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The present study aims to investigate the origin, type, thermal maturity and hydrocarbon generation potential of organic matter and paleo-depositional environment of the Early Paleocene (Danian) Hangu Formation outcropped in the Kala-Chitta Range of Northwest Pakistan, Eastern Tethys. Organic-rich shale and coal intervals were utilized for geochemical analyses including TOC (total organic carbon) and Rock–Eval pyrolysis coupled with carbon (δ13Corg) and nitrogen (δ15Norg) stable isotopes. The organic geochemical results showed that the kerogen Type II (oil/gas prone) and Type III (gas prone) dominate the investigated rock units. The TOC (wt%) and S2 yield indicate that the rock unit quantifies sufficient organic matter (OM) to act as potential source rock. However, the thermal maturity Tmax°C marks the over maturation of the OM, which may be possibly linked with the effect attained from nearby tectonically active Himalayan Foreland Fold-and-Thrust Belt system and associated metamorphosed sequences. The organic geochemical analyses deciphered indigenous nature of the OM and resultant hydrocarbons. The δ13Corg and δ15Norg stable isotopic signatures illustrated enrichment of the OM from both marine and terrestrial sources accumulated into the Hangu Formation. The Paleo-depositional model established using organic geochemical and stable isotopic data for the formation supports its deposition in a shallow marine proximal inner shelf environment with prevalence of sub-oxic to anoxic conditions, a scenario that could enhance the OM preservation. Overall, the formation holds promising coal and shale intervals in terms of organic richness, but due to relatively over thermal maturation, it cannot act as an effective source rock for liquid hydrocarbon generation and only minor amount of dry gas can be expected. In implication, the results of this study suggest least prospects of liquid hydrocarbon generation potential within Hangu Formation at studied sections.

The optical and radar satellite data based Global Digital Elevation Models (DEMs) serve as a main data source in hydrological studies today. Open access Remote Sensing (RS) products have increasing accuracy and improved spatial resolution. The main research purposes are to study the use of AW3D30, ASTER GDEM V003 and SRTMGL1 DEMs in modeling mountainous lake basin and comparative analysis of their spatial accuracy. Topographic maps and very high resolution satellite imagery of the study area have been applied for the spatial accuracy verification and surface referencing. The relative accuracies of three different DEMs were analyzed using 1284 elevation points on the terrain surfaces. Comparison of these DEMs with 30 m spatial resolution confirms that an AW3D30 DEM has a higher vertical accuracy compared to other models and can be used for modeling river and lake basins over high mountainous terrain. The detected unreliable sections of the modeled lake basin boundary were analyzed and corrected based on the basin delineation by different DEMs. Analysis of spatial accuracy of the delineated Issyk-Kul Lake basin provide further incentive for DEM modification based on higher resolution remote sensing data, considering the applied geoid height differences as well by using satellite positioning data.

The preserved successions from the Mesoproterozoic Era (1600 to 1000 Ma) are a relatively understudied part of Australian geological evolution, especially considering that this era has a greater time span than the entire Phanerozoic. These rocks are mostly known in variably-preserved sedimentary basins overlying Paleoproterozoic or Archean cratons or at the margins of these cratons. Some metamorphosed equivalents occur within the orogens between or marginal to these cratons. Both energy and mineral resources are hosted in Australian Mesoproterozoic basins, including the highly-prospective organic rich shale units within the Beetaloo Sub-basin (Northern Territory), which form part of the Beetaloo Petroleum Supersystem. The primary aim for this record is to provide a consolidated state of knowledge of Australian basins or successions similar in age to that of the Mesoproterozoic Beetaloo Petroleum Supersystem. The findings of this report will assist prioritising future work, through improved geological understanding and resource prospectivity. This report presents an overview of 14 Mesoproterozoic-age sedimentary basins or successions and their current level of understanding, including location, basin architecture, stratigraphy and depositional environments, age constraints and mineral and energy resources. Basins or successions included in this record are unmetamorphosed or metamorphosed to very low-grade conditions. Recommendations are made for future work to address the main knowledge gaps identified from this review. While some of these basins have been the focus of recent intense study and data acquisition, the extent of knowledge varies broadly across basins. All basins reviewed in this record would benefit from further geochemical and geochronological analyses, and stratigraphic study to better understand the timing of depositional events and their correlation with nearby basins. Elucidation of the post-depositional history of alteration, migration of fluids and/or hydrocarbons would facilitate future exploration and resource evaluation.

