Search

Pyroclastic deposits of the Holocene Igwisi Hills kimberlite volcanoes, Tanzania, preserve unequivocal evidence for rapid, syn-eruptive agglutination. The unusual pyroclasts are composed of ash-sized particles agglutinated to each other by thin necks. The textures suggest the magma was disrupted into droplets during ascent. Collisions between particles occurred within a volcanic plume and on deposition within the conduit to form a weakly agglutinated, porous pyroclastic deposit. Theoretical considerations indicate that agglutination occurred over short timescales. Agglutinated clasts were entrained into weak volcanic plumes and deposited around the craters. Our results support the notion that agglutination can occur during kimberlite eruptions, and that some coherent, dense rocks in ancient kimberlite pipes interpreted as intrusive rocks could instead represent agglutinated pyroclastic rocks. Differentiating between agglutinated pyroclastic rocks and effusive or intrusive rocks in kimberlite pipes is important because of the potential effects that pyroclastic processes might have on diamond concentrations in deposits.

BVD is funded by the Natural Environment Research Council through the EnvEast Doctoral Training partnership (grant number NE/1002582/1)., Proximal deposits of small-volume trachytic eruptions are an under-studied record of eruption dynamics despite being common across a range of settings. The 59 ± 4 ka Echo Canyon deposits, Ascension Island, resulted from a small-volume explosiveeffusive trachytic eruption. Variations in juvenile clast texture reveal changes in ascent dynamics and transitions in eruption style. Five dominant textural types are identified within the pumice lapilli population. Early Strombolian-Vulcanian eruption phases are typified by macro- and micro-vesicular equant clast types. Sheared clasts are most abundant at the eruption peak, transitioning to dense clasts in later phases due to shear-induced coalescence, outgassing and vesicle collapse. Melt densification and outgassing via tuffisite veins increased plume density, contributing to partial column collapse and the explosive-effusive transition. Bulk vesicularity distributions indicate a shift in dominant fragmentation mechanism during the eruption, from early-stage bubble interference and rupture to late-stage transient fragmentation, with a transient peak of Plinian activity. Dome and lava groundmass crystallinities of up to 70% indicate near-complete degassing during effusive phases, followed by shallow over pressurisation and a final less explosive phase. We provide textural evidence for high-intensity explosive phases and rapid transitions in eruptive style during small-volume trachytic eruptions and consider the impact of trachytic melt compositions on underlying dynamics of these short-lived, explosive events. This analysis demonstrates the value of detailed stratigraphy in understanding critical changes in eruption dynamics and the timescales over which they may occur which is of particular value in anticipating future eruptions of this type., Natural Environment Research Council through the EnvEast Doctoral Training partnership NE/1002582/1

Identification of volcanic signals preserved in paleoenvironmental records can provide key insights into the timing and consequences of explosive volcanism. Yet the eruption record is incomplete and this confounds our ability to link volcanic eruptions to their impacts on climate and environments. Studies have suggested that stalagmite records can help to address these gaps, through the identification of transient geochemical variability associated with incorporation of elements derived from erupted material. However, the utility of stalagmites for tracing volcanism is poorly constrained globally. Here, we present a high-resolution geochemical dataset for stalagmite NIED08–05 from Niedźwiedzia Cave (Poland). We do this with two primary aims: (1) to test the suitability of NIED08–05 as a record of volcanism since 3 ka BP, and (2) to ascertain whether stalagmites grown in temperate regions preserve volcanic signals with success comparable to those grown in tropical regions. We find transient enrichments of 16 trace elements and the rare-earth-elements Y, La, Nd, which coincide with the timing of some known eruption events. Using Principal Component Analysis (PCA) we find that elements atypically incorporated into calcite (e.g., Fe) co-vary. Similarly, filtering PC1 (17% of the dataset variability) for high magnitude deviations from a baseline signal yields tentative agreement between PC scores and some known large eruptions with tephra found in Poland. We use our analysis to discuss the complexities involved in associating volcanic signals with stalagmite chemistry in temperate regions far from the source of large eruptions. The transport pathway from volcanic source to stalagmite growth surfaces includes the complex Niedźwiedzia Cave hydrological system and is influenced by dense forest above the cave site. Together these factors increase the potential for attenuation of volcanic-derived chemical signals prior to reaching the stalagmite, and so make it difficult to unambiguously link trace element enrichments in NIED08–05 to volcanic eruptions. Our results provide strong evidence that in a temperate depositional environment far from active volcanoes, climate and hydrology conspire to mute the strength of volcanic geochemical signals. Therefore, this work provides important incentives for future research in this area by highlighting that stalagmites grown in a comparatively simple hydrological regime and grown in caves overlain by thin vegetation and soil cover , may preserve volcanic signatures with greater success than those grown in temperate environments.

Ocean island volcanism is generally considered to be dominated by basaltic eruptions, yet felsic products associated with more hazardous explosive eruptive events are also present in the geological record of many of these islands. Ascension Island, recently recognised as an active volcanic system, exhibits explosive felsic eruption deposits but their age, eruptive styles and stratigraphic association with mafic volcanism are thus far unclear. Here we present a felsic pyroclastic stratigraphy for Ascension Island, supplemented by 26 new 40Ar/39Ar ages and whole rock geochemical XRF data. More than 80 felsic pyroclastic eruptions have occurred over the last ~ 1 Myr, including subplinian and phreatomagmatic eruptions, which produced pumice fall and pyroclastic density current deposits. Detailed sampling suggests felsic events are unevenly distributed in space and time. Subaerial activity can be divided into four Periods: Period 1 (~1000 – 500 ka) felsic and mafic eruptions, with felsic explosive eruptions, linked to a Central Felsic Complex; Period 2 (~ 500 – 100 ka) mafic period; Period 3 (~ 100 – 50 ka) felsic eruptions associated with the Eastern Felsic Complex; Period 4 (< 50 ka) mafic eruptions. The last explosive eruption occurred at ~ 60 ka. This work highlights the cyclical nature of ocean island volcanism and the timescales over which changes between predominantly mafic and felsic volcanism occur. The prevalence of past felsic explosive eruptions on Ascension highlights the need to consider the possibility of future subplinian or phreatomagmatic events in hazard management plans, with any potential risk compounded by Ascension’s small size and remote location.

Volcanic ash and pyroclasts can weld when deposited hot by pyroclastic density currents, in near-vent fall deposits, or in fractures in volcano interiors. Welding progressively decreases the permeability of the particle packs, influencing a range of magmatic and volcanic processes, including magma outgassing, which is an important control on eruption dynamics. Consequently, there is a need for a quantitative model for permeability evolution during welding of ash and pyroclasts under the range of conditions encountered in nature. Here we present in situ experiments in which hydrous, crystal-free, glassy pyroclasts are imaged via x-ray tomography during welding at high temperature. For each 3D dataset acquired, we determine the porosity, Darcian gas permeability, specific surface area, and pore connectivity. We find that all of these quantities decrease as a critical percolation threshold is approached. We develop a constitutive mathematical model for the evolution of permeability in welding volcanic systems based on percolation theory, and validate the model against our experimental data. Importantly, our model accounts for polydispersivity of the grainsize in the particle pack, the pressures acting on the pack, and changes in particle viscosity arising from degassing of dissolved H2O during welding. Our model is theoretically grounded and has no fitting parameters, hence it should be valid across all magma compositions. The model can be used to predict whether a cooling pyroclast pack will have sufficient time to weld and to degas, the scenarios under which a final deposit will retain a permeable network, the timescales over which sealing occurs, and whether a welded deposit will have disequilibrium or equilibrium H2O content. A user-friendly implementation of the model is provided.

