclusions of altered wall rock. They contain gold, pyrite, and galena in addition to chalcopyrite and both hypogene and supergene haematite and covellite. Parameters that consistently define primary gold mineralization in the area include silicification, sulphidation, sericitization, K‐feldspar alteration, haematitization, and carbonatization. Gold grains recovered from heavy mineral concentrate and grains that occur as inclusions in pyrite were characterized by microchemical methods. The gold grains are zoned and exhibit a simple internal structure of partly deformed and leached rims and high‐purity intragranular veinlets. Gold is alloyed with Ag; gold fineness varies between 859 and 877 in the core and from 958 to 997 in the leached rims. Inclusions of gold in pyrite cluster between 875 and 900. Pyrite has up to 0.59 wt% Au, and other trace elements occur in low quantities but for Pb (0.13 wt%), Ag (1.36 wt%), and Sb (1.63 wt%). The bulk trace element signature of the veins is characterized by Au, Ag, As, Bi, Ba, Cr, Cu, Mn, Pb, Sb, Sr, V, W, Zn, and Zr. This depicts a geochemical association of Au ± Cu ± Bi ± As ± Pb. The occurrence of Au as well as elevated Pb and Zn could suggest a granitic source for the ore‐bearing fluid. The auriferous quartz veins are characterized by a widespread in δ34S from 2.8 to 14.9‰ pointing to multiple sources of sulphur in the system, perhaps a mixture of sulphur from the metasedimentary and the granitic rocks. [ABSTRACT FROM AUTHOR]

The Batouri gold mining area in southeastern Cameroon is part of the Adamawa–Yadé Domain of the Central African Fold Belt (Pan-African). It is underlain by a variety of granitic rocks, including alkali-feldspar granite, syeno-monzogranite, granodiorite, and tonalite. Geochemical data suggest that these rocks formed by differentiation of I-type tonalitic magma under oxidizing conditions in a continental volcanic arc setting. U–Pb dating of zircons from gold-associated monzogranite-granodiorite at Kambélé gave concordant ages of 619 ± 2 and 624 ± 2 Ma, while Ar–Ar dating of alkali-feldspar granite yielded a non-plateau maximum age of 640–620 Ma. These ages imply that the Batouri granitoids were emplaced during the collision of the West African Craton and the Congo Craton. The geochemical characteristics of the Batouri granitoids as well as their oxidized state (magnetite series) are typical of gold-associated felsic rocks in subduction settings elsewhere. The similarities in age, composition, and geochemical affinities of these granitoids with those reported from other localities in the Adamawa–Yadé Domain reinforce the earlier assumption that the granitic rocks of this domain represent parts of a regional-scale batholith, with commonly small-scale, high-grade auriferous quartz veins in structurally favourable sites. The spatial and temporal association of gold mineralization and the Batouri granitoids may suggest potential for regional-scale, high-tonnage, granite-related gold ore. [ABSTRACT FROM AUTHOR]

The Neoproterozoic Pan-African Orogeny in the Adamawa-Yadé domain (AYD) of Cameroon is characterized by intense magmatism of metaluminous to weakly peraluminous I-type granites spatially associated with transcurrent shear zones. This domain provides a critical geological record that is important for unravelling the regional tectonic evolution and geodynamic setting. We present new zircon U-Pb ages and Lu-Hf isotope data from pre-collisional biotite granite and porphyritic K-feldspar granite of the gold-producing Colomine district. Zircon U-Pb ages of biotite granite samples suggest emplacement at 727 ± 8 Ma and at 671 ± 6 for the porphyritic K-feldspar granite. Metamorphic-hydrothermal events between 600 and 550 Ma resulted in Pb-loss of most dated zircons. Lu-Hf isotope data of zircon grains form the porphyritic K-feldspar granite with ϵHf (t) values of −28.7 to −22.6 and T DM c ages of 2.4–2.1 Ga overlap with those of the biotite granite (ϵHf (t) values of −29.4 to −19.6; T DM c ages of 2.5–1.9 Ga). Depleted mantle model ages and ϵHf (t) values suggest that the granites were derived from crustal reworking of older Archean to Paleoproterozoic crust with minor mixing from a juvenile component during the Pan-African. The formation of these pre-collisional granites is interpreted as related to accretion tectonics that started around 750 Ma and incorporating tectonic domains of the Central African Fold belt, namely, the NW Cameroon domain, Mayo-Kebbi domain and the Adamawa-Yade domain. • U–Pb, Lu–Hf isotope data from Colomine zircons presented. • Biotite granites and porphyritic K-feldspar granite were emplacement at ca. 727 ± 8 Ma and ca. 671 ± 6, respectively. • Model Hf ages for the zircons grains ranges from 2.5 to 1.9 Ga. • The granites were derived from crustal reworking of older Paleoproterozoic crust with mixing from a juvenile component. • Accretion tectonics started around 750 Ma incorporating tectonic domains of the Central African Fold belt. [ABSTRACT FROM AUTHOR]

Tin mineralization at Mayo-Darlé in the Cameroon Volcanic Line is associated with highly evolved anorogenic ferroan granite magmatism with a pervasive hydrothermal overprint. Mineralization occurs as cassiterite-quartz-muscovite stockwork and disseminated in quartz-mica and quartz-topaz greisen in low-Ca alkali feldspar granite with a composition near the 1 kbar haplogranitic thermal minimum. The trace element composition of zircon indicates elevated temperature (880 ± 55 °C) and very low oxidation state below the quartz-fayalite-magnetite buffer. Laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) identifies a partly disturbed U-Pb system for igneous zircon (U and Th contents >1000 ppm) but defines Tera-Wasserburg concordia ages and common-lead-corrected weighted 206Pb/238U ages of about 54 Ma, similar to a previous 87Rb/86Sr vs 87Sr/86Sr regression with a date of 56.1 ± 1.7 Ma (MSWD = 58; n = 9) and an initial 87Sr/86Sr ratio of 0.7085 ± 0.0035 (2 s). Hydrothermal cassiterite gives a pooled LA-ICPMS Tera-Wasserburg concordia age of 56.7 ± 0.6 Ma on two samples (each about 20 points, MSWD = 0.54 and 1.3). These new age data define a period of early Cenozoic intraplate calc-alkalic felsic magmatism as a precursor to abundant Oligocene to Recent alkali basalt volcanism along the Cameroon Volcanic Line. Geochemical and Sr–Nd–Hf isotopic data suggest that the granitic rocks from Mayo Darlé were largely derived by partial melting of Mesoproterozoic basement and modified by strong differentiation, all likely powered by heat (and possibly fluids) from the mantle. The Tertiary age of the rare-metal magmatism sets this system apart from the widespread Late Neoproterozoic to Early Paleozoic rare-metal pegmatites and granites in the Pan-African collisional belts of Africa, and also from the anorogenic Mesozoic ring complexes in Central Nigeria. [Display omitted] • Tin mineralization is associated with anorogenic alkali feldspar granite magmatism. • Igneous zircons yield a partially disturbed U-Pb age of 54 Ma. • Zircon trace elements indicate very low oxidation state. • Hydrothermal cassiterite gives a pooled U-Pb concordia age of 56.7 ± 0.6 Ma. • Cassiterite proves to be suitable for U-Pb dating of highly evolved granite systems. [ABSTRACT FROM AUTHOR]