Search

Global groundwater volumes in the upper 2 km of the Earth’s continental crust – critical for water security – are well estimated. Beyond these depths, a vast body of largely saline and non-potable ...

Remotely sensed data and the instruments that acquire them are core parts of Earth and planetary observation systems. They are used to quantify the Earth's interconnected systems, and remote sensing is the only way to get a daily, or more frequent, snapshot of the status of the Earth. It really is the Earth's stethoscope. In a similar manner remote sensing is the rock hammer of the planetary scientist and the only way comprehensive data sets can be acquired. To risk offending many remotely sensed data acquired across the electromagnetic spectrum, it is the tricorder to explore known and unknown planets. Arriving where we are today in the use of remotely sensed data in the solar system has been a continually evolving synergy between Earth observation, planetary exploration, and fundamental laboratory work.

Thirty silicate glasses were synthesized as realistic analogs to those expected to exist on Mars, the Moon, and Mercury. Samples were measured using visible/near-infrared and Mossbauer spectroscopy to determine the effects of varying bulk chemistry, oxygen fugacity, and temperature on spectral properties. For Martian glasses, the fO2 during fusion strongly affects absorption band intensities in the spectra, while bulk chemistry has noticeable secondary effects on absorption band positions. Titanium and iron content drive spectral changes in lunar glasses, where Fe3+ is effectively absent. Iron-free Mercury analog glasses have much higher albedos than all other samples, and their spectral shape is a close match to some pyroclastic deposits on Mercury. Synthetic glass spectra were used as inputs into a spectral unmixing model applied to remote orbital datasets to test for the presence of glass. The model is validated against physical laboratory mixture spectra, as well as previous detections of glass-rich pyroclastic deposits on the Moon. Remote data were then used from suspected impact deposits and possible pyroclastic deposits on Mars as a new application of the model: the results reveal spatially coherent glass-rich material, and the strong spectral match of the synthetic glasses to these remotely sensed data gives new insights into the presence and character of glasses on the Martian surface. The large library of glass spectra generated here, acquired from consistently synthesized and measured samples, can serve as a resource for further studies of volcanic and impact processes on planetary bodies.

We examine the stratigraphic architecture and mineralogy of the western fan deposit in the Jezero crater paleolake on Mars to reassess whether this fan formed as a delta in a standing body of water, as opposed to by alluvial or debris flow processes. Analysis of topography and images reveals that the stratigraphically lowest layers within the fan have shallow dips (

Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite-bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X-ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe3+ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat-lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite-rich host rock formed gypsum-bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars.

Cross crater is a 65 km impact crater, located in the Noachian highlands of the Terra Sirenum region of Mars (30°S, 158°W), which hosts aluminum phyllosilicate deposits first detected by the Observatoire pour la Mineralogie, L’Eau, les Glaces et l’Activitie (OMEGA) imaging spectrometer on Mars Express. Using high-resolution data from the Mars Reconnaissance Orbiter, we examine Cross crater’s basin-filling sedimentary deposits. Visible/shortwave infrared (VSWIR) spectra from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) show absorptions diagnostic of alunite. Combining spectral data with high-resolution images, we map a large (10 km × 5 km) alunite-bearing deposit in southwest Cross crater, widespread kaolin-bearing sediments with variable amounts of alunite that are layered in

The rock alteration and rind formation in analog environments like Antarctica may provide clues to rock alteration and therefore paleoclimates on Mars. Clastic sedimentary rocks derived from basaltic sources have been studied in situ by martian rovers and are likely abundant on the surface of Mars. Moreover, how such rock types undergo alteration when exposed to different environmental conditions is poorly understood compared with alteration of intact basaltic flows. Here we characterize alteration in the chemically immature Carapace Sandstone from Antarctica, a terrestrial analog for martian sedimentary rocks. We employ a variety of measurements similar to those used on previous and current Mars missions. Laboratory techniques included bulk chemistry, powder X-ray diffraction (XRD), hyperspectral imaging and X-ray absorption spectroscopy. Through these methods we find that primary basaltic material in the Carapace Sandstone is pervasively altered to hydrated clay minerals and palagonite as a result of water–rock interaction. A thick orange rind is forming in current Antarctic conditions, superimposing this previous aqueous alteration signature. The rind exhibits a higher reflectance at visible-near infrared wavelengths than the rock interior, with an enhanced ferric absorption edge likely due to an increase in Fe3+ of existing phases or the formation of minor iron (oxy)hydroxides.more » This alteration sequence in the Carapace Sandstone results from decreased water–rock interaction over time, and weathering in a cold, dry environment, mimicking a similar transition early in martian history. This transition may be recorded in sedimentary rocks on Mars through a similar superimposition mechanism, capturing past climate changes at the hand sample scale. These results also suggest that basalt-derived sediments could have sourced significant volumes of hydrated minerals on early Mars due to their greater permeability compared with intact igneous rocks.« less

a b s t r a c t Molecular hydrogen produced through iron oxidation during formation of serpentine and magnetite can sustain terrestrial subsurface ecosystems. The Fe 3+ in serpentine partitions into octahedral and tetrahedral sites differently as serpentinization proceeds, and tetrahedral Fe 3+ is present toward the end of serpentinization. We map Fe oxidation states in a serpentinite to determine the degree to which serpentinization progressed and where hydrogen production has been maximized to assess habitability at an abandoned chrysotile mine in Norbestos, Quebec, in association with the Canadian Space Agency's Mars Methane Analogue Mission. We also analyzed stable isotopes of carbon and oxygen in carbonates to constrain the conditions of water-rock interaction during serpentinization. Iron oxidation and coordination was determined through field imaging of rock walls with a visible hyperspectral imager (420-720 nm), and samples collected from imaged rocks and elsewhere in the mine were imaged in the laboratory (420-1100 nm). Sample chemistry, mineralogy, and oxidation state were determined with laboratory measurements of visible through mid-infrared reflectance spectra, major element chemistry, mineralogy, and Mossbauer spectroscopy. Mapping with hyperspectral imaging of outcrops and hand samples shows that tetrahedral Fe 3+ is common in serpentinites at this site, and results are confirmed through other measurements. Major element chemistry and mineralogy are consistent with serpentine plus minor carbonate. Carbonate samples show an exceptional range in δ 13

We present results from geomorphic mapping and visible to near-infrared spectral analyses of the Jezero crater paleolake basin and its associated watershed. The goal of this study is to understand the provenance of the sedimentary deposits within this open-basin lake using a source-to-sink approach. Two fan deposits located within the basin have distinct visible to near-infrared mineralogic signatures measured by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). The northern fan is spectrally characterized by a mixture of Mg-rich carbonate and olivine, while the western fan is characterized by Fe/Mg-smectite (e.g., saponite or nontronite) with variable amounts of Mg-rich carbonate and olivine in isolated exposures. The watersheds of these deposits contain a variety of geomorphic units that are likely to have supplied sediment to the Jezero crater paleolake, as the fluvial valleys that fed the basin incise these units. The geomorphic units include exposures of Fe/Mg-smectite-, olivine-, and Mg-rich carbonate-bearing terrain. We show that the difference in fan deposit mineralogy is a function of the areal exposure of the major geomorphic units within their watersheds. This indicates that the spectrally dominant aqueous alteration minerals in the fan deposits are primarily detrital, or transported, in nature and did not form in situ. We conclude that the aqueous alteration of the units in the watershed occurred prior to the fluvial activity that carved the valleys of the Jezero crater paleolake system, and that the two periods of aqueous activity are not genetically related.