Portuguese Foundation for Science and Technology IF/01641/2015 Fondos de Instalacion Academica - FCFM Universidad de Chile

The generation of felsic melts (through open or closed system processes) within ocean island volcanoes has been a key area of study since their identification. At Ascension Island in the south Atlantic, explosively erupted felsic melts have, to date, demonstrated a marked absence of signs of magma mixing and crustal assimilation. Here we present the first observations of a fall deposit from Ascension Island recording both macro- and micro-scale evidence for magma mingling. Geochemical analyses of mineral and glass phases, coupled with volatile concentrations of melt inclusions highlight the role of lower-crustal partial melting to produce rhyolitic magmas. Glass textures and the lack of zoning in major mineral phases indicate that mingling with a mafic melt occurred shortly prior to eruption. These inferences of a deep rhyolite production zone, coupled with rapid ascent rates highlight the challenges in forecasting a similar style of eruption at Ascension Island in the future.

The Younger Dryas is considered the archetypal millennial-scale climate change event, and identifying its cause is fundamental for thoroughly understanding climate systematics during deglaciations. However, the mechanisms responsible for its initiation remain elusive, and both of the most researched triggers (a meltwater pulse or a bolide impact) are controversial. Here, we consider the problem from a different perspective and explore a hypothesis that Younger Dryas climate shifts were catalysed by the unusually sulfur-rich 12.880 ± 0.040 ka BP eruption of the Laacher See volcano (Germany). We use the most recent chronology for the GISP2 ice core ion dataset from the Greenland ice sheet to identify a large volcanic sulfur spike coincident with both the Laacher See eruption and the onset of Younger Dryas-related cooling in Greenland (i.e. the most recent abrupt Greenland millennial-scale cooling event, the Greenland Stadial 1, GS-1). Previously published lake sediment and stalagmite records confirm that the eruption's timing was indistinguishable from the onset of cooling across the North Atlantic but that it preceded westerly wind repositioning over central Europe by ∼ 200 years. We suggest that the initial short-lived volcanic sulfate aerosol cooling was amplified by ocean circulation shifts and/or sea ice expansion, gradually cooling the North Atlantic region and incrementally shifting the midlatitude westerlies to the south. The aerosol-related cooling probably only lasted 1–3 years, and the majority of Younger Dryas-related cooling may have been due to the sea-ice–ocean circulation positive feedback, which was particularly effective during the intermediate ice volume conditions characteristic of ∼ 13 ka BP. We conclude that the large and sulfur-rich Laacher See eruption should be considered a viable trigger for the Younger Dryas. However, future studies should prioritise climate modelling of high-latitude volcanism during deglacial boundary conditions in order to test the hypothesis proposed here.

Igneous sills and dykes that intrude pervasively into prospective sedimentary basins are a common occurrence in volcanic margins, impacting the petroleum system and causing geological and technical drilling challenges during hydrocarbon exploration. The Faroe-Shetland Basin (FSB), NE Atlantic Margin, has been the focus of exploration for over 45 years, with many wells penetrating igneous intrusions. Utilising 29 FSB wells (with 251 intrusions) and 3D seismic data, this study presents new insights into the impacts that igneous intrusions have on hydrocarbon exploration. Examination of cores reveals additional igneous material in individual wells, compared to estimates using seismic or petrophysical data alone, leading to potential underestimation of the volume of the igneous component in a basin. Furthermore, analysis of petrophysical data shows that within the FSB there are silicic intrusions such as diorite and rhyolite, in addition to the commonly encountered mafic intrusions. These silicic intrusions are difficult to recognise in seismic and petrophysical data due to their low density and compressional velocity and have historically been misidentified on seismic reflection data as exploration targets. Drilling data acquired through intrusions provide valuable insight into the problems exploration wells can encounter, often unexpectedly, many of which can be detrimental to safe drilling practice and result in prolonged non-productive time.

At the base of many flood basalt sequences and along volcanic rifted margins, volcanism can compete with the existing sedimentary environments, resulting in interbedded sequences of volcanic rocks and sediments. Here we report on sediment interlayers that are found in the lowermost volcanic units of the Etendeka flood basalts in NW Namibia (Twyfelfontein and Awahab formations), part of the much larger Paraná–Etendeka Igneous Province. The sandstone bodies, predominantly eolian dunes, are isolated in a sequence of Lower Cretaceous (∼ 134 Ma) lava flows. The uppermost part or where sediment deposition and lava emplacement is observed to interact is characterized by barchanoid dunes, which were actively migrating during the emplacement of the lava flows. The fossil (isolated by lava) barchan dunes studied in Dune Valley show three characteristically different diagenetic styles. In Dune Valley, each dune body is completely encapsulated by lava, with additional igneous intrusions cutting through some bodies. We recognize three distinct styles of diagenesis: Type 1: fossilised dunes that are red in color and lack major authigenic mineralization, with grain compaction and subsequent porosity loss being the dominant diagenetic process. Type 2: dunes that have been bleached white, which have undergone a more complex diagenetic pathway. Type 2 dunes have abundant calcite, kaolinite, and böhmite as authigenic phases and lack hematite grain coatings. Detrital plagioclase is absent in white dunes (XRD analysis), with pseudomorphs of kaolinite common. This diagenetic assemblage results in the white dunes having lower porosity and permeability compared to the red dunes. The observations are probably due to a flux of carbon dioxide (CO2), hydrogen sulfide (H2S) and/or hydrogen (H2)–rich hydrothermal groundwater derived from igneous intrusions below. Type 3: “hot contact” effects at lava-flow contacts, where the unconsolidated dunes were rapidly indurated during lava emplacement (volcano-eogenesis). Type 3 diagenesis is restricted to << 1 m depth below lava contacts and common in dunes displaying both Type 1 and Type 2 diagenesis. The distribution of diagenetic Types 1 and 2 is dune specific, and throughout Dune Valley approximately half of the dunes have been bleached (e.g., Type 2 diagenesis), whereas diagenetic Type 3 is a hot contact phenomenon and is therefore found along all basal lava and dike contacts. This work has relevance to understanding the development of sediment–lava systems, to hydrocarbon exploration and development in preserved sediment–lava sequences, and the hydrothermal process described provides an example of natural CO2 sequestration.

Many prospective sedimentary basins contain a variety of extrusive volcanic products that are ultimately sourced from volcanoes. However, seismic reflection-based studies of magmatic rift basins have tended to focus on the underlying magma plumbing system, meaning that the seismic characteristics of volcanoes are not well understood. Additionally, volcanoes have similar morphologies to hydrothermal vents, which are also linked to underlying magmatic intrusions. In this study, we use high resolution 3D seismic and well data from the Bass Basin, offshore southern Australia, to document 34 cone- and crater-type vents of Miocene age. The vents overlie magmatic intrusions and have seismic properties indicative of a volcanic origin: their moderate–high amplitude upper reflections and zones of “wash-out” and velocity pull-up beneath. The internal reflections of the vents are similar to those found in lava deltas, suggesting they are composed of volcaniclastic material. This interpretation is corroborated by data from exploration wells which penetrated the flanks of several vents. We infer that the vents we describe are composed of hyaloclastite and pyroclasts produced during submarine volcanic eruptions. The morphology of the vents is typical of monogenetic volcanoes, consistent with the onshore record of volcanism on the southern Australian margin. Based on temporal, spatial and volumetric relationships, we propose that submarine volcanoes can evolve from maars to tuff cones as a result of varying magma-water interaction efficiency. The morphologies of the volcanoes and their links to the underlying feeder systems are superficially similar to hydrothermal vents. This highlights the need for careful seismic interpretation and characterization of vent structures linked to magmatic intrusions within sedimentary basins.