Glaciers in the northern part of Pakistan are the major source of water to the main river systems in Pakistan. These reservoirs of freshwater are under threat due to a continuous increase in the global mean temperature. The present study investigates two selected (Khordopin and Passu) glaciers surge and resultant induce glacier lakes and lake area change in terms of time and space. Observed temperature and precipitation data obtained from three high-altitude weather stations are also analyzed to examine the recent climate change in the region. The Khordopin glacier has shown an advancing behavior with an average surge of around 15–18 m/day for April–May 2017; it shows reduced velocity to 10 m/day during May–June 2017 as computed to the monthly Sentinel 2 and Landsat OLI images for the study area. During a field campaign, its velocity was recorded 2 m/day from 2 km above stream level of the glacier flow. However, the glacier shows different surge behaviors at different locations and altitudes. The Khordopin and the associated glacial lake show the best example of a surging glacier and formation of a Glacier dammed lake in the region. On the other hand, Passu Glacier indicates glacier retreating behavior. From the analysis of meteorological data (1995–2010), the maximum and minimum temperatures increase at a rate of 0.07 °C/year and 0.08 °C/year, respectively, while annual precipitation increases at 0.18 mm/year during the observational period. The MODIS snow data show an increasing trend in maximum snow-covered from 2000 onward, while the decreasing trend in minimum snow-covered from 2000 to 2008.

The Bransfield Strait (Antarctica) is an important region for evaluating changes in Weddell Sea shelf waters on geological time scales because of its restricted connections to the surrounding ocean. However, the detailed oceanographic consequences of the opening of the strait remain unclear. We present bottom-current-related sedimentary features in the Bransfield Strait and examine the impact of the strait’s opening on deep-water circulation. Our findings show that the ocean circulation started to resemble that of the present day after a period of volcanic activity, possibly around the Middle Pleistocene. Coeval changes in Bransfield Strait morphology and an increase in seafloor irregularities due to the formation of volcanic chains finally determined new pathways for the Bransfield deep and bottom waters, enhanced due to the new climatic scenario of 100 k.y. cycles. The fact that “modernlike” oceanic circulation occurred only during previous interglacial periods demonstrates the significant impact of 100 k.y. climate cycles on the thermohaline changes of Antarctic deep waters. Hence, establishing a modern-day circulation model would enable researchers to assess paleoproductivity and local upwelling that have profoundly influenced the marine ecosystem of the Antarctic Peninsula after the Middle Pleistocene, SI

The eminent palaeontologist and Greenland explorer Claus Heinberg was born in 1945 and died in 2021 after prolonged illness. His scientific production was focused on two remarkably different subjects: the bivalve fauna of the Cretaceous–Palaeogene (K–T) boundary beds and the Mesozoic geology and stratigraphy of eastern North Greenland. He was employed at Roskilde University during most of his career until he retired in 2012. He was part of a cross disciplinary collaborative environment, comprising biologists, geographers, geologists, sociologists, civil engineers and architects. He was a highly engaged social debater of a wide spectrum of societal subjects throughout his life. He was a fine person, a good colleague and friend.

General circulation models (GCMs) are the primary tools for evaluating the possible impacts of climate change; however, their results are coarse in temporal and spatial dimensions. In addition, they often show systematic biases compared to observations. Downscaling and bias correction of climate model outputs is thus required for local applications. Apart from the computationally intensive strategy of dynamical downscaling, statistical downscaling offers a relatively straightforward solution by establishing relationships between small- and large-scale variables. This study compares four statistical downscaling methods of bias correction (BC), the change factor of mean (CFM), quantile perturbation (QP) and an event-based weather generator (WG) to assess climate change impact on drought by the end of the 21st century (2071–2100) relative to a baseline period of 1971–2000 for the weather station of Uccle located in Belgium. A set of drought-related aspects is analysed, i.e. dry day frequency, dry spell duration and total precipitation. The downscaling is applied to a 28-member ensemble of Coupled Model Intercomparison Project Phase 6 (CMIP6) GCMs, each forced by four future scenarios of SSP1–2.6, SSP2–4.5, SSP3–7.0 and SSP5–8.5. A 25-member ensemble of CanESM5 GCM is also used to assess the significance of the climate change signals in comparison to the internal variability in the climate. A performance comparison of the downscaling methods reveals that the QP method outperforms the others in reproducing the magnitude and monthly pattern of the observed indicators. While all methods show a good agreement on downscaling total precipitation, their results differ quite largely for the frequency and length of dry spells. Using the downscaling methods, dry day frequency is projected to increase significantly in the summer months, with a relative change of up to 19 % for SSP5–8.5. At the same time, total precipitation is projected to decrease significantly by up to 33 % in these months. Total precipitation also significantly increases in winter, as it is driven by a significant intensification of extreme precipitation rather than a dry day frequency change. Lastly, extreme dry spells are projected to increase in length by up to 9 %.

