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In this paper, we have analyzed neutron spectroscopy data gathered by the high energy neutron detector instrument onboard Mars Odyssey in order to study the behavior of CO 2 condensed mass at the polar regions of Mars. It is known that observation of the neutron albedo of Mars provides not only information on distribution of water ice/bounded water through Martian subsurface but is also sensitive to the condensation/sublimation of atmospheric CO 2 at the Martian poles. Analysis of temporal variations of neutron flux between summer and winter seasons allowed the creation of multidimensional model of CO 2 deposition describing behavior of CO 2 condensed mass as a function of longitude, latitude and time. Based on this model, we have estimated the total masses of north seasonal cap ((3.8 ± 0.4) × 10 15 kg), south seasonal cap ((6.3 ± 0.6) × 10 15 kg) and compared our estimations with predictions of General Circulation Model. Furthermore, using the data gathered during second Martian year on the orbit, we have conducted preliminary comparison between seasonal cycles of two successive Martian years.

[1] A new technique has been developed for characterizing gamma-ray emission from a planetary surface in the presence of large background signals generated in a spacecraft. This technique is applied to the analysis of Al gamma rays measured by the MESSENGER Gamma-Ray Spectrometer to determine the abundance of Al on the surface of Mercury. The result (Al/Si = 0.29� 0.13 +0.05 ) is consistent with Al/Si ratios derived from the MESSENGER X-Ray Spectrometer and confirms the finding of low Al abundances. The measured abundance rules out a global, lunar-like feldspar-rich crust and is consistent with previously suggested analogs for surface material on Mercury, including terrestrial komatiites, low-iron basalts, partial melts of CB chondrites, and partial melts of enstatite chondrites. Additional applications of this technique include the measurement of other elements on Mercury’s surface as well as the analysis of data from other planetary gamma-ray spectrometer experiments.

[1] Orbital gamma-ray measurements obtained by the MESSENGER spacecraft have been analyzed to determine the abundances of the major elements Al, Ca, S, Fe, and Na on the surface of Mercury. The Si abundance was determined and used to normalize those of the other reported elements. The Na analysis provides the first abundance estimate of 2.9 ± 0.1 wt% for this element on Mercury's surface. The other elemental results (S/Si = 0.092 ± 0.015, Ca/Si = 0.24 ± 0.05, and Fe/Si = 0.077 ± 0.013) are consistent with those previously obtained by the MESSENGER X-Ray Spectrometer, including the high sulfur and low iron abundances. Because of different sampling depths for the two techniques, this agreement indicates that Mercury's regolith is, on average, homogenous to a depth of tens of centimeters. The elemental results from gamma-ray and X-ray spectrometry are most consistent with petrologic models suggesting that Mercury's surface is dominated by Mg-rich silicates. We also compare the results with those obtained during the MESSENGER flybys and with ground-based observations of Mercury's surface and exosphere.

[1] More than 3 Mars' years (MY) of atmospheric argon (Ar) measurements are used to study annual and seasonal variations in atmospheric transport and mixing. Data are obtained over the period 20 May 2002 to 4 May 2008 by the Gamma Subsystem (GS) of the Gamma Ray Spectrometer (GRS) on the Mars Odyssey spacecraft in orbit around Mars. Here we augment previous studies of Mars' Ar in which strong seasonal variations were observed and horizontal meridional mixing coefficients for the southern hemisphere were computed. Comparison of year-to-year seasonal abundance shows strong similarity but also some short-period (∼15°–30° Ls) and interannual variations. Evidence for short periods of strong eddy transport is exhibited during autumn and winter. The seasonal change in Ar concentration for southern latitudes is relatively gradual and well defined, but seasonal changes at high northern latitudes are chaotic and indicate that atmospheric disturbance is ubiquitous. Major topographic landforms (Elysium, Tharsis, Noachis Terra, Hellas) apparently have little control over seasonal Ar concentration at the spatial resolution of the GRS data set. Some indication of local enhanced Ar concentration is present from 30°N to 60°N for the Hellas and Tharsis sectors in late winter and early spring. The data show some significant (3σ) differences between MY 26 and MY 27 in geographical sectors that are likely produced by local weather. The GS data do not show seasonal variation of Ar at equatorial and low-latitude zones, in contrast to those from the Alpha Particle X-ray Spectrometer (APXS) measurements from the Mars Exploration Rovers.