On December 29, 2013, an isolated vulcanian-type eruption occurred at Chaparrastique volcano (El Salvador) after 12 years of inactivity. The eruption was classified as VEI 2 and produced an ash plume with a maximum height of ~ 9 km. Textural and compositional data from phenocrysts from the erupted products have been integrated with geochemical and isotopic information from bulk rocks to elucidate the magmatic processes responsible for the reawakening of volcanic activity. Phenocrysts consist of Fo-rich poikilitic olivines hosting high-Mg titanomagnetites, and Fo-poor olivines coexisting with low-Mg titanomagnetites. Mineral-melt equilibria suggest an origin for the distinct phenocryst populations by mixing between a high- T (~ 1130–1150 °C), basaltic magma with f O 2 (NNO buffer) typical of the lower crust in arc systems and a low- T (~ 1060–1080 °C), basaltic andesitic magma with f O 2 (NNO + 1 buffer) commonly encountered in shallower, more oxidized crustal reservoirs. Thermobarometry based on Fe-Mg exchange between orthopyroxene and clinopyroxene constrains the crystallization before eruption at relative low- P (~ 150–250 MPa) and low- T (~ 1000–1050 °C). Mixing between two chemically distinct magmas is also evidenced by the occurrence of reverse zoned plagioclase phenocrysts with resorbed sodic cores and re-growth of sieve-textured calcic mantles. Conversely, plagioclase rims exhibit disequilibrium compositions addressed to decompression kinetics (~ 10 − 3 MPa/s) driven by rapid magma ascent to the surface (~ 0.03 m/s). Major and trace element modelling excludes fractional crystallization as the primary mechanism controlling the bulk rock variability, whereas geochemical data align along a mixing trend between two end-members representative of the primitive basalt and the differentiated basaltic andesite. Trace element and isotope data indicate that the primary source of magmatism is an enriched MORB-like mantle with the contribution of fluxes of metasomatic fluids and/or melts produced by the subducted slab. The role played by slab-fluid inputs of carbonate origin and slab-melts from the hemipelagic sediments seems to be minimal. Assimilation/contamination processes of magmas by crustal rocks are also negligible. In contrast, the geochemical signature of magmas is greatly influenced by slab-derived aqueous fluids produced prevalently by progressive dehydration of marine sediments and altered basaltic crust.

Ocean island volcanoes erupt a wide range of magmatic compositions via a diverse range of eruptive styles. Understanding where and how these melts evolve is thus an essential component in the anticipation of future volcanic activity. Here we examine the role of crustal structure and magmatic flux in controlling the location, evolution and ultimately composition of melts at Ascension Island. Located in the South Atlantic, Ascension Island is an ocean island volcano that has produced a continuum of eruptive compositions from basalt to rhyolite in its 1 Myr subaerial eruptive history. Volcanic rocks broadly follow a silica-undersaturated subalkaline evolutionary trend, and new data presented here show a continuous compositional trend from basalt through trachyte to rhyolite. Detailed petrographic observations are combined with in situ geochemical analyses of crystals and glass, and new whole-rock major and trace element data from mafic and felsic pyroclastic and effusive deposits that span the entire range in eruptive ages and compositions found on Ascension Island. These data show that extensive fractional crystallization is the main driver for the production of felsic melts for Ascension Island, a volcano built on thin, young, oceanic crust. Strong spatial variations in the compositions of erupted magmas reveal the role of a heterogeneous lower crust; differing degrees of interaction with a zone of plutonic rocks are responsible for the range in mafic lava compositions, and for the formation of the central and eastern felsic complexes. A central core of nested, small-scale plutonic, or mush-like, bodies inhibits the ascent of mafic magmas, allowing sequential fractional crystallization within the lower crust, and generating felsic magmas in the core of the island. There is no evidence for magma mixing preserved in any of the studied eruptions, suggesting that magma storage regions are transient, and material is not recycled between eruptions.

Ash aggregation is a common phenomenon in particle-laden environments of volcanic eruption plumes and pyroclastic density currents. Many of these initially fragile aggregates gain sufficient mechanical strength to remain intact after atmospheric transport and deposition. Several processes contribute to ash aggregate stability, including electrostatic and hydrostatic bonding, ice formation, and cementation by salt precipitates. Here, we compare leachate chemistry from aggregates from a variety of eruption and sedimentation conditions, ranging from dry magmatic eruptions with immediate deposition, to eruptions through seawater. The leachate data shows that the broad window of opportunity for aggregation and aggregate break-up may be used to qualitatively constrain suspended ash concentration and its temporal evolution. We show that aggregation rate and aggregate stability largely depend on the availability of external water and salt source. In particular, high humidity and extensive salt precipitation in seawater environments, such as during the Surtseyan eruptions, promote high aggregation rates and aggregate stability, with accordingly accentuated proximal deposition and aggregate concentration in the deposits. On the other hand, low humidity and salt concentrations during dry magmatic eruptions promote less aggregation and more efficient aggregate break-up, explaining the rarity of aggregates in the deposits. These results have strong implications for the ash budget in volcanic plumes and associated models of plume dispersal and related hazards.

Many volcanoes worldwide still have poorly resolved eruption histories, with the date of the last eruption often undetermined. One such example is Ascension Island, where the timing of the last eruption, and consequently, the activity status of the volcano, is unclear. Here, we use the 40Ar/39Ar dating technique to resolve ages of the three youngest lava flows on the island, which are hawaiites and mugearite with 1.5 – 1.9 wt% K2O. In dating these lavas, we provide the first evidence of Holocene volcanic activity on Ascension (0.51 ± 0.18 ka; 0.55 ± 0.12 ka; 1.64 ± 0.37 ka), determining that it should be classed as an active volcanic system. In addition, we demonstrate that the 40Ar/39Ar method can reproducibly date mafic lava flows younger than 1 ka, decreasing the gap between recorded history and geological dating. These results offer new prospects for determining patterns of late-Holocene volcanic activity; critical for accurate volcanic hazard assessment.

The Miocene Yamanlar composite volcano is located in the central part of a shear zone in western Turkey. The volcano's deeply-eroded interior provides excellent three-dimensional exposure of a faulted caldera-floor and caldera-fill rocks as well as surrounding extracaldera ignimbrites. We present a much-revised stratigraphy and geological map of Yamanlar in order to quantify the evolutionary stages of the volcano. The Yamanlar volcanic cone was composed of > 800 m of basaltic-andesite to andesite lavas and lava domes. The volcano underwent at least one phase of caldera formation associated with an explosive eruption that deposited an ignimbrite sheet within and outside the caldera. Lithofacies architecture analysis is applied to the proximal and medial exposures of the Early-Middle Yamanlar Formation, which occurs outside of the caldera. Field evidence of the succession indicates a caldera-forming eruption. Our results indicate that the formation of the Yamanlar caldera resulted from one major catastrophic eruption that generated several sustained pyroclastic density currents (PDCs) subdivided by fall deposits with sharp contacts. The ignimbrite sheet is composed of four flow units. The presence of numerous coarse-grained lithic-rich horizons within the ignimbrite sheet is consistent with caldera subsidence. Post-caldera volcanism is indicated by intrusions and lava domes erupted along the inferred caldera-bounding faults, some of which record ~ 90 m of displacement. Widespread, coarse-grained breccias that overlie the ignimbrite sheet are interpreted as debris avalanche deposits resulting from gravitational failure of the flanks of the volcano or the caldera wall during or after caldera subsidence.