ispartof: ENERGY & FUELS vol:35 issue:13 pages:10461-10474 status: published

The youngest time interval of the Cretaceous Period is known as the Maastrichtian, in reference to the shallow-marine strata outcropping in the area surrounding the city of Maastricht, in the Netherlands-Belgium border region. While the type-Maastrichtian strata have yielded a wealth of paleontological data, comparatively little geochemical work has so far been carried out on this succession. To date, age assessment of the type-Maastrichtian, and stratigraphic correlation with sections elsewhere, have largely been based on biostratigraphy and preliminary attempts at cyclostratigraphy. However, these techniques are hampered by bio-provincialism and the presence of stratigraphic gaps in the succession, respectively. In recent years, stable carbon isotope stratigraphy has proven to be a powerful tool for correlating Upper Cretaceous strata on a global scale. When integrated with biostratigraphy, carbon isotope stratigraphy can be used to test the synchroneity of biological and climatic events across the globe and to reconcile inter-regional biostratigraphic schemes. Therefore, we have generated the first high-resolution bulk stable carbon isotope stratigraphy for the type-Maastrichtian, using an extensive sample set acquired within the context of the Maastrichtian Geoheritage Project spanning approximately 100 meters of stratigraphy at the Hallembaye and former ENCI quarries. In combination with bulk major and trace element data generated using µXRF, this record presents the first high-resolution chemostratigraphic survey for the type-Maastrichtian. The µXRF-based element profiles through the type-Maastrichtian succession reveal variable fluxes of terrigenous input into this carbonate system over time, marking three distinct stratigraphic sequences, separated by sequence boundaries at the Froidmont, Lichtenberg and Vroenhoven horizons. In addition, the carbon isotope profile records the Campanian–Maastrichtian Boundary Event (CMBE) and the Mid-Maastrichtian Event (MME) in the Maastrichtian type area for the first time. Our refined age model allows for global correlation between the type-Maastrichtian sequence and Maastrichtian successions worldwide and places the abundant paleontological records from the type-Maastrichtian in a global context.

The Coles Hill uranium deposit, with an indicated resource of about 130 Mlb of U3O8, is the largest unmined uranium deposit in the United States. The deposit is hosted in the Taconian (approx. 480-450 Ma) Martinsville igneous complex, which consists of the Ordovician Leatherwood Granite (granodiorite) and the Silurian Rich Acres Formation (diorite). The host rock was metamorphosed to orthogneiss during the Alleghanian orogeny (approx. 325-260 Ma), when it also underwent dextral strike-slip movement along the Brookneal shear zone. During the Triassic, extensional tectonics led to the development of the Dan River Basin that lies east of Coles Hill. The mineralized zone is hosted in brittle structures in the footwall of the Triassic Chatham fault that forms the western edge of the basin. Within brittle fracture zones, uranium silicate and uranium-bearing fluorapatite with traces of brannerite form veins and breccia-fill with chlorite, quartz, titanium oxide, pyrite, and calcite. Uranium silicates also coat and replace primary titanite, zircon, ilmenite, and sulfides. Sodium metasomatism preceded and accompanied uranium mineralization, pervasively altering host rock and forming albite from primary feldspar, depositing limpid albite rims on igneous feldspar, altering titanite to titanium oxide and calcite, and forming riebeckite. Various geothermometers indicate temperatures of less than similar to 200 degrees C during mineralization. In situ U-Pb analyses of titanite, Ti-oxide, and apatite, along with Rb/Sr and U/Pb isotope systematics of whole-rock samples, resolve the timing of geologic processes affecting Coles Hill. The host Leatherwood Granite containing primary euhedral titanite is dated at 450 to 445 Ma, in agreement with previously obtained ages from zircon in the Martinsville igneous complex. A regional metamorphic event at 330 to 310 Ma formed anhedral titanite and some apatite, reequilibrated whole-rock Rb/Sr and U-Pb isotopes, and is interpreted to have coincided with movement along the Brookneal shear zone. During shearing and metamorphism, primary refractory uranium-bearing minerals including titanite, zircon, and uranothorite were recrystallized, and uranium was liberated and mixed locally with hematite, clay, and other fine-grained minerals. Uranium mineralization was accompanied by a metasomatic episode between 250 and 200 Ma that reset the Rb-Sr and U-Pb isotope systems and formed titanium oxide and apatite that are associated and, in places, intimately intergrown with uranium silicate dating mineralization. This event coincides with rifting that formed the Dan River Basin and was a precursor to the breakup of Pangea. The orientation of late-stage tectonic stylolites is compatible with their formation during Late Triassic to Early Jurassic basin inversion, postdating the main stage of uranium mineralization and effectively dating mineralization as Mesozoic. Based on the close spatial and temporal association of uranium with apatite, we propose that uranium was carried as a uranyl-phosphate complex. Uranium was locally reduced by coupled redox reactions with ferrous iron and sulfide minerals in the host rock, forming uranium silicates. The release of calcium during sodium metasomatic alteration of primary calcic feldspar and titanite in the host rock initiated successive reactions in which uranium and phosphate in mineralizing fluids combined with calcium to form U-enriched fluorapatite. Based on the deposit mineralogy, oxygen isotope geochemistry, and trace element characteristics of uranium silicate and gangue minerals, the primary mineralizing fluids likely included connate and/or meteoric water sourced from the adjacent Dan River Basin. High heat flow related to Mesozoic rifting may have driven these (P-Na-F- rich) fluids through local aquifers and into basin margin faults, transporting uranium from the basin or mobilizing uranium from previously formed U minerals in the Brookneal shear zone, or from U-enriched older basement rock. Published version Public domain – authored by a U.S. government employee