Recent advancements in visible to near infrared orbital measurements of the lunar surface have allowed the character and extent of the primary anorthositic crust to be studied at unprecedented spatial and spectral resolutions. Here we assess the lunar primary anorthositic crust in global context using a spectral parameter tool for Moon Mineralogy Mapper data to identify and map Fe-bearing crystalline plagioclase based on its diagnostic 1.25 µm absorption band. This allows plagioclase-dominated rocks, specifically anorthosites, to be unambiguously identified as well as distinguished from lithologies with minor to trace amounts of mafic minerals. Low spatial resolution global mosaics and high spatial resolution individual data strips covering more than 650 targeted craters were analyzed to identify and map the mineralogy of spectrally pure regions as small as ~400 m in size. Spectrally, pure plagioclase is identified in approximately 450 targets located across the lunar surface. Diviner thermal infrared (TIR) data are analyzed for 37 of these nearly monomineralic regions in order to understand the compositional variability of plagioclase (An#) in these areas. The average An# for each spectrally pure region is estimated using new laboratory measurements of a well-characterized anorthite (An96) sample. Diviner TIR results suggest that the plagioclase composition across the lunar highlands is relatively uniform, high in calcium content, and consistent with plagioclase compositions found in the ferroan anorthosites (An94–98). Our results confirm that spectrally pure anorthosite is widely distributed across the lunar surface, and most exposures of the ancient anorthositic crust are concentrated in regions of thicker crust surrounding impact basins on the lunar nearside and farside. In addition, the scale of the impact basins and the global nature and distribution of pure plagioclase requires a coherent zone of anorthosite of similar composition in the lunar crust supporting its formation from a single differentiation event like a magma ocean. Our identifications of pure anorthosite combined with the GRAIL crustal thickness model suggest that pure anorthosite is currently observed at a range of crustal thickness values between 9 and 63 km and that the primary anorthositic crust must have been at least 30 km thick.

The investigation of hyperspectral data from the Mars Reconnaissance Orbiter Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) and the Observatoire pour la Minéralogie, L'Eau, les Glaces et l'Activitié (OMEGA) on Mars Express has revealed an increasingly diverse suite of minerals present on the Martian surface. A revised set of 60 spectral parameters derived from corrected spectral reflectance at key wavelengths in CRISM targeted observations and designed to capture the known diversity of surface mineralogy on Mars is presented here as “summary products.” Some of the summary products have strong heritage to OMEGA spectral parameter calculations; this paper also presents newly derived parameters that highlight locations with more recently discovered spectral signatures. Type locations for the diversity of currently identified mineral spectral signatures have been compiled into a library presented in this work. Our analysis indicates that the revised set of summary products captures the known spectral diversity of the surface, and successfully highlights and differentiates between locations with differing spectral signatures. The revised spectral parameter calculations and related products provide a useful tool for scientific interpretation and for future mission landing site selection and operations.

[1] The igneous evolution of Mars is well represented in stratigraphic settings that transition across major time stratigraphic boundaries. Here we analyze in detail the morphology and composition, determined through visible–near-infrared spectroscopy, of igneous volcanic terrains in Ares Vallis, Mars. Upland plateau units with crater-filling volcanic plains are of Noachian age; smooth units to the west and north of the mouth of Ares Vallis have been mapped as Hesperian in age. The age and origin of the units that comprise the floor of Ares Vallis, connecting the upland plateau units and the smooth units to the west and north of the mouth of Ares Vallis, is less certain due to the small area available for crater counting. The mafic mineral compositions of these units are well resolved with OMEGA (Observatoire pour la Mineralogie, l'Eau, les Glaces et l'Activite) and CRISM (Compact Reconnaissance Imaging Spectrometer for Mars) data. The data show that the Noachian volcanic units are distinctly olivine-rich, while the plains units to the west and the floor of Ares Vallis volcanics show diagnostic absorptions of olivine-pyroxene, typical of Hesperian volcanics elsewhere on Mars. Based on these findings, we propose there has been a change in the temperature and/or degree of partial melting in the mantle over time for this region of Mars.

[1] There is ample evidence of both ancient and long-lasting fluvial activity and chemical alteration in the Libya Montes region south of Isidis Basin. The region hosts Noachian to Amazonian aged surface rocks with extensive outcrops of olivine- and pyroxene-bearing material. Libya Montes also features surface outcrops and/or deposits hosting Fe/Mg-smectite, Fe/Mg-smectite mixed with carbonate and/or other Fe/Mg-rich phyllosilicates, and Al-smectite. These units likely formed through chemical alteration connected with hydrothermal activity resulting from the formation of the Isidis Basin and/or the pervasive fluvial activity throughout this region. The morphology and stratigraphy of the aqueous and mafic minerals are described using High Resolution Imaging Science Experiment and High Resolution Stereo Camera derived digital terrain models. Analyses of the Compact Reconnaissance Imaging Spectrometer for Mars spectra show variations in the chemistry of the Fe/Mg-smectite from nontronite-like exposures with spectral features near 2.29 and 2.4 µm more consistent with Fe3+2OH groups in the mineral structure, and saponite-like outcrops with spectral features near 2.31 and 2.38 µm characteristic of Mg2+3OH groups. These Fe/Mg-smectite bearing materials also have bands near 1.9 µm due to H2O and near 2.5 µm that could be due to the smectite, other phyllosilicates, and carbonates. All regions exhibiting carbonate features near 3.4–3.5 µm also have features consistent with the presence of olivine and Fe/Mg-smectite, indicating that the carbonate signatures occur in rocks likely containing a mixture of these minerals. The Al-smectite-bearing rocks have bands near 1.41, 1.91, and 2.19 µm that are more consistent with beidellite than other Al-phyllosilicates, indicating a higher-temperature or diagenetically processed origin for this material. Our interpretation of the geologic history of this region is that ancient Noachian basaltic crustal materials experienced extensive aqueous alteration at the time of the Isidis impact, during which the montes were also formed, followed by emplacement of a rough olivine-rich lava or melt, and finally the smooth pyroxene-bearing caprock unit.

[1] High-resolution images from Chandrayaan-1 Terrain Mapping Camera and Lunar Reconnaissance Orbiter Camera reveal landslides and gully formation on the interior wall of a 7 km-diameter simple crater emplaced in Schrodinger basin on the farside of the Moon. These features occur on the steep upper crater wall, where the slope is ~35°. The gullies show a typical alcove-channel-fan morphology. Some gullies incise bedrock, where impact-related faults are present. Slope failure along the concentric faults also led to formation of landslides. Dark slope streaks are abundant at the bright gully regions, especially near the fan and channel deposits. Spectral characteristics inferred from data obtained by Hyperspectral Imager and Moon Mineralogy Mapper on board Chandrayaan-1 show that the gullies and landslides are characterized by high optical immaturity and devoid of prominent spectral absorption features related to water or hydroxyl molecules, suggesting youthful dry-granular flows. Mass movements on the crater wall led to the formation of arcuate ridges and ponding of fine-grained sediments on the crater floor. Runout flows from small impact craters on the slopes indicate that impact-induced seismic shaking was responsible for the downslope mass movements. Crater size-frequency distributions suggest a minimum age of 18–2 Ma for the gullies and 2 Ma for the landslides, while age of the host crater ejecta was inferred to be about 175 Ma. The gullies and landslides also occur on the interior wall of other impact craters elsewhere on the Moon and probably formed by similar processes.

[1] We have undertaken high-resolution mapping of the distribution, physical characteristics, orientation, and stratigraphic occurrence of >4000 linear ridge segments in two study areas, the Nilosyrtis highlands and the Nili Fossae region covering 1 × 105 km2. Ridges are typically hundreds of meters in length, meters in width, and up to tens of meters in height. Ridges form intersecting networks of anastomosing and bifurcating segments and consequently have variable orientations. Ridges are expressed in altered and brecciated basement materials on the floors and rims of impact craters deeply eroded by fluvial and other processes. The ridge-bearing basement is the lowest exposed stratigraphic unit and is overlain by a relatively unaltered mafic cap rock. Ridges are observed to terminate at the contact of these two units. We interpret the ridges to represent a complex of fractures, faults, shear zones, clastic and melt-bearing dikes, and pseudotachylytes that have been variably indurated by fluid percolation and mineralization. The fluid conduits were hardened relative to the host rock and are expressed as ridges due to differential erosion. The orientations of the exhumed ridges record the state of stress in the crust at the time of formation. In Nili Fossae, a significant population of ridges is aligned with the orientations of the Nili Fossae graben, indicating that their emplacement may be related to crustal loading of the Isidis Basin after the impact event. The association of ridges with the hydrated mineral-bearing basement suggests that, in the postimpact environment, the fractures served as conduits of preferential fluid flow, which were cemented by mineral precipitation.