Most kimberlite rocks contain large proportions of ellipsoidal-shaped xenocrystic olivine grains that are derived mainly from disaggregation of peridotite. Here, we describe the shapes, sizes and surfaces of olivine grains recovered from kimberlite lavas erupted from the Quaternary Igwisi Hills volcano, Tanzania. The Igwisi Hills kimberlitic olivine grains are compared to phenocrystic olivine, liberated from picritic lavas, and mantle olivine, liberated from a fresh peridotite xenolith. Image analysis, scanning electron microscopy imagery and laser microscopy reveal significant differences in the morphologies and surface features of the three crystal populations. The kimberlitic olivine grains form smooth, rounded to ellipsoidal shapes and have rough flaky micro-surfaces that are populated by impact pits. Mantle olivine grains are characterised by flaked surfaces and indented shapes consistent with growth as a crystal aggregate. Phenocrystic olivine exhibit faceted, smooth-surfaced crystal faces. We suggest that the unique shape and surface properties of the Igwisi Hills kimberlitic olivine grains are products of the transport processes attending kimberlite ascent from mantle source to surface. We infer that the unique shapes and surfaces of kimberlitic olivine grains result from three distinct mechanical processes attending their rapid transport through the thick cratonic mantle lithosphere: (1) penetrative flaking from micro-tensile failure induced by rapid decompression; (2) sustained abrasion and attrition driven by particle–particle collisions between grains within a turbulent, volatile-rich flow regime; and (3) higher-energy particle–particle collisions producing impact cavities superimposed on decompression structures. The combination of these processes during the rapid ascent of kimberlite magmas is responsible for the distinctive ellipsoidal shape of olivine xenocrysts found in kimberlites worldwide.

Geochemical data are presented for the kimberlitic Holocene Igwisi Hills volcanoes (IHV), Tanzania, which preserve extra-crater lavas and pyroclastic rocks. Their young age and exceptional preservation enable investigation of kimberlite magma compositions and alteration pathways of kimberlites. The IHV lavas have a variable matrix assemblage dominated by calcite, olivine and a serpentine-like mineral (termed serpentine-X). Minor primary groundmass phases include apatite, phlogopite, monticellite, perovskite and spinel representing late-stage crystalisation. Secondary phases include hydrogarnet, a mixed-layer chlorite–vermiculite–montmorrilonite, minor brucite and low-temperature oxides and clays such as goethite and jamborite. The matrix of pyroclastic rocks is dominated by calcite with fewer groundmass phases. The parental magmas are inferred to have had ~ 21 wt.% SiO2, ~ 22 wt.% CaO, ~ 23 wt.% MgO and Mg# ~ 70. The IHV are classified as calcite kimberlites. The total volatile concentrations of the primary melt are ~ 14 wt.%, which predominantly consists of CO2 although the H2O content is also high. Whole-rock geochemical analyses indicate minor crustal contamination, low-temperature alteration and weathering. Pervasive serpentinisation in both lavas and pyroclastic rocks results from low-temperature alteration induced by the circulation of meteoric waters during cooling. Serpentine-X is potentially a new mineral and is richer in Al2O3 and FeO and poorer in SiO2 than published analyses of serpentine minerals. These compositions are attributed to a 1:2 mixture of serpentine and hydrotalcite. We propose that serpentine-X has replaced a reactive, late stage residual silicate glass, the existence of which helps explain the presence of vesicular scoria (similar to glassy basaltic pyroclasts) and viscous kimberlite lavas.

The Younger Dryas is the most well-documented millennial-scale cooling event of the Quaternary, but the mechanisms responsible for its initiation remain elusive. Here we use a recently revised chronology for the GISP2 ice core ion dataset to identify a large volcanic sulphur spike coincident with both the sulphur-rich Laacher See volcanic eruption and the onset of Younger Dryas-related cooling (GS-1) in Greenland. Lake sediment and stalagmite records confirm that the eruption's timing was indistinguishable from the onset of cooling across the North Atlantic, but that it preceded westerly wind repositioning over central Europe by ~ 200 years. We suggest that the initial short-lived volcanic sulphate aerosol cooling was amplified by oceanic circulation shifts or sea ice expansion, gradually cooling the North Atlantic region and incrementally shifting the mid-latitude westerlies to the south. The aerosol-related cooling probably only lasted 2–4 years, and the majority of Younger Dryas-related cooling was instead due to this positive feedback, which was particularly effective during the intermediate ice volume conditions characteristic of ~ 13 ka BP. We conclude that the large and sulphur-rich Laacher See eruption should be considered a viable trigger for the Younger Dryas.

Hawaiian basaltic eruptions commonly initiate as a fissure, producing fountains, spattering, and clastogenic lava flows. Most fissures rapidly localize to form a small number of eruptive vents, the location of which may influence the subsequent distribution of lava flows and associated hazards. We present results from a detailed field investigation of the proximal deposits of episode 1 of the 1969 fissure eruption of Mauna Ulu, Kīlauea, Hawai‘i. Exceptional preservation of the deposits allows us to reconstruct vent-proximal lava drainage patterns and to assess the role that drainage played in constraining vent localization. Through detailed field mapping, including measurements of the height and internal depth of lava tree moulds, we reconstruct high-resolution topographic maps of the pre-eruption ground surface, the lava high-stand surface and the post-eruption ground surface. We calculate the difference in elevation between pairs of maps to estimate the lava inundation depth and lava drainage depth over the field area and along different segments of fissure. Aerial photographs collected during episode 1 of the eruption allow us to locate those parts of the fissure that are no longer exposed at the surface. By comparing with the inundation and drainage maps, we find that fissure segments that were inundated with lava to greater depths (typically 1–6 m) during the eruption later became foci of lava drainage back into the fissure (internal drain-back). We infer that, in these areas, lava ponding over the fissure suppressed discharge of magma, thereby favouring drain-back and stagnation. By contrast, segments with relatively shallow inundation (typically less than ~ 1 m), such as where the fissure intersects pre-eruptive topographic highs, or where flow away from the vent (outflow) was efficient, are often associated with sub-circular vent geometries in the post-eruption ground surface. We infer that these parts of the fissure became localization points for ongoing magma ascent and discharge. We conclude that lava inundation and drainage processes in basaltic fissure eruptions can play an important role in controlling their localization and longevity.

Offshore sequences of volcaniclastic rocks (such as hyaloclastite deposits) are poorly understood in terms of their rock properties and their response to compaction and burial. As petroleum exploration targets offshore volcanic rifted margins worldwide, understanding of volcanic rock properties becomes important both in terms of drilling and how the rocks may behave as seals, reservoirs, or permeability pathways. The Hawaiian Scientific Drilling Project phase II in 2001 obtained a 3 km-(2-mi)-long core of volcanic and volcaniclastic rocks that records the emergence of the largest of the Hawaiian islands. Core recovery of 2945 m (9662 ft) resulted in an unparalleled data set of volcanic and volcaniclastic rocks. Detailed logging, optical petrology, and major element analysis of two sections at depths 1831–1870 and 2530–2597 m (6007–6135 and 8300–8520 ft) are compared to recovered petrophysical logs (gamma ray, resistivity, and P-wave velocity). This study concludes deviation in petrophysical properties does not seem to correlate to changes in grain size or clast sorting, but instead correlates with alteration type (zeolite component) and bulk mineralogy (total olivine phenocryst percentage component). These data sets are important in helping to calibrate well-log responses through hyaloclastite intervals in areas of active petroleum exploration such as the North Atlantic (e.g., Faroe-Shetland Basin, United Kingdom, and Faroe Islands, the Norwegian margin and South Atlantic margins bordering Brazil and Angola).

We assess bias in the record of kimberlite volcanism by using newly acquired size data on more than 900 kimberlite bodies from 12 kimberlite fields eroded to depths of between 0 m and >1200 m, and by a comparison with intraplate monogenetic basaltic volcanic fields. Eroded kimberlite fields are composed of pipes (or diatremes) and dikes, and within any one kimberlite field, regardless of erosion level, kimberlite bodies vary in area at Earth’s surface over 2–3 orders of magnitude. Typically 60%–70% of the bodies are

The Orapa Diamond Mine (Republic of Botswana) exposes a bi-lobate kimberlite pipe that erupted during the Late-Cretaceous epoch (~ 93 Ma) through Archaean basement and volcano-sedimentary rocks of the Karoo Supergroup. Geological mapping of the crater zone of the South Pipe has revealed a 15-25 m thick in-situ kimberlite pyroclastic flow deposit. The pyroclastic deposit fills in the crater and completely drapes lower units, indicating that the parent flow originated from an adjacent kimberlite pipe. The unit comprises a basal coarse lithic concentration layer exhibiting imbricated clasts, which grades upwards into massive poorly sorted lapilli tuff. The tuff contains abundant sub-vertical degassing structures defined by lithic enrichment and depletion in fine-grained material. Degassing structures commonly emanate from blocks in the basal layer. The presence of degassing structures and a coarse basal layer distinguishes this deposit from pipe-filling massive volcaniclastic kimberlite, which is typically homogeneous in terms of texture and clast size over distances on the order of 100s of metres. Studies of the thermal remanent magnetism in basalt clasts from the deposit, together with serpentine-diopside assemblages, indicate that it was emplaced at elevated temperatures on the order of 200-440 °C, consistent with deposition from a pyroclastic flow. The lithofacies characteristics can be explained by the interaction of the pyroclastic flow with the complex topography of a pre-existing crater. © 2009 Elsevier B.V. All rights reserved.

Pyroclastic cones built along basaltic fissures provide important volcanological information, but it is often difficult to examine the early-erupted products due to burial by later products. Furthermore, it is rare to see the link between the feeder dyke and overlying cone fully exposed. In this study, we detail the architecture of a hybrid spatter cone, scoria half-cone and feeder dyke that has been dissected to below the pre-eruption surface by glacial floods. The cones were constructed during the 6–8 ka Rauðuborgir-Kvensoðul fissure eruption in North Iceland during Hawaiian- and Strombolian-style activities. Widening of their feeder dyke in the shallow sub-surface to produce an upward flaring morphology was accommodated by country rock removal and elastic host rock deformation. Ballistic calculations and stratigraphic relationships indicate that the scoria half-cone was constructed early in the eruption from the deposits of a lava fountain ~100 m high. A decline in fountain height and the generation of abundant welded deposits resulted in the formation of a nested spatter cone within the scoria half-cone. The cones are similar in structure and size to the hybrid scoria and spatter cones produced during the 15-km3 1783 Laki eruption and serve as a valuable window into the construction of pyroclastic edifices during basaltic fissure eruptions.

Particle aggregation governs the sedimentation of small volcanic tephra particles from ash clouds generated by explosive volcanic eruptions. Particle aggregates have larger sizes, lower densities, and higher terminal fall velocities than individual ash particles. Critically, this process reduces the atmospheric lifetime of volcanic ash clouds. Aggregation increases sedimentation rates in proximal regions and correspondingly decreases airborne ash mass loadings in distal regions. Aggregation processes and products vary with distance from a volcano. Proximal aggregates are larger (up to centimeter size), may have concentric internal structures, may be strongly bound (cemented and/or frozen), and can be associated with pyroclastic density currents. Distal aggregates are smaller (submillimeter), less well structured, weakly bound, and are deposited exclusively from the base of ash clouds. Bonding forces for individual ash particles include hydrostatic bonds (liquid and ice water) and electrostatic forces, and the availability of liquid determines the aggregate morphology. Gravitational convective instabilities observed in recent eruption clouds influence aggregation rates. Recently, much progress has been made in documenting and understanding aggregation through field studies, laboratory experiments, and numerical modeling. However, there remains uncertainty over the roles of eruption source parameters (eg, particle size distribution, erupted mass, eruption column height, cloud liquid content, and temperature), the eruption plume temperature lapse rate, and environmental parameters in determining the nature and distribution of aggregates. This chapter will provide an overview of aggregates observed falling out of recent volcanic clouds, aggregates found in deposits, and key formation mechanisms.

We present an impactoclastic density current model for terrestrial meteorite impact ejecta emplacement that is based on a hitherto-unreported threefold sequence of lithofacies in the recently identified Stac Fada impact ejecta outflow blanket in Scotland. Massive suevite (division A) grades seamlessly up into massive suevite containing whole and broken accretionary lapilli (division B), and this is overlain by a thin layer of clast-supported dust pellets (division C). The sequence closely resembles sequences in accretionary lapilli-bearing ignimbrites emplaced by pyroclastic density currents at volcanoes, and we deduce similar emplacement mechanisms. We propose that ≥99% of the thickness of the Stac Fada ejecta blanket as seen at outcrop was deposited from a single depletive (spatially decelerating), granular fluid–based density current that rapidly waxed and then waned. A previously unreported thin layer of pellets (division C) records direct fallout from a residual atmospheric dust plume. We pro...

Mountain lee waves are a form of atmospheric gravity wave that is generated by flow over mountain topography. Mountain lee waves are of considerable interest, because they can produce drag that affects the general circulation, windstorms, and clear-air turbulence that can be an aviation hazard, and they can affect ozone abundance through mixing and inducing polar stratospheric clouds. There are difficulties, however, in measuring the three-dimensional wind velocities in high-altitude mountain waves. Mountain waves are routinely used by sailplane pilots to gain altitude. Methods are described for estimating three-dimensional wind velocities in mountain waves using data collected during sailplane flights. The data used are the logged sailplane position and airspeed (sailplane speed relative to the local air mass). An algorithm is described to postprocess this data to estimate the three-dimensional wind velocity along the flight path, based on an assumption of a slowly varying horizontal wind velocity. The method can be applied to data from dedicated flights or potentially to existing flight records used as sensors of opportunity. The methods described are applied to data from a sailplane flight in lee waves of the Sierra Nevada in California.

Aggregation of airborne particles is an important way in which the atmosphere is cleansed of fine dust particles, such as following explosive eruptions and meteorite impacts. We identify successive stages in the growth history of particle aggregates based upon well-preserved ash aggregate–bearing pyroclastic layers on Tenerife. The layers are persistently organized into couplets made up of a lower ignimbrite layer and an upper, widespread coignimbrite ash-fall layer. The upper part of each ignimbrite contains whole and fragmented concentric-laminated accretionary lapilli, whereas the overlying coignimbrite ash-fall layer lacks accretionary lapilli and is composed of framework-supported smaller and nonlaminated ash pellets, sometimes slightly deformed or partly disaggregated. The pellets resemble the cores of the larger accretionary lapilli in the underlying ignimbrite layer. These field relations are repeated numerous times in several different successions, and they indicate that ash pellets, not accretionary lapilli, form within the coignimbrite ash plumes. Some pellets fell directly to the ground, producing coignimbrite ash-fall layers, but others settled into pyroclastic density currents, where they accreted successive concentric laminations of fine ash as they circulated through the variously turbulent levels of the stratified current, and heat of the lower part of the current dried and partly lithified them into brittle accretionary lapilli. The fully formed whole and broken accretionary lapilli were then deposited from the current along with ash and pumice lapilli. Numerous ignimbrite veneers on Tenerife have the form of ash layers, a few centimeters thick, that drape topography and locally contain matrix-supported accretionary lapilli. Most volcanoes lack laterally continuous field exposure, and such accretionary lapilli–bearing layers might be mistaken for ash-fall deposits. We highlight the value of careful distinction between different types of ash aggregate facies when interpreting the origin of pyroclastic deposits, for example, during hazard assessments.

Lithofacies in kimberlite pipes in southern Africa exhibit features consistent with welded pyroclastic rocks. These include flared conduit-filling geometries, abundant lithic clasts, lithic clast layers, subhorizontal clast fabrics, gradational contacts with volcaniclastic rocks and sintered and coalesced globular ash, and lapilli and melt-coated particles. The welding dynamics of kimberlite pyroclasts differ from those of glassy, vesiculated pyroclasts in silicic volcanic systems. Low melt viscosity (∼0.1 Pa s) results in the efficient separation of volatiles and melt and the breakup of magma into nonvesicular spherical droplets. The glassy state is difficult to form in silica-deficient magmas because the crystallization kinetics are fast in low-viscosity melts. Three pyroclastic lithofacies are recognized that primarily relate to the state of the initial melt phase in the pyroclasts on deposition: (1) densely welded kimberlite forms where the initial melt phase in pyroclasts remains as pure mel...

Geological mapping has allowed constraints to be placed on the eruption mechanisms involved in the formation of the Late Permian–Early Triassic Jwaneng Centre kimberlite pipe, Botswana. Twelve lithofacies and three lithofacies associations (LFA 1–3) are recognised. LFA 1 comprises massive to bedded volcaniclastic kimberlite and marginal shale breccias and outcrops over 65% of the surface area of the pipe. It is characterised by a lithic population dominated by Transvaal shale clasts. LFA 1 grades into LFA 2, which comprises massive and bedded volcaniclastic kimberlite and volcaniclastic breccias and outcrops over 19% of the surface area of the pipe. The lithic population of LFA 2 is dominated by contorted and fluidal-outlined Karoo-age mudstones and siltstones. LFA 3 comprises a wedge-shaped unit in the north of the pipe and consists of a series of allochthonous megablocks of sedimentary and volcaniclastic strata. The juvenile clast type and matrix mineral assemblages of the volcaniclastic deposits in the Centre Pipe differ from those in many other southern African kimberlite pipes. Various emplacement models for kimberlite pipes are discussed and evaluated in the light of the new geological data. Both a maar–diatreme model and an explosive volatile-driven eruption model could account for much of the geology of the Centre Pipe and distinguishing between the two models based on deposits alone is difficult. There is strong circumstantial evidence for ambient conditions favourable to phreatomagmatism at the time of the eruption, and the influence of external water may explain the differences between the Jwaneng Centre Pipe and the Class 1 kimberlites common across Southern Africa in terms of both the juvenile clasts and of the inter-clast cement. However, low abundances of some types of lithic inclusions derived from major country rock units pose an unresolved problem for a classic maar–diatreme model of pipe formation.

K2 is a steep-sided kimberlite pipe with a complex internal geology. Geological mapping, logging of drillcore and petrographic studies indicate that it comprises layered breccias and pyroclastic rocks of various grain sizes, lithic contents and internal structures. The pipe comprises two geologically distinct parts: K2 West is a layered sequence of juvenile- and lithic-rich breccias, which dip 20–45° inwards, and K2 East consists of a steep-sided pipe-like body filled with massive volcaniclastic kimberlite nested within the K2 pipe. The layered sequence in K2 West is present to > 900 m below present surface and is interpreted as a sequence of pyroclastic rocks generated by explosive eruptions and mass-wasting breccias generated by rock fall and sector collapse of the pipe walls: both processes occurred in tandem during the infill of the pipe. Several breccia lobes extend across the pipe and are truncated by the steep contact with K2 East. Dense pyroclastic rocks within the layered sequence are interpreted as welded deposits. K2 East represents a conduit that was blasted through the layered breccia sequence at a late stage in the eruption. This phase may have involved fluidisation of trapped pyroclasts, with loss of fine particles and comminution of coarse clasts. We conclude that the K2 kimberlite pipe was emplaced in several distinct stages that consisted of an initial explosive enlargement, followed by alternating phases of accumulation and ejection.

The Glaramara tuff presents extensive exposures of the medial and distal deposits of a large tuff ring (original area >800 km2) that grew within an alluvial to lacustrine caldera basin. Detailed analysis and correlation of 21 sections through the tuff show that the eruption involved phreatomagmatic to magmatic explosions resulting from the interaction of dacitic magma and shallow-aquifer water. As the eruption developed to peak intensity, numerous, powerful single-surge pyroclastic density currents reached beyond 8 km from the vent, probably >12 km. The currents were strongly depletive and deposited coarse lapilli (>5 cm in diameter) up to 5 km from source, with only fine ash and accretionary lapilli deposited beyond this. As the eruption intensity waned, currents deposited fine ash and accretionary lapilli across both distal and medial regions. The simple wax–wane cycle of the eruption produced an overall upward coarsening to fining sequence of the vertical lithofacies succession together with a corresponding progradational to retrogradational succession of lithofacies relative to the vent. Various downcurrent facies transitions record transformations of the depositional flow-boundary zones as the depletive currents evolved with distance, in some cases transforming from granular fluid-based to fully dilute currents primarily as a result of loss of granular fluid by deposition. The tuff-ring deposits share several characteristics with (larger) ignimbrite sheets formed during Plinian eruptions and this underscores some overall similarities between pyroclastic density currents that form tuff rings and those that deposit large-volume ignimbrites. Tuff-ring explosive activity with such a wide area of impact is not commonly recognized, but it records the possibility of such currents and this should be factored into hazard assessments.