[1] We report maps of the concentrations of H, Si, Cl, K, Fe, and Th as determined by the Gamma Ray Spectrometer (GRS) on board the 2001 Mars Odyssey Mission for ±∼45° latitudes. The procedures by which the spectra are processed to yield quantitative concentrations are described in detail. The concentrations of elements determined over the locations of the various Mars landers generally agree well with the lander values except for Fe, although the mean of the GRS Fe data agrees well with that of Martian meteorites. The water-equivalent concentration of hydrogen by mass varies from about 1.5% to 7.5% (by mass) with the most enriched areas being near Apollinaris Patera and Arabia Terra. Cl shows a distribution similar to H over the surface except that the Cl content over Medusae Fossae is much greater than elsewhere. The map of Fe shows enrichment in the northern lowlands versus the southern highlands. Silicon shows only very modest variation over the surface with mass fractions ranging from 19% to 22% over most of the planet, though a significant depletion in Si is noted in a region west of Tharsis Montes and Olympus Mons where the Si content is as low as 18%. K and Th show a very similar pattern with depletions associated with young volcanic deposits and enrichments associated with the TES Surface Type-2 material. It is noted that there appears to be no evidence of significant globally distributed thick dust deposits of uniform composition.

[1] To elucidate the nature of permafrost in the shallow subsurface of Mars, we analyze jointly neutron albedo from the High Energy Neutron Detector (HEND) on the Mars Odyssey spacecraft and near-IR (1064-nm) surface reflectance from the Mars Orbiter Laser Altimeter (MOLA) on Mars Global Surveyor. The first dataset measures the content of hydrogen (in the form of water or hydroxyl) in the soil, and the second yields the flux of absorbed solar energy by the surface. We identify a statistically–significant negative cross-correlation between these data at latitudes poleward of 40° latitude in the northern hemisphere and in the latitude band 40°–60° in the southern hemisphere, which we interpret as evidence for the presence of stable water ice under a dry equilibrium top layer (ETL). We deduce an empirical relation between near-IR reflectance and thickness of this ETL, which allows the burial depth of the water ice table to be estimated with km-scale spatial resolution. We observe no correlation between neutron and near-IR albedo within the southern hemisphere poleward of 60° latitude. While it is known from previously analyzed neutron and gamma-ray data that subsurface water ice is present within this region and is covered by a layer of dry regolith, the absence of a correlation indicates that the thickness of this layer is not controlled by an equilibrium condition between the ice table and atmosphere.

[1] In this paper, we have analyzed neutron spectroscopy data gathered by the High Energy Neutron Detector (HEND) instrument on board Mars Odyssey for two Martian years of orbital mapping. We focused on the observations of the Martian southern seasonal cap for this period of time. Nuclear methods based on numerical modeling allow us to derive an estimation of the distribution of CO2 frost column density and mass from the temporal variations of neutron flux between summer and winter seasons. We have estimated the seasonal behavior of both the column density and mass of CO2 frost. Comparison between two Martian years revealed minor (

[1] Quantifying secular variations in the chemical composition of the Martian crust provides unique insights into the processes that have guided the evolution of the Martian crust-mantle system. Using global abundances for a suite of elements determined by the Gamma Ray Spectrometer (GRS) on board the Mars Odyssey spacecraft and global mapping of apparent surface age adapted from existing geologic maps in the USGS Martian Geologic Investigation series, we report the average abundance of K, Th, Fe, Cl, H, and Si for the major Martian geologic epochs (Noachian, Hesperian, and Amazonian). Average GRS-determined K and Th abundances generally decrease by 9% and 7%, respectively, between the Hesperian and the Amazonian, possibly implying evolving magma chemistry throughout major resurfacing events (although the effects of surficial alteration processes cannot be entirely discounted). GRS-determined Fe and Cl averages increase by 12% and 19%, respectively, with younger apparent relative surface age, suggesting the possible mobilization and transport of these elements through aqueous processes (although an igneous origin for the variation in Fe also cannot be excluded). While H abundance does vary with surface age, the relationship is likely not governed by geologic processes. No statistically reliable apparent surface age relation was found for Si.

[1] K/Th determined by the Mars Odyssey Gamma Ray Spectrometer varies by a factor of 3 on Mars (3000 to 9000), but over 95% of the surface area has K/Th between 4000 and 7000. K/Th is distinctly lower than average in some areas, including west of Olympus Mons in the Amazonis Planitia, the region around Memnonia Fossae, Chryse Planitia, southeastern Arabia Terra, Syrtis Major Planum, and northwest of Apollinaris Patera. On the other hand, K/Th is distinctly higher than average in other areas, including the central part of Valles Marineris and the surrounding highlands, and in the northern part of Hellas. The generally modest variation in K/Th may be explained by inherent variations in igneous rocks and by variations in the extent of aqueous alteration.