The mineralogical composition of the Martian surface is investigated by a Multiple-Endmember Linear Spectral Unmixing Model (MELSUM) of the Observatoire pour la Mineralogie, l’Eau, les Glaces et l’Activite (OMEGA) imaging spectrometer onboard Mars Express. OMEGA has fully covered the surface of the red planet at medium to low resolution (2–4 km per pixel). Several areas have been imaged at a resolution up to 300 m per pixel. One difficulty in the data processing is to extract the mineralogical composition, since rocks are mixtures of several components. MELSUM is an algorithm that selects the best linear combination of spectra among the families of minerals available in a reference library. The best fit of the observed spectrum on each pixel is calculated by the same unmixing equation used in the classical Spectral Mixture Analysis (SMA). This study shows the importance of the choice of the input library, which contains in our case 24 laboratory spectra (endmembers) of minerals that cover the diversity of the mineral families that may be found on the Martian surface. The analysis is restricted to the 1.0–2.5 μm wavelength range. Grain size variations and atmospheric scattering by aerosols induce changes in overall albedo level and continuum slopes. Synthetic flat and pure slope spectra have therefore been included in the input mineral spectral endmembers library in order to take these effects into account. The selection process for the endmembers is a systematic exploration of whole set of combinations of four components plus the straight line spectra. When negative coefficients occur, the results are discarded. This strategy is successfully tested on the terrestrial Cuprite site (Nevada, USA), for which extensive ground observations exist. It is then applied to different areas on Mars including Syrtis Major, Aram Chaos and Olympia Undae near the North Polar Cap. MELSUM on Syrtis Major reveals a region dominated by mafic minerals, with the oldest crustal regions composed of a mixing between low-calcium pyroxenes (LCPs) (orthopyroxenes (OPx)) and high-calcium pyroxenes (HCPs) (clinopyroxenes (CPx)). The Syrtis volcanic edifice appears depleted in LCP (OPx) and enriched in HCP (CPx), which is consistent with materials produced with a lower partial fusion degree at an age younger to the surrounding crust. Strong olivine signatures are found between the two calderas Nili Patera and Meroe Patera and in Nili Fossae. A strong signature of iron oxides is found within Aram Chaos, with a spatial distribution also consistent with thermal emission spectrometer (TES). Gypsum is unambiguously detected in the northern polar region, in agreement with the study of Langevin et al. [2005. Sulfates in the north polar region of Mars detected by OMEGA/Mars Express. Science 307(5715), 1584–1586]. Our results show that the linear spectral unmixing provides good first order results in a variety of mineralogical contexts, and can therefore confidently be used on a wider scale to analyze the complete archive of OMEGA data.

Spectroscopic studies of analog terrestrial mineral assemblages are necessary to develop criteria to identify similar environments on Mars. We use visible/near infrared (VNIR) laboratory, field, and remotely acquired spectral data to identify the iron-bearing and hydrous minerals of Rio Tinto, Spain, an astrobiological analog. Mineralogy evolves from iron sulfate- and oxide-rich (jarosite, rozenite, gypsum, schwertmannite, copiapite, goethite, and hematite assemblages) in young sediments to hydrated iron oxides in preserved terraces. Using spectra from the Rio Tinto, we examine one of the key challenges of extraterrestrial exploration: how to identify promising targets from spatially coarse data for in situ investigation. We apply an index to quantify the expression of spectral diversity as a function of spatial scale from hand sample to landscape. To validate this method for use at the decimeter orbital scale, we apply the index to cm-scale point spectra and meter-scale gridded spectra collected in the field. This exercise in spatial scaling gives increased confidence in the ability of the Spectral Variance Index (SVI) method to locate regions with increased mineral diversity from remotely sensed data. We divide the remotely sensed data into 25 × 25 pixel (200 m × 200 m) cells and calculate the average mean (albedo) and spectral variance over all wavelengths for each cell. We next calculate the expected variance for each cell with a linear regression between mean and spectral variance. The number of standard deviations of each cell's spectral variance is from the expected variance is the SVI value. We locate ∼ 20 areas with high SVI values within the tailing piles and along wide riverbanks downstream of the active mine. This method uses spatially coarse VNIR spectra to recognize areas in Rio Tinto that would be ideal targets for future field exploration, and could also be applied to Mars orbital spectral datasets, such as OMEGA and CRISM.

Environmental conditions on Mars are conducive to the modification and erosion of impact craters, potentially revealing the nature of their substructure. On Earth, postimpact erosion of complex craters in a wide range of target rocks has revealed the nature and distribution of crater-related fault structures and a complex array of breccia and pseudotachylyte dikes, which range up to tens of meters in width and tens of kilometers in length. We review the characteristics of fault structures, breccia dikes, and pseudotachylyte dikes on Earth, showing that they occur in complex network-like patterns and are often offset along late-stage crater-related faults. Individual faults and dikes can undulate in width and can branch and bifurcate along strike. Detailed geological analyses of terrestrial craters show that faults and breccia dikes form during each of the major stages of the impact-cratering process (compression, excavation, and modification). We report here on the discovery of prominent, lattice-like ridge networks occurring on the floor of a highly modified impact crater 75 km in diameter near the dichotomy boundary of the northern lowland and southern upland. Interior fill and crater-floor units have been exhumed by fluvial and eolian processes to reveal a unit below the crater floor containing a distinctive set of linear ridges of broadly similar width and forming a lattice-like pattern. Ridge exposures range from ~1-4 km in length and ~65-120 m in width, are broadly parallel, straight to slightly curving, and are cross-cut by near-orthogonal ridges, forming a box or lattice-like pattern. Ridges are exposed on the exhumed crater floor, extending from the base of the wall toward the center. On the basis of the strong similarities of these features to terrestrial crater-related fault structures and breccia dikes, we interpret these ridges to be faults and breccia dikes formed below the floor of the crater during the excavation and modification stages of the impact event, and subsequently exhumed by erosion. The recognition of such features on Mars will help in documenting the nature of impact-cratering processes and aid in assessment of crustal structure. Faults and breccia dikes can also be used as data for the assessment of post-cratering depths and degrees of landform exhumation.

IRMA (the acronym stands for InfraRed Microscope Analysis) is a hyperspectral imaging spectrometer which is capable, in its present design, to achieve a spatial resolution of 38 μm in the 0.8–5 μm infrared spectral range. IRMA has the goal to first ever quantitatively characterize the mineralogy and the microphysical structure of the materials of the Martian soils and rocks down to the depth available to a lander sampling mechanism. The experiment has been selected by the Italian Space Agency (ASI), in the framework of the Italian participation to the NASA's Mars Surveyor Programme, to be part of the Italian Package for Scientific Experiments (IPSE). IPSE was to fly on-board the ill-fated MARS2003 MARS SAMPLE RETURN Mission, postponed during the early months of 2000 to a later date (possibly 2007). IRMA present state of development is compatible with a flight readiness in 2007. IPSE is a small laboratory devoted to the analysis of in situ collected samples of rock and soil of Martian material. Details on IPSE are given in a paper in this same journal issue. IRMA will provide detailed information on: • texture, habit and microphysical properties of the grains and particulates of the Martian soil as well as the petrography of Martian rocks, with a spatial resolution of the order of the tens of micron. • Mineralogical composition and relative mineral abundances of the rocks and soils, with a relative accuracy of the order of 1%. A Signal to Noise Ratio of at least 100 shall be required to achieve this goal IRMA measurements shall provide essential contributions to the understanding of outstanding scientific issues such as the history of water and other volatiles, e.g., CO2, the role of physical and chemical weathering in the past and present day Mars and hence the assessment of the environmental conditions present on the martian surface throughout its history.