Observations in the USA, Iceland and Tenerife, Canary Islands reveal how processes occurring during basaltic eruptions can result in complex physical and stratigraphic relationships between lava and proximal tephra fall deposits around vents. Observations illustrate how basaltic lavas can disrupt, dissect (spatially and temporally) and alter sheet-form fall deposits. Complexity arises through synchronous and alternating effusive and explosive activity that results in intercalated lavas and tephra deposits. Tephra deposits can become disrupted into mounds and ridges by lateral and vertical displacement caused by movement (including inflation) of underlying pāhoehoe lavas and clastogenic lavas. Mounds of tephra can be rafted away over distances of 100 s to 1,000 s m from proximal pyroclastic constructs on top of lava flows. Draping of irregular topography by fall deposits and subsequent partial burial of topographic depressions by later lavas can result in apparent complexity of tephra layers. These processes, deduced from field relationships, have resulted in considerable stratigraphic complexity in the studied proximal regions where fallout was synchronous or alternated with inflation of subjacent lava sheets. These mechanisms may lead to diachronous contact relationships between fall deposits and lava flows. Such complexities may remain cryptic due to textural and geochemical quasi-homogeneity within sequences of interbedded basaltic fall deposits and lavas. The net effect of these processes may be to reduce the usefulness of data collected from proximal fall deposits for reconstructing basaltic eruption dynamics.

Rootless cones result from the explosive interaction between lava flows and underlying water-saturated sediment or volcaniclastic deposits. Rootless explosions can represent a significant far-field hazard during basaltic eruptions, but there are few detailed studies of their deposits. A rootless cone field in the 8.5 Ma Ice Harbor flow field of the Columbia River Basalt Province, NW USA, is revealed by sections through rootless conduit and cone structures. The Ice Harbor lava flow hosting the rootless cones was emplaced across a floodplain or lacustrine environment that had recently been mantled by a layer of silicic volcanic ash from a major explosive eruption. Our observations indicate a two-stage growth model for the rootless cones: (1) initial explosions generated sediment-rich tephra emplaced by fallout and pyroclastic density currents and (2) later weaker explosions that generated spatter-rich fountains. Variable explosive activity resulted in a wide range of pyroclast morphologies and vesicularities. Cross-sections through funnel-shaped conduits also show how the conduits were constructed and stabilised. The growth model is consistent with decreasing water availability with time, as inferred for rootless cones described in Iceland. The Ice Harbor rootless cones provide further lithological data to help distinguish between rootless cone-derived tephra and tephra generated above an erupting dyke.

This chapter outlines the physical characteristics of different types of pyroclastic density current deposits and reviews what field studies over the past two decades have told us about the transport and depositional processes operating within the parent currents.

Deep, steep-sided kimberlite pipes in southern Africa are normally partially filled with multiple units of a characteristically massive, structureless volcaniclastic rock, here termed massive volcaniclastic kimberlite (MVK). These units can be arranged in a pseudo-concentric, nested ‘pipes-within-pipes’ structure. Several key observations on typical MVK from the Venetia kimberlite pipes, South Africa, indicate that fluidisation may have been an important process during its emplacement. These include: (1) the thorough mixing together of juvenile components and of lithic components derived from all stratigraphic levels of the country rock and; (2) a matrix composed of void-filling minerals related to hydrothermal metamorphism (mainly diopside and serpentine), which indicates that the primary deposit had a high porosity (> 50%); and (3) particle size distributions poor in fine ash ( 10 cm). Analogue experiments utilising a sand bed laced with marker horizons were conducted in order to investigate the role of fluidisation in the formation of MVK. High-pressure gas, fed through the bed from a point source, resulted in the formation of an upwardly diverging pipe structure of thoroughly mixed fluidised material bounded by undisturbed sand. Strong upward gas flow along the centre of the pipe is characteristically bubbly and results in internal circulation with downward moving regions at the pipe margins. Analysis of the experimental results suggests that the gas velocity decreases linearly with height and has a Gaussian distribution of vertical velocity in the cross-flow direction. A decrease in the gas flow rate resulted in the development of nested pipes reminiscent of the ‘pipes-within-pipes’ structures in kimberlite pipes. The results suggest that fluidisation could be a major control on the structure and sorting of deposits in kimberlite pipes. We propose that the fluidisation of particles in a kimberlite pipe occurs during the final stages of the eruption when erupting pyroclasts and incorporated fragmented lithic material can no longer be ejected out of the deep, wide conduit. This bed is subject to quasi-sustained fluidisation by the erupting gas-particle flow, which imparts on it the distinctive characteristics of a massive well-mixed, poorly sorted deposit.

Kimberlite volcanism involves the ascent of low viscosity (0.1 to 1 Pa s) and volatile-rich (CO2 and H2O) ultrabasic magmas from depths of 150 km or greater. Theoretical models and empirical evidence suggest ascent along narrow (∼1 m) dykes at speeds in the range > 4 to 20 m/s. With typical dyke breadths of 1 to 10 km, magma supply rates are estimated in the range 102 to 105 m3/s with eruption durations of many hours to months. Based on observations, theory and experiments we propose a four-stage model for kimberlite eruptions to explain the main geological relationships of kimberlites. In stage I magma reaches the Earth's surface along fissures and erupts explosively due to their high volatile content. The early flow exit conditions are overpressured with choked flow conditions; an exit velocity of ∼200 m/s is estimated as representative. Explosive expansion and near surface overpressures initiate crater and pipe formation from the top downwards. In stage II under-pressures (the difference between the lithostatic pressure and pressure of the erupting mixture) develop within the evolving pipe causing rock bursting at depth, undermining overlying rocks and causing down-faulting and crater rim slumping. Rocks falling into the pipe interior are ejected by the strong explosive flows. Stage II is the erosive stage of pipe formation. As the pipe widens and deepens larger under-pressures develop enhancing pipe wall instability. A critical threshold is reached when the exit pressure falls to one atmosphere. As the pipe widens and deepens further the gas exit velocity declines and ejecta becomes trapped within the pipe, initiating stage III. A fluidised bed of pyroclasts develops within the pipe as the eruption wanes to form typical massive volcaniclastic kimberlite. Marginal breccias represent the transition between stages II and III. After the eruption stage IV is a period of hydrothermal metamorphism (principally serpentinisation) and alteration as the pipe cools and meteoric waters infiltrate the hot pipe fill. Following an eruption an open crater can be filled by kimberlite- and country-rock derived sediments, forming the crater-facies.

The 273 ka Poris Formation in the Bandas del Sur Group records a complex, compositionally zoned explosive eruption at Las Canadas caldera on Tenerife, Canary Islands. The eruption produced widespread pyroclastic density currents that devastated much of the SE of Tenerife, and deposited one of the most extensive ignimbrite sheets on the island. The sheet reaches ~ 40-m thick, and includes Plinian pumice fall layers, massive and diffuse-stratified pumiceous ignimbrite, widespread lithic breccias, and co-ignimbrite ashfall deposits. Several facies are fines-rich, and contain ash pellets and accretionary lapilli. Eight brief eruptive phases are represented within its lithostratigraphy. Phase 1 comprised a fluctuating Plinian eruption, in which column height increased and then stabilized with time and dispersed tephra over much of the southeastern part of the island. Phase 2 emplaced three geographically restricted ignimbrite flow-units and associated extensive thin co-ignimbrite ashfall layers, which contain abundant accretionary lapilli from moist co-ignimbrite ash plumes. A brief Plinian phase (Phase 3), again dispersing pumice lapilli over southeastern Tenerife, marked the onset of a large sustained pyroclastic density current (Phase 4), which then waxed (Phase 5), covering increasingly larger areas of the island, as vents widened and/or migrated along opening caldera faults. The climax of the Poris eruption (Phase 6) was marked by widespread emplacement of coarse lithic breccias, thought to record caldera subsidence. This is inferred to have disturbed the magma chamber, causing mingling and eruption of tephriphonolite magma, and it changed the proximal topography diverting the pyroclastic density current(s) down the Guimar valley (Phase 7). Phase 8 involved post-eruption erosion and sedimentary reworking, accompanied by minor down-slope sliding of ignimbrite. This was followed by slope stabilization and pedogenesis. The fines-rich lithofacies with abundant ash pellets and accretionary lapilli record agglomeration of ash in moist ash plumes. They resemble phreatomagmatic deposits, but a phreatomagmatic origin is difficult to establish because shards are of bubble-wall type, and the moisture may have arisen by condensation within ascending thermal co-ignimbrite ash plumes that contained atmospheric moisture enhanced by that derived from the evaporation of seawater where the hot pyroclastic currents crossed the coast. Ash pellets formed in co-ignimbrite ash-clouds and then fell through turbulent pyroclastic density currents where they accreted rims and evolved into accretionary lapilli.

A much-revised Quaternary stratigraphy is presented for ignimbrites and pumice fall deposits of the Bandas del Sur, in southern Tenerife. New 40Ar/39Ar data obtained for the Arico, Granadilla, Fasnia, Poris, La Caleta and Abrigo formations are presented, allowing correlation with previously dated offshore marine ashfall layers and volcaniclastic sediments. We also provide a minimum age of 287±7 ka for a major sector collapse event at the Güimar valley. The Bandas del Sur succession includes more than seven widespread ignimbrite sheets that have similar characteristics, including widespread basal Plinian layers, predominantly phonolite composition, ignimbrites with similar extensive geographic distributions, thin condensed veneers with abundant diffuse bedding and complex lateral and vertical grading patterns, lateral gradations into localized massive facies within palaeo-wadis, and widespread lithic breccia layers that probably record caldera-forming eruptions. Each ignimbrite sheet records substantial bypassing of pyroclastic material into the ocean. The succession indicates that Las Cañadas volcano underwent a series of major explosive eruptions, each starting with a Plinian phase followed by emplacement of ignimbrites and thin ash layers, some of co-ignimbrite origin. Several of the ignimbrite sheets are compositionally zoned and contain subordinate mafic pumices and banded pumices indicative of magma mingling immediately prior to eruption. Because passage of each pyroclastic density current was characterized by phases of non-deposition and erosion, the entire course of each eruption is incompletely recorded at any one location, accounting for some previously perceived differences between the units. Because each current passed into the ocean, estimating eruption volumes is virtually impossible. Nevertheless, the consistent widespread distributions and the presence of lithic breccias within most of the ignimbrite sheets suggest that at least seven caldera collapse eruptions are recorded in the Bandas del Sur succession and probably formed a complex, nested collapse structure. Detailed field relationships show that extensive ignimbrite sheets (e.g. the Arico, Poris and La Caleta formations) relate to previously unrecognized caldera collapse events. We envisage that the evolution of the nested Las Cañadas caldera is more complex than previously thought and involved a protracted history of successive ignimbrite-related caldera collapse events, and large sector collapse events, interspersed with edifice-building phases.

New geochemical and isotopic data on volcanic rocks spanning the period ~75–50 ka BP on Ischia volcano, Italy, shed light on the evolution of the magmatic system before and after the catastrophic, caldera-forming Monte Epomeo Green Tuff (MEGT) eruption. Volcanic activity during this period was influenced by a large, composite and differentiating magmatic system, replenished several times with isotopically distinct magmas of deep provenance. Chemical and isotopic variations highlight that the pre-MEGT eruptions were fed by trachytic/phonolitic magmas from an isotopically zoned reservoir that were poorly enriched in radiogenic Sr and became progressively less radiogenic with time. Just prior to the MEGT eruption, the magmatic system was recharged by an isotopically distinct magma, relatively more enriched in radiogenic Sr with respect to the previously erupted magmas. This second magma initially fed several SubPlinian explosive eruptions and later supplied the climactic, phonolitic-to-trachytic MEGT eruption(s). Isotopic data, together with erupted volume estimations obtained for MEGT eruption(s), indicate that >5–10 km3 of this relatively enriched magma had accumulated in the Ischia plumbing system. Geochemical modelling indicates that it accumulated at shallow depths (4–6 km), over a period of ca. 20 ka. After the MEGT eruption, volcanic activity was fed by a new batch of less differentiated (trachyte-latite) magma that was slightly less enriched in radiogenic Sr. The geochemical and Sr–Nd-isotopic variations through time reflect the upward flux of isotopically distinct magma batches, variably contaminated by Hercynian crust at 8–12 km depth. The deep-sourced latitic to trachytic magmas stalled at shallow depths (4–6 km depth), differentiated to phonolite through crystal fractionation and assimilation of a feldspar-rich mush, or ascended directly to the surface and erupted.

The 1300 km3 tholeiitic lava flow field of the 14.98 Ma Roza Member of the Columbia River Basalt Province has the best-preserved vent system of any known continental flood basalt. Detailed geological mapping and logging of the exposed pyroclastic rocks along the >180-km-long vent system enable the reconstruction of pyroclastic edifices (partial cones) built around vents. The pyroclastic cones differ from those constructed during typical basaltic effusive eruptions and are characterized by low to moderate slope angles (1 km) fountains enhanced by fallout from the lower parts of convective plumes that rose above the fountains.

Unraveling the eruptive history of the Island of Ischia (southern Italy) is problematic due to its burial, caldera collapse, resurgent uplift and erosion. Here, we present new major and trace element glass data for 39–75 ka proximal tephra deposits, including those of the caldera-forming Monte Epomeo Green Tuff (MEGT) eruption. Correlations with the distal tephra archive preserved at Lago Grande di Monticchio (LGdM) are used to constrain the timing of as yet undated eruptive events. Out of 13 LGdM tephras analysed from the 39–104 ka time window, glass geochemical data show that all are compositionally consistent with the explosive volcanic eruptions of Ischia, whilst 5 of them can be correlated with specific proximal deposits. Pre-MEGT pyroclastic sequences comprise three compositional groups, these groups occur repeatedly in sucessive eruptions. Proximal-distal correlations indicate that the Porticello eruption occurred at 59 ± 2 ka and the Tisichiello eruption probably occurred at 76 ± 3 ka. The MEGT eruption is correlated with LGdM TM-19, which has been directly dated at 55 ± 2 ka. Post-MEGT tephras form compositional groups that overlap with the pre-MEGT but are displaced to lower FeO and TiO2 and lower incompatible element contents. Proximal-distal correlations indicate that the Schiappone and Pietre Rosse eruptions occurred at 50.6 ± 2.0 ka and 45 ± 6 ka, respectively. Tephra from the MEGT eruption span a wide compositional range, broadly overlapping the three pre-MEGT compositional groups but are displaced to higher Nd and Y and contain an additional less evolved glass population. Glass geochemistry is used to recognise and confirm distal equivalents of the MEGT at LGdM (TM-19) and in the Ionian (Y-7), Adriatic (PRAD 1870) and Tyrrhenian (C-18, MD 28) seas. Distal occurences of MEGT tephra define a dispersal axis to the south-southeast and are found as far as 540 km from Ischia, making the MEGT one of the most widely dispersed late Quaternary pyroclastic deposit erupted in the Campanian region. We estimate a volume of approximately 40 km3 for the fallout portion of the MEGT pyroclastic sequence on the basis of proximal and distal deposit thicknesses.