[1] The 2001 Mars Odyssey Gamma Ray Spectrometer (GRS) has made the first measurement of the equatorial and midlatitude distribution of Cl at the near-surface of Mars. A mean concentration value of 0.49 wt% Cl has been determined from a grand sum of GRS spectra collected over the planet excluding high-latitude regions. Cl is significantly enriched within the upper few tens of centimeters of the surface relative to the Martian meteorites and estimates for the bulk composition of the planet. However, Cl is not homogeneously distributed and varies by a factor of ∼4 even after smoothing of data with a 10°-arc-radius filter. Several contiguous, geographically large (>20°) regions of high and low Cl concentrations are present. In particular, a region centered over the Medusae Fossae Formation west of Tharsis shows significantly elevated Cl. A large region north of Syrtis Major extending into Utopia Planitia in the northern hemisphere shows the lowest Cl concentrations. On the basis of hierarchical multivariate correlations, Cl is positively associated with H while negatively associated with Si and thermal inertia. We discuss four possible geologic mechanisms (aeolian, volcanic, aqueous, and hydrothermal) that may have affected the Cl distribution seen by GRS. While some of the distribution may be due to Cl-rich dust deposits transported by aeolian processes, this mechanism does not appear to account for all of the observed variability. We propose that reactions with volcanic exhalations may have been important for enriching Cl in Medusae Fossae Formation material.

[1] Conclusions are drawn about the column density (g/cm2), spatial extent, and mass of the seasonal carbon dioxide frost on the poles of Mars as a function of time utilizing data from the 2001 Mars Odyssey Gamma Ray Spectrometer (GRS). Quantification of these CO2 values is achieved by observing attenuation effects of the surface-emitted hydrogen gamma ray flux as the frost condenses and sublimates in a seasonal exchange of CO2 between the ground and the atmosphere. Columnar thickness and mass results are discussed and plotted for latitudes including ±60° and poleward. GRS observations are compared to predictions from the NASA Ames Research Center General Circulation Model and to similar experimental results from the Mars Odyssey High Energy Neutron Detector and Neutron Spectrometer. Models for north and south polar atmosphere and regolith distributions are incorporated, and our results indicate that the assumption of a 100% H2O-ice residual cap underlying the seasonal frost in the north is accurate. The GRS CO2 frost observations are in good agreement with the other studies mentioned, in particular for the timing of the beginning of frost deposition to the complete sublimation of surface CO2 back into the atmosphere. The total amount of condensed carbon dioxide mass seen by the GRS is on the order of 6.0 × 1015 kg and verifies previous reports that nearly 25% of the Martian CO2 reservoir participates in the ground-atmosphere exchange cycle.

[1] The thickness of seasonal CO2 frost that covers the north pole of Mars during the winter and spring seasons is studied using gamma ray and neutron data measured using the gamma ray spectrometer suite of instruments aboard Mars Odyssey. The resultant seasonal variation of CO2 ice/frost thickness for latitudes greater than +85° is in close agreement (within 9% at maximum) with those predicted using all three major Mars general circulation models presently in use. These observed CO2 ice results are significantly different from those inferred from the Mars Obiter Laser Altimeter experiment aboard Mars Global Surveyor (MGS). A possible explanation is that the density of the CO2 ice/frost cap is considerably lower than that inferred from observed variations of the MGS orbit. Other significant results are that the thermal neutron counting rates provide evidence for variations in the abundance of noncondensable components of the polar atmosphere of Mars and that the basement terrain below the seasonal cover of CO2 frost within about 10° of the pole is nearly 100% water ice.

The Thermal and Evolved Gas Analyzer (TEGA) on the Mars Polar Lander spacecraft is composed of two separate components which are closely coupled: a Differential Scanning Calorimeter (DSC) and an Evolved Gas Analyzer (EGA). TEGA has the capability of performing differential scanning calorimetry on eight small (0.038 mL) soil samples selected in the vicinity of the lander. The samples will be heated in ovens to temperatures up to 950°C, and the volatile compounds water and carbon dioxide, which are released during the heating, will be analyzed in the EGA. The power required by the sample oven is continuously monitored during the heating and compared to that required to heat simultaneously a similar, but empty, oven. The power difference is the output of the DSC. Both endothermic and exothermic phase transitions can be detected, and the data can be used in the identification of the phases present. By correlating the gas release with the calorimetry, the abundance of the volatile compounds associated with the different phases can be determined. The EGA may also be able to detect the release of oxygen associated with any superoxide that may be on the surface of the soil grains. The instrument can detect the melting of ice in the DSC down to abundances on the order of 0.2% of the sample, and it can detect the decomposition of calcite, CaCO3, down to abundances of 0.5%. Using the EGA, TEGA can detect small amounts of water, down to 8 ppm in the sample, and it can detect the associated release of CO2 down to the equivalent abundances of 0.03%. The EGA also has the ability to determine the 13C/12C ratio in the evolved CO2, but it is not clear if the accuracy of this ratio will be sufficient to address the scientific issues.