Observations of mixing across mare-highland contacts using high-resolution Clementine data allow a new assessment of the relative importance of vertical versus lateral mass transport on the Moon at least at mare-highland contact. We analyze mare-highland contacts in the Grimaldi, Orientale, and Fecunditatis basins and Tsiolkovsky crater through image-based nonlinear spectral mixture modeling of Clementine ultraviolet-visible (UV-VIS) light spectrometer multi-spectral data. The mare in these regions differ in ages, but they are characterized by having simple geological contacts. The symmetric distribution of mare and highland soil constituents across their geological contact indicates that lateral transport is more efficient than deep vertical transport during the formation of the observed mixing zones. Observations across the lunar limb with the Clementine UV-VIS filters show that there is a stray light component of scattered light across high-contrast albedo boundaries. However, the magnitude and spatial properties of scattered light do not significantly affect the nature of compositional boundaries determined here. Since repetitive meteorite bombardment governs lateral transport across the geological contacts and is a random process, a stochastic model is developed to describe this lateral transport. Analysis of the power decay law for crater ejecta thickness indicates that the high-velocity ejecta travels long distances and follows a −3 power decay law. This results in an infinite variance, which requires an anomalous diffusion model since a classical diffusion model would be invalid. Mathematical modeling supports this result where it is shown that classical diffusion produces a relatively poor fit to profiles of material abundance, while the anomalous diffusion model fits the profiles adequately. These results indicate that high-velocity ejecta dominates the formation of the observed compositional gradients, while the ejecta near the crater rim is relatively less important. On the basis of these ejecta distributions and the assumption of random impact cratering, we derive a relationship that can be used as an index for relative age dating of geological contacts as well as for investigating cratering rates.

Linear and nonlinear spectral mixture models applied to Clementine multispectral images of the Moon result in roughly similar spatial distributions of endmember abundances. However, there are important differences in the absolute values of the predicted abundances. The magnitude of these differences and the implications for understanding geological processes are investigated across a geologic contact between mare and highland in the Grimaldi Basin on the western nearside of the Moon. Vertical and lateral mass transport due to impact cratering has redistributed mare and highland materials across the contact, creating a gradient in composition. Solutions to linear and nonlinear spectral mixture models for identical spectral endmembers of mare, highland, and fresh crater materials are compared across this simple geologic contact in the Grimaldi Basin. Profiles of mare abundance across the contact are extracted and compared quantitatively. Profiles from the linear mixture models indicate that the geologic contact has an average mare abundance of 60%, and the compositional boundary is asymmetric with more mare transported onto the highland side of the contact than highland onto the mare side of the contact. In contrast the nonlinear abundance profiles indicate that the geologic contact has an average mare abundance of 50%, and the compositional boundary is remarkably symmetric. Given the expectation that materials will be intimately mixed on the surface of the Moon, and that the asymmetries implied by the linear model are not consistent with our understanding of lunar surface processes, the nonlinear spectral mixture model is preferred and should be applied whenever quantitative abundance information is required. The remarkable symmetry in the compositional gradients across this contact indicate that lateral mass transport dominates over vertical transport at this boundary.

— Spectroscopic measurement and analysis of Martian meteorites provide important information about the mineralogy of Mars, as well as necessary ground-truths for deconvolving remote sensing spectra of the Martian surface rocks. The spectroscopic properties of particulate ALH 84001 from 0.3 to 25 μm correctly identify low-Ca pyroxene as the dominant mineralogy. Absorption bands due to electronic transitions of ferrous iron are observed at 0.94 and 1.97 μm that are typical for low-Ca pyroxene. A strong, broad water band is observed near 3 μm that is characteristic of the water band typically associated with pyroxenes. Weaker features near 4.8, 5.2 and 6.2 μm are characteristic of particulate low-Ca pyroxene and can be distinguished readily from the features due to high-Ca pyroxene and other silicate minerals. The reflectance minimum occurs near 8.6 μm for the ALH 84001 powder, which is more consistent with high-Ca pyroxene and augite than low-Ca pyroxene. The dominant mid-infrared (IR) spectral features for the ALH 84001 powder are observed near 9 and 19.5 μm; however, there are multiple features in this region. These mid-IR features are generally characteristic of low-Ca pyroxene but cannot be explained by low-Ca pyroxene alone. Spectral features from 2.5–5 μm are typically associated with water, organics and carbonates and have been studied in spectra of the ALH 84001, split 92 powder and ALH 84001, splits 92 and 271 chip surfaces. Weak features have been identified near 3.5 and 4 μm that are assigned to organic material and carbonates. Another feature is observed at 4.27 μm in many surface spots and in the powder but has not yet been uniquely identified. Spectroscopic identification of minor organic and carbonate components in this probable piece of Mars suggests that detection of small amounts of organics and carbonates in the Martian surface regolith would also be possible using visible-infrared hyperspectral analyses. Laboratory spectroscopic analysis of Martian meteorites provides a unique opportunity to identify the spectral features of minerals and other components while they are embedded in their natural medium.

— Reflectance spectra of splits 92 and 271 from the Martian meteorite Allan Hills (ALH) 84001 are presented and analyzed in this paper. Although the visible and infrared spectra of both chips show that the dominant mineralogy is low-Ca pyroxene, the focus here is on identification of the minor constituents. Infrared spectra measured at multiple spots along the surface of chips 92 and 271 show subtle spectroscopic variations due to changes in the low-Ca pyroxene texture and composition and to the presence of secondary minerals. Absorption bands observed near 0.93 and 1.95 μm are characteristic of low-Ca pyroxene. Strong mid-infrared reststrahlen bands are observed near 9 and 19.5 μm in all surface spectra, and additional bands near 7, 10.5, 11.4, 17.8, 20.5 and 23 μm are variable depending on the low-Ca pyroxene texture and the presence of secondary minerals. Selected spectra exhibit carbonate features near 4, 6.4–7.1 and 11.3 μm. Detailed analysis of these carbonate features indicates the presence of Mg-Fe carbonate, which is consistent with petrographic studies. Many of these spectra with strong carbonate features exhibit a magnetite feature near 17.9 μm and a shoulder near 20.5 μm that cannot be uniquely ascribed to one mineral. Spectroscopic identification of the minor carbonate and magnetite minerals in this probable piece of Mars indicates that detection of small amounts of these minerals of possible biological significance will be possible using infrared hyperspectral analyses of the Martian surface. Also of importance for remote sensing on Mars is the result that Mg, Fe and Mg-Fe carbonates in a low-Ca pyroxene matrix should be distinguishable from one another in the spectral region measured by the thermal emmitance spectrometer (TES).

The primary objective of this analysis is to determine the mineralogic composition of relatively pristine terrains exposed on the surface of Mars. This analysis is conducted using imaging spectrometer data acquired in 1989 by the Imaging Spectrometer for Mars (ISM) instrument that was onboard the Phobos-II spacecraft. The ISM instrument acquired some of the highest spectral (64 channels between 0.77 and 3.14 μm) and spatial resolution (≈22 km/pixel) observations to date of Mars, focused on the equatorial region. Relatively unaltered surfaces were identified in these data on the basis of their spectral properties (low albedo, weak spectral slope, absence of ferric absorptions), and were found in volcanic terrains of Syrtis Major, Valles Marineris, Ophir Planum, and Sinus Meridiani/Oxia Palus. Spectra representative of the diversity among terrains were extracted for detailed analysis using the Modified Gaussian Model to determine the primary mafic mineralogy, It was determined that the mafic mineralogy of the regions investigated is dominated by low-calcium and high-calcium pyroxene (LCP, HCP), and that there was homogeneity within a given region but some heterogeneity between regions in the relative abundance of LCP to HCP. The two-pyroxene mineralogy is consistent with the mineralogies of the basaltic SNC meteorites believed to have originated on Mars. Two-pyroxene volcanic mineralogies are indicative of large degrees of partial melting (e.g., komatiites) or a mantle source depleted in aluminum. Integration of these findings with previous studies of Mars and the SNC meteorites indicates that (1) the SNC mineralogies are representative of large volcanic regions of Mars with surface ages as old as 2–3 Ga, (2) the martian mantle was depleted in aluminum at least as long ago as the oldest terrain analyzed (Ophir Planum), and (3) there has been little evolution in the composition of mantle source regions as the 180 Ma SNC mineralogies are comparable to those of the oldest terrains analyzed.