Due to the unique soil and morphological conditions prevailing in Izmir Bay basin, structural damage has been governed by site effects. Consistently, during October 30, 2020 M7.0 Samos Earthquake, which took place offshore of Samos Island, structural damage and life losses were observed to be concentrated in Bayrakli region of Izmir Bay, despite the fact that the fault rupture was at a distance of 65-75 km from the city of Izmir. Additionally, strong ground motions recorded in Izmir Bay showed unique site amplifications that were observed surprisingly at both rock and soil sites. Soil amplifications and duration elongations were mostly due to site effects governed by the response of very deep alluvial deposits of low plasticity. Similarly, due to very extensive faulting-induced fracturing and unusually stratified nature of rock sub-layers, unexpected long period amplifications were also observed at rock sites. These earthquake and site resonance effects were more pronounced in the period range of 0.5-1.5 s. When they were superposed with relatively coinciding natural period of 7-9 story residential buildings of Izmir City, it was concluded that the triple resonance effects among incoming rock ground motions, soil deposits, and the damaged buildings, amplified and prolonged the overall system response. Within the confines of this manuscript, the governing role of site effects leading to increased seismic demand was assessed, through a series of 1D equivalent linear, total stress-based site response assessments, the results of which clearly highlighted the variation of seismic demand in Izmir Bay., Middle East Technical University, The earthquake reconnaissance studies were supported by Middle East Technical University. The authors would also like to thank the undergraduate students, who collaborated on field campaigns and data processing.

An advection–diffusion model of fluvial processes was used to analyze the stratigraphic expression of avulsions in terminal river systems and understand their control on basin-fill architecture. The initial and boundary conditions of the model runs (i.e., catchment area, smoothed initial topographic surface, grain-size distribution and sediment supply rates) were extracted from the modern Rio Colorado dryland terminal river system in the Altiplano Basin (Bolivia). Water-discharge and sediment-load values were derived from global regression curves and the BQART equation, respectively. To evaluate the robustness of the simulations, the model was tested under increasing sediment-load scenarios ranging from 0.003 m3/s to 0.095 m3/s. Data-model comparison provided insights into the role of avulsions in the geomorphological evolution of terminal river systems. The observed stacking of sediments, as captured by geospatial and geochronological data from the Rio Colorado, is consistent with the high sediment-load scenarios, which start with a single-thread fluvial channel that in time radially expands over the floodplain by successive river avulsions on account of alluvial-ridge aggradation and channel-floor elevation above the surrounding floodplain. The model output shows a laterally extensive, convex-upwards lobate topography which is in agreement with the lateral and longitudinal geomorphology in the upper and lower coastal plain of the Rio Colorado. The simulated inter-avulsion period, which is the time period between two successive full (or stabilized) avulsions in the model, varies from 0.18 to 1.2 kyr and is consistent with the OSL-age determination in the Rio Colorado with inter-avulsion periods up to 1.28 ± 0.34 kyr.

The Zagros Fold and Thrust Belt of the Kurdistan region of northern Iraq host major volumes of hydrocarbons in multiple fractured carbonate reservoirs throughout the Jurassic, Cretaceous, Palaeogene and Neogene. Limited research has been undertaken to characterize these recently discovered carbonate reservoir rocks. Here, the reservoir quality of the Neogene Euphrates and Jeribe Formations is investigated. Samples from five outcrops along the Azhdagh and Mamlaha anticlines and from four nearby wells (North Oil Company wells JM37, KM3, SAR1 and KU1) have been analysed to understand better their reservoir properties. In both formations very low matrix porosities (

Geochemical study of Kazhdumi and Pabdeh Formations as potential source rocks in Gachsaran Oilfield demonstrates that the Kazhdumi Formation has a fair to good capability of hydrocarbon generation and predominately contains type II-III kerogen. On the other hand, the Pabdeh Formation has a poor to good petroleum potential and contains different kerogen types, including type II, type II-III, type III and even for one sample, type IV, indicating different depositional conditions for this formation. The geochemical log of the Kazhdumi Formation shows that there is a close correlation between different geological parameters as noticed prominently in well number 55, which suggests the more extensive the anoxic condition, the higher the petroleum potential is