The composition of mare-highland boundaries is investigated in the region of southwestern Oceanus Procellarum using multispectral images from the Galileo solid-state imaging system. The data are analyzed using a linear image-based spectral mixture model to map the distribution and abundance of spectral end-members representing mare basalt, mature highland soils, and fresh crater materials. The fraction images that result from the mixture modeling are then integrated into a geographic information system database to analyze the relationship between the compositional gradients and regional geologic and geomorphic units. Within this framework, three basic types of mixing gradients are recognized: narrow mixing zones, broad mixing zones, and complex mixing zones. The narrow zones appear to be the result of simple postformation lateral mass transport of surface materials due to the time-averaged effects of impact cratering and regolith gardening. The broad or moderate mixing zones exhibit evidence for significant incorporation of basalt into the distal basin ejecta of Orientale, and thus are interpreted to indicate that pre-Orientale volcanism and volcanic deposits were widespread in the Procellarum region. This is further corroborated by the mare-rich ejecta blanket observed for the 100-km-diameter impact crater Letronne. The complex mixing zones show evidence for extensive pre-Orientale, and perhaps pre-Imbrium cryptomare, as well as some volcanism extending into the late Imbrian period. These results indicate that mare-highland boundaries frequently contain a convolved geologic record that allows insight into the geologic events prior to the final one apparently recorded by surface deposits. For this region of the Moon, we now recognize that volcanism was well established and widespread in early Imbrian time but had become more focused to a few major volcanic regions (Humorum, Procellarum) by the late Imbrian.

[1] Abundant evidence exists for valley network-related fluvial activity near the Noachian-Hesperian transition on Mars, and areally significant quantities of volcanic ridged plains were emplaced during this period as well. Thus, it is worthwhile to explore the hypothesis that lava-water interaction occurred on the surface of Mars at this time. We analyzed the morphology, physical properties, composition, and surface ages of thirty open-basin lakes (topographic lows with both an inlet valley and an outlet valley) that were also resurfaced by volcanic flows. Hyperspectral imaging data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) and Observatoire pour la Mineralogie, l'Eau, les Glaces et l'Activite (OMEGA) instruments indicate that of the 30 basins, 12 exhibit the spectral properties of basaltic lithologies with diagnostic absorptions of olivine, high-calcium pyroxene and low-calcium pyroxene. An olivine/high-calcium pyroxene mixture is the most commonly identified mineral assemblage, consistent with other Hesperian-aged volcanic units. Therefore, our mineralogical results for over a third of the open-basin lake floors analyzed support prior interpretations that the basins were resurfaced by volcanic flows. Supporting evidence for resurfacing by volcanic flows is also given by the observed morphology and physical properties (e.g., surface roughness, thermal inertia) of the resurfaced open-basin lake floors. In these 30 examples, however, no evidence was found for lava-water interaction. The ages of emplacement, derived through counts of superposed craters, of all 30 of the open-basin lake volcanic resurfacing units show that resurfacing began in the Late Noachian, near the Noachian-Hesperian boundary, was concentrated in the Hesperian, and continued into the Early Amazonian. The lack of geologic features indicative of lava-water interaction suggests that the basins were likely to have been mostly devoid of water at the time of the latest phase of volcanic resurfacing. We conclude that there is no geologic evidence that suggests the fluvial activity associated with the studied paleolakes was coeval with the emplacement of the observed volcanic resurfacing units, several of which date to the Late Noachian-Early Hesperian.

Lacking plate tectonics and crustal recycling, the long-term evolution of the crust-mantle system of Mars is driven by mantle convection, partial melting, and silicate differentiation. Volcanic landforms such as lava flows, shield volcanoes, volcanic cones, pyroclastic deposits, and dikes are observed on the martian surface, and while activity was widespread during the late Noachian and Hesperian, volcanism became more and more restricted to the Tharsis and Elysium provinces in the Amazonian period. Martian igneous rocks are predominantly basaltic in composition, and remote sensing data, in-situ data, and analysis of the SNC meteorites indicate that magma source regions were located at depths between 80 and 150 km, with degrees of partial melting ranging from 5 to 15 %. Furthermore, magma storage at depth appears to be of limited importance, and secular cooling rates of 30 to 40 K Gyr−1 were derived from surface chemistry for the Hesperian and Amazonian periods. These estimates are in general agreement with numerical models of the thermo-chemical evolution of Mars, which predict source region depths of 100 to 200 km, degrees of partial melting between 5 and 20 %, and secular cooling rates of 40 to 50 K Gyr−1. In addition, these model predictions largely agree with elastic lithosphere thickness estimates derived from gravity and topography data. Major unknowns related to the evolution of the crust-mantle system are the age of the shergottites, the planet’s initial bulk mantle water content, and its average crustal thickness. Analysis of the SNC meteorites, estimates of the elastic lithosphere thickness, as well as the fact that tidal dissipation takes place in the martian mantle indicate that rheologically significant amounts of water of a few tens of ppm are still present in the interior. However, the exact amount is controversial and estimates range from only a few to more than 200 ppm. Owing to the uncertain formation age of the shergottites it is unclear whether these water contents correspond to the ancient or present mantle. It therefore remains to be investigated whether petrologically significant amounts of water of more than 100 ppm are or have been present in the deep interior. Although models suggest that about 50 % of the incompatible species (H2O, K, Th, U) have been removed from the mantle, the amount of mantle differentiation remains uncertain because the average crustal thickness is merely constrained to within a factor of two.

[1] The earliest formed crust on a single plate planet such as Mars should be preserved, deeply buried under subsequent surface materials. Mars' extensive cratering history would have fractured and disrupted the upper layers of this ancient crust. Large impacts occurring late in Martian geologic history would have excavated and exposed this deeply buried material. We report the compositional analysis of unaltered mafic Martian crater central peaks with high-resolution spectral data that was used to characterize the presence, distribution and composition of mafic mineralogy. Reflectance spectra of mafic outcrops are modeled with the Modified Gaussian Model (MGM) to determine cation composition of olivine and pyroxene mineral deposits. Observations show that central peaks with unaltered mafic units are only observed in four general regions of Mars. Each mafic unit exhibits spectrally unmixed outcrops of olivine or pyroxene, indicating dunite and pyroxenite dominated compositions instead of basaltic composition common throughout much of the planet. Compositional analysis shows a wide range of olivine Fo# ranging from Fo60 to Fo5. This variation is best explained by a high degree of fractionation in a slowly cooling, differentiating magma body. Pyroxene analysis shows that all the sites in the Southern Highlands are consistent with moderately Fe-rich, low-Ca pyroxene. Mineral segregation in the ancient crust could be caused by cumulate crystallization and settling in a large, potentially global, lava lake or near surface plutons driven by a hypothesized early Martian mantle overturn.

We used a suite of techniques, including those emulating compositional data sets obtained from Mars orbit and obtainable at the Mars surface, to examine aqueous alteration of basaltic rocks from Iceland as a mineralogic and geochemical analog for Noachian environments on Mars. A sample suite was collected for laboratory measurement of (1) whole-rock visible/near-infrared (VNIR) reflectance and thermal infrared (TIR) emission spectra; (2) VNIR and TIR reflectance spectra of particle-size separates derived from the bulk rock and from materials extracted from fractures/vesicles; (3) X-ray diffraction (XRD) patterns for determination of quantitative modal mineralogy; (4) major element chemistry using flux fusion of whole-rock powders; and (5) electron microprobe analyses of minerals in thin sections. Conclusions about aqueous alteration can be influenced by technique. For these basalts, whole-rock chemical data showed scant evidence for chemical fractionation, but TIR, VNIR, and XRD measurements identified distinctive assemblages of hydrous silicate minerals, differing by sample. XRD provided the most complete and accurate quantitative determination of sample mineralogy. However, VNIR spectroscopy was the technique most useful for determining composition of low-abundance smectite clays, and TIR spectroscopy was the most useful for recognizing hydrated silicates in thin surface coatings. High spatial resolution mineralogical and chemical data sets were useful for understanding the texture and distribution of alteration products and variations in fluid chemistry. No single approach provides a complete assessment of the environment of alteration, demonstrating the importance of employing multiple, synergistic mineralogical and geochemical techniques and instruments in exploration of rock strata from aqueous paleoenvironments on Mars.

Spectra of basalt samples were dominated by Fe 2+ crystal field transitions with weak alteration bands near 1.4 and/or 1.9 mm. Reststrahlen bands in mid-infrared showed the convolution of plagioclase and pyroxene features typical of basalts. Saprolite samples were incompletely leached, and their spectra were dominated by complex Al- and Fe/Mg-bearing smectite clays and retained no original mafic signatures. XRD and Mossbauer detected pyroxene and plagioclase not visible by reflectance spectroscopy in some saprolite samples. Zeolites were present throughout the saprolite. The laterite was the most leached horizon, and all analyses showed kaolinite and iron oxide assemblages. This kaolinite and hematite association would be expected if kaolinite on Mars formed through leaching under conditions similar to those on Earth and has implications for abundant freshwater on the Martian surface.

[1] Changes of vegetation phenology in response to climate change in the temperate forests have been well documented recently and have important implications on the regional and global carbon and water cycles. Predicting the impact of changing phenology on terrestrial ecosystems requires an accurate phenology model. Although species-level phenology models have been tested using a small number of vegetation species, they are rarely examined at the regional level. In this study, we used remotely sensed phenology and meteorological data to parameterize the species-level phenology models. We used a remotely sensed vegetation index (Two-band Enhanced Vegetation Index, EVI2) derived from the Moderate Resolution Spectroradiometer (MODIS) 8-day reflectance product from 2000 to 2010 of New England, United States to calculate remotely sensed vegetation phenology (start/end of season, or SOS/EOS). The SOS/EOS and the daily mean air temperature data from weather stations were used to parameterize three budburst models and one senescence model. We compared the relative strengths of the models to predict vegetation phenology and selected the best model to reconstruct the “landscape phenology” in New England from year 1960 to 2010. Of the three budburst models tested, the spring warming model showed the best performance with an averaged Root Mean Square Deviation (RMSD) of 4.59 days. The Akaike Information Criterion supported the spring warming model in all the weather stations. For senescence modeling, the Delpierre model was better than a null model (the averaged phenology of each weather station, averaged model efficiency = 0.33) and has a RMSD of 8.05 days. A retrospective analysis using the spring warming model suggests a statistically significant advance of SOS in New England from 1960 to 2010 averaged as 0.143 days per year (p = 0.015). EOS calculated using the Delpierre model and growing season length showed no statistically significant advance or delay between 1960 and 2010 in this region. These results suggest the applicability of species-level phenology models at the regional level (and potentially terrestrial biosphere models) and the feasibility of using these models in reconstructing and predicting vegetation phenology.

The Noachian-Hesperian transition on Mars was a period marked by changes in volcanic processes and styles of aqueous alteration. Understanding the timing and nature of environmental change requires the exploration of units recording both sets of processes. Herein, we report the compositional stratigraphy of distinctive Noachian to Hesperian units along the northeastern margin of the Syrtis Major volcanic flows. A layered, polyhydrated sulfate-bearing unit with jarosite ridges has been discovered beneath the Syrtis Major lava flows and above the regionally-extensive stratigraphy of Noachian plains units reported previously. Sequential clay-, carbonate-, and sulfate-bearing units formed in-situ and record a transition from alkaline pH to acidic pH waters. The sequence is chronologically bookended by the Isidis impact and Syrtis Major flows, and is one of the most temporally-constrained and well-preserved stratigraphic sections from early Mars available for landed exploration.

[1] A closed depression in the Noctis Labyrinthus region of Mars (at 10.4°S, 98.6°W), believed to have formed in the Late Hesperian, holds an inner pit partially filled with several hundred meters of stratified material. Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) visible-near infrared reflectance data reveal signatures of numerous hydrated minerals including halloysite/kaolinite, Fe-smectite, Si-OH bearing phases and Fe-sulfates (polyhydrated, monohydrated, and hydroxylated types, including jarosite). We use CRISM data, high resolution imagery (HiRISE) and HRSC (High Resolution Stereo Camera) derived elevation to analyze the morphology, composition and stratigraphy of these materials. We propose an alteration sequence including formation of acid sulfate solutions from groundwater and magmatic sulfur, which then locally altered the basaltic bedrock and layered sediments mainly deposited from volcanic tephra, forming Fe-smectite and Fe-sulfates. The mineral variability can mostly be explained by local variations in the pH of the altering fluids, with original acidity being buffered by dissolution of primary minerals; and by variable fluid input and evaporation and/or freezing rates (resulting in various water/rock ratios). This site shows local formation of almost all classes of minerals identified thus far on Mars without invoking global conditions. Processes related to local volcanic activity and associated hydrothermalism were able to produce, during an era in which the climate is believed to have been cold, a large variety of hydrated minerals. This study highlights the importance of the geological setting of hydrated minerals in the understanding of Mars geologic and climatic evolution.

To verify the quality and accuracy of Phobos-2 Imaging Spectrometer for Mars (ISM) spectra of Mars, we have performed comparisons with telescopic data obtained contemporaneously and which have spatial and spectral overlap with the ISM measurements. We find general agreement between the independently-calibrated data sets in terms of spectral shape and absorption band strength and position in the 0.77 to 0.93 micron overlap region. The telescopic data were scaled to the ISM reflectance values in this overlap region to yield new bright and dark region composite reflectance spectra from 0.40 to 3.14 microns. We ascribe the increase in band depth and overall spectral heterogeneity of the ISM data relative to previous telescopic observations to the more than order of magnitude increase in spatial resolution achieved by ISM from Martian orbit. Further increases in spatial resolution from future orbital imaging spectroscopic instruments can be expected to reveal even greater degrees of compositional and mineralogic diversity on Mars.

International audience; Since the first images of polar regions on Mars revealed alternating bright and dark layers, there has been speculation that their formation might be tied to the planet's orbital climate forcing. But uncertainties in the deposition timescale exceed two orders of magnitude: estimates based on assumptions of dust deposition, ice formation and sublimation, and their variations with orbital forcing suggest a deposition rate of 10-3 to 10-2cmyr-1 (refs 5, 6), whereas estimates based on cratering rate result in values as high as 0.1 to 0.2cmyr-1 (ref. 7). Here we use a combination of high-resolution images of the polar layered terrains, high-resolution topography and revised calculations of the orbital and rotational parameters of Mars to show that a correlation exists between ice-layer radiance as a function of depth (obtained from photometric data of the images of the layered terrains) and the insolation variations in summer at the martian north pole, similar to what has been shown for palaeoclimate studies of the Earth. For the best fit between the radiance profile and the simulated insolation parameters, we obtain an average deposition rate of 0.05cmyr-1 for the top 250m of deposits on the ice cap of the north pole of Mars.

[1] The NASA Discovery Moon Mineralogy Mapper imaging spectrometer was selected to pursue a wide range of science objectives requiring measurement of composition at fine spatial scales over the full lunar surface. To pursue these objectives, a broad spectral range imaging spectrometer with high uniformity and high signal-to-noise ratio capable of measuring compositionally diagnostic spectral absorption features from a wide variety of known and possible lunar materials was required. For this purpose the Moon Mineralogy Mapper imaging spectrometer was designed and developed that measures the spectral range from 430 to 3000 nm with 10 nm spectral sampling through a 24 degree field of view with 0.7 milliradian spatial sampling. The instrument has a signal-to-noise ratio of greater than 400 for the specified equatorial reference radiance and greater than 100 for the polar reference radiance. The spectral cross-track uniformity is >90% and spectral instantaneous field-of-view uniformity is >90%. The Moon Mineralogy Mapper was launched on Chandrayaan-1 on the 22nd of October. On the 18th of November 2008 the Moon Mineralogy Mapper was turned on and collected a first light data set within 24 h. During this early checkout period and throughout the mission the spacecraft thermal environment and orbital parameters varied more than expected and placed operational and data quality constraints on the measurements. On the 29th of August 2009, spacecraft communication was lost. Over the course of the flight mission 1542 downlinked data sets were acquired that provide coverage of more than 95% of the lunar surface. An end-to-end science data calibration system was developed and all measurements have been passed through this system and delivered to the Planetary Data System (PDS.NASA.GOV). An extensive effort has been undertaken by the science team to validate the Moon Mineralogy Mapper science measurements in the context of the mission objectives. A focused spectral, radiometric, spatial, and uniformity validation effort has been pursued with selected data sets including an Earth-view data set. With this effort an initial validation of the on-orbit performance of the imaging spectrometer has been achieved, including validation of the cross-track spectral uniformity and spectral instantaneous field of view uniformity. The Moon Mineralogy Mapper is the first imaging spectrometer to measure a data set of this kind at the Moon. These calibrated science measurements are being used to address the full set of science goals and objectives for this mission.

[1] Valles Marineris represents the deepest natural incision in the Martian upper crust. Previous studies showed that the upper parts of the walls were made of finely layered probable basalts in most of the chasmata, while the base of the stratigraphy reveals primary Noachian crustal blocks. Exposures of pristine Noachian bedrock are rare on Mars, and mostly observed outside of their geological context. The occurrence of well-preserved and extended outcrops of pristine material in this giant rift could bring valuable information on the early processes that took place at the surface of Mars. Analyses of high resolution data over the best exposures of lower walls in Coprates Chasma, central Valles Marineris, revealed the presence of multiple magmatic intrusions interpreted as dikes. These dikes intrude an old, massive, fractured bedrock interpreted as being preserved ancient Noachian crust. Their composition, determined using CRISM data, and distribution, limited to this ancient crust at the bottom walls, indicate that they might have formed early in the rift formation, and therefore represent exceptionally well-preserved outcrops of the early history of Mars.

[1] Using the Moon Mineralogy Mapper(M3), we examine the Marius Hills volcanic complex for the first time from 0.46 to 2.97 μm. The integrated band depth at 1 μm separates the mare basalts on the plateau in two units: (1) a strong 1 μm band unit of localized lava flows within the plateau that has similar olivine-rich signatures to those of the nearby Oceanus Procellarum and (2) a weaker 1 μm band unit that characterizes most of the basalts of the plateau, which is interpreted as having a high-calcium pyroxene signature. Domes and cones within the complex belong to the high-calcium pyroxene plateau unit and are associated with the weakest 1 μm band observed on the plateau. This difference could be the result of higher silica content, more opaque minerals, and/or a weaker olivine content of the magma. Finally, the floor of Marius crater has one of the strongest olivine-rich signatures of the entire Marius Hills complex. These compositional differences are indicative of the long and complex volcanic history of the region. The first episode started before the emplacement of the surrounding basalts of the plateau and produced the high-calcium pyroxene flows present on the plateau and their associated domes and cones. The second episode occurred concurrently or slightly after the emplacement of the adjacent Procellarum basalts and produced the olivine-rich basalts seen within the plateau, outside the plateau, and in Marius crater. If the olivine content of the lava flows increases with time, the olivine-rich region on the floor of Marius crater may represent one of the latest episodes of volcanism exposed on the Marius Hills complex.

[1] The Moon Mineralogy Mapper (M3) acquired high spatial and spectral resolution data of the Aristarchus Plateau with 140 m/pixel in 85 spectral bands from 0.43 to 3.0 μm. The data were collected as radiance and converted to reflectance using the observational constraints and a solar spectrum scaled to the Moon-Sun distance. Summary spectral parameters for the area of mafic silicate 1 and 2 μm bands were calculated from the M3 data and used to map the distribution of key units that were then analyzed in detail with the spectral data. This analysis focuses on five key compositional units in the region. (1) The central peaks are shown to be strongly enriched in feldspar and are likely from the upper plagioclase-rich crust of the Moon. (2) The impact melt is compositionally diverse with clear signatures of feldspathic crust, olivine, and glass. (3) The crater walls and ejecta show a high degree of spatial heterogeneity and evidence for massive breccia blocks. (4) Olivine, strongly concentrated on the rim, wall, and exterior of the southeastern quadrant of the crater, is commonly associated the impact melt. (5) There are at least two types of glass deposits observed: pyroclastic glass and impact glass.

[1] A systematic approach for deconvolving remotely sensed lunar olivine-rich visible to near-infrared (VNIR) reflectance spectra with the Modified Gaussian Model (MGM) is evaluated with Chandrayaan-1 Moon Mineralogy Mapper (M3) spectra. Whereas earlier studies of laboratory reflectance spectra focused only on complications due to chromite inclusions in lunar olivines, we develop a systematic approach for addressing (through continuum removal) the prominent continuum slopes common to remotely sensed reflectance spectra of planetary surfaces. We have validated our continuum removal on a suite of laboratory reflectance spectra. Suites of olivine-dominated reflectance spectra from a small crater near Mare Moscoviense, the Copernicus central peak, Aristarchus, and the crater Marius in the Marius Hills were analyzed. Spectral diversity was detected in visual evaluation of the spectra and was quantified using the MGM. The MGM-derived band positions are used to estimate the olivine's composition in a relative sense. Spectra of olivines from Moscoviense exhibit diversity in their absorption features, and this diversity suggests some variation in olivine Fe/Mg content. Olivines from Copernicus are observed to be spectrally homogeneous and thus are predicted to be more compositionally homogeneous than those at Moscoviense but are of broadly similar composition to the Moscoviense olivines. Olivines from Aristarchus and Marius exhibit clear spectral differences from those at Moscoviense and Copernicus but also exhibit features that suggest contributions from other phases. If the various precautions discussed here are weighed carefully, the methods presented here can be used to make general predictions of absolute olivine composition (Fe/Mg content).

[1] High-resolution compositional data from Moon Mineralogy Mapper (M3) for the Moscoviense region on the lunar farside reveal three unusual, but distinctive, rock types along the inner basin ring. These are designated “OOS” since they are dominated by high concentrations of orthopyroxene, olivine, and Mg-rich spinel, respectively. The OOS occur as small areas, each a few kilometers in size, that are widely separated within the highly feldspathic setting of the basin rim. Although the abundance of plagioclase is not well constrained within the OOS, the mafic mineral content is exceptionally high, and two of the rock types could approach pyroxenite and harzburgite in composition. The third is a new rock type identified on the Moon that is dominated by Mg-rich spinel with no other mafic minerals detectable (

[1] Moon Mineralogy Mapper (M3) image and spectral reflectance data are combined to analyze mare basalt units in and adjacent to the Orientale multiring impact basin. Models are assessed for the relationships between basin formation and mare basalt emplacement. Mare basalt emplacement on the western nearside limb began prior to the Orientale event as evidenced by the presence of cryptomaria. The earliest post-Orientale-event mare basalt emplacement occurred in the center of the basin (Mare Orientale) and postdated the formation of the Orientale Basin by about 60–100 Ma. Over the next several hundred million years, basalt patches were emplaced first along the base of the Outer Rook ring (Lacus Veris) and then along the base of the Cordillera ring (Lacus Autumni), with some overlap in ages. The latest basalt patches are as young as some of the youngest basalt deposits on the lunar nearside. M3 data show several previously undetected mare patches on the southwestern margins of the basin interior. Regardless, the previously documented increase in mare abundance from the southwest toward the northeast is still prominent. We attribute this to crustal and lithospheric trends moving from the farside to the nearside, with correspondingly shallower density and thermal barriers to basaltic magma ascent and eruption toward the nearside. The wide range of model ages for Orientale mare deposits (3.70–1.66 Ga) mirrors the range of nearside mare ages, indicating that the small amount of mare fill in Orientale is not due to early cessation of mare emplacement but rather to limited volumes of extrusion for each phase during the entire period of nearside mare basalt volcanism. This suggests that nearside and farside source regions may be similar but that other factors, such as thermal and crustal thickness barriers to magma ascent and eruption, may be determining the abundance of surface deposits on the limbs and farside. The sequence, timing, and elevation of mare basalt deposits suggest that regional basin-related stresses exerted control on their distribution. Our analysis clearly shows that Orientale serves as an excellent example of the early stages of the filling of impact basins with mare basalt.

[1] Lunar geochemical groups such as Mg suite, ferroan anorthosite, and alkali suite rocks are difficult to distinguish from orbit because they are defined by both modal mineralogy and elemental composition of their constituent minerals. While modal mineralogy can be modeled, only specific minerals or elements can be directly detected. At near-infrared (NIR) wavelengths, pyroxenes are among the most spectrally distinctive minerals, and their absorption bands are sensitive to structure and composition. Pyroxenes thus provide important clues to distinguish these geochemical groups and to understand lunar crustal evolution. Using Moon Mineralogy Mapper data, we search for lithologies dominated by strong low-calcium pyroxene (LCP) signatures. We compare the NIR absorptions of 20 LCPs to a suite of synthetic pyroxenes to determine which lunar pyroxenes appear magnesian enough to be candidate Mg suite norites. We detail three prominent regions of LCP (1) in South Pole–Aitken Basin (SPA), (2) south of Mare Frigoris, and (3) north of Mare Frigoris. The absorption band positions suggest that the LCPs north of Mare Frigoris and those in SPA are compositionally similar to one another and of ∼Mg50–75, implying that the mafic material excavated by the SPA impact was relatively iron-rich. Modified Gaussian modeling results suggest that the Apollo basin may have tapped different composition material than is exposed in much of SPA. The LCPs located in the highlands south of Mare Frigoris exhibit absorption bands at short wavelengths consistent with Mg > ∼80. The coincidence of these Mg-rich LCPs with the thorium measured by Lunar Prospector make them good candidates for KREEP-related Mg suite pyroxenes.

In this paper, we analyze water ice occurrences at the surface of Mars using near-infrared observations, and we study their distribution with a climate model. Latitudes between 45{\deg}S and 50{\deg}N are considered. Data from the Observatoire pour la Min\'eralogie, l'Eau, les Glaces et l'Actitit\'e and the Compact Reconnaissance Imaging Spectrometer for Mars are used to assess the presence of surface water ice as a function of location and season. A modeling approach combining the 1-D and 3-D versions of the General Circulation Model of the Laboratoire de M\'et\'eorologie Dynamique de Jussieu is developed and successfully compared to observations. Ice deposits 2-200 \mu m thick are observed during the day on pole facing slopes in local fall, winter and early spring. Ice extends down to 13{\deg} latitude in the Southern Hemisphere but is restricted to latitudes higher than 32{\deg} in the north. On a given slope, the pattern of ice observations at the surface is mainly controlled by the global variability of atmospheric water (precipitation and vapor), with local ground properties playing a lower role. Only seasonal surface ice is observed: no exposed patches of perennial ground ice have been detected. Surface seasonal ice is however sensitive to subsurface properties: the results presented in this study are consistent with the recent discovery of low latitude subsurface ice obtained through the analysis of CO2 frost.

The study characterizes Syrtis Major, an old, low relief volcanic plateau near the equatorial regions of Mars, on the basis of ISM data in order to characterize the spectral properties of the surface, to identify the major mafic mineralogy of the volcanic materials, and to derive estimates of the chemistry of these minerals. The value and spatial distribution of four primary spectral variables (albedo, continuum slope, wavelength of the ferric-ferrous band minimum, and area of the ferric-ferrous absorption) are mapped and coregistered to Viking digital photomosaics. It is shown that although there is a high degree of overall spectral variability on the plateau, the key indicators of mafic mineralogy are relatively homogeneous.

[1] The surface materials of Acidalia and Chryse planitiae, Mars, have been variably interpreted morphologically as basalt and compositionally as andesite or altered basalt. A thorough survey using the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) near-infrared spectrometer reveals olivine and high-calcium pyroxene signatures in the shallow subsurface exposed by impact craters. These signatures indicate that the near surface of these regions are primarily basaltic in nature and are similar to other regions of Hesperian volcanism across Mars (e.g., Syrtis Major). Previous spectroscopic studies using coarser-resolution data sets have failed to identify these mafic signatures due to obscuration of the underlying material in addition to the relatively small-scale exposures in impact craters. The nature of the surficial obscuration material is likely multifaceted and includes the deposition of latitude-dependent mantling material and the presence of alteration rinds. This observation shows that the northern plains of Mars are basaltic and must be factored into the thermal and surficial evolution of Mars.

[1] Sedimentary deposits within the 280 km wide crater containing Aram Chaos (∼3°N, 339°E) have been differentially eroded by wind to expose a stratigraphic column 900–1000 m thick that unconformably overlies the chaos bedrock. A detailed stratigraphic and mineralogical description of the deposits is presented based on data from the Mars Reconnaissance Orbiter Compact Reconnaissance Imaging Spectrometer for Mars, Context Imager, and High Resolution Imaging Science Experiment. Two sedimentary units overlie the basement chaos material representing the original plains fill in Aram Crater: the first and oldest is composed of (1) a 50–75 m thick dark-toned basal unit containing ferric hydroxysulfate intercalated with monohydrated-sulfate-bearing materials, (2) a 75–100 m thick light-toned unit with monohydrated sulfates, and (3) a 175–350 m thick light-toned resistant capping unit with nanophase ferric oxides and monohydrated sulfates. After a period of wind erosion, these deposits were partially and unconformably covered by the second sedimentary unit, a 75–100 m thick, discontinuous dark-toned unit containing crystalline hematite and polyhydrated sulfate material. These sedimentary deposits were formed by evaporite deposition during at least two distinct rising groundwater episodes fed by regional-scale recharge. Later groundwater event(s) formed the polyhydrated materials, indicating that environmental conditions changed to a higher water-to-rock ratio. Wind has continued to shape the landscape after the last wetting event to produce the features and exposures observed.

Serpentine, recently discovered on Mars using Mars Reconnaissance Orbiter data, is uncommon but found in three geologic settings: (1) in melange terrains at the Claritas Rise and the Nili Fossae, (2) associated with a few southern highlands impact craters, and (3) associated with a regional olivine-rich stratigraphic unit near the Isidis basin. Any presently active serpentinization processes would be occurring beneath the surface and mineral products would not be apparent with surface and orbital data; however, finding serpentine in several Noachian terrains indicates active serpentinization processes in Mars' past. Important implications are the past production of magnetite, which may contribute to chemical remnant magnetization of Mars' crust, and production of H_2, which is a suitable energy source for chemosynthetic microbial life.

Near-surface perennial water ice on Mars has been previously inferred down to latitudes of about 45° and could result from either water vapor diffusion through the regolith under current conditions or previous ice ages precipitations. In this paper we show that at latitudes as low as 25° in the southern hemisphere buried water ice in the shallow (< 1 m) subsurface is required to explain the observed surface distribution of seasonal CO2 frost on pole facing slopes. This result shows that possible remnants of the last ice age, as well as water that will be needed for the future exploration of Mars, are accessible significantly closer to the equator than previously thought, where mild conditions for both robotic and human exploration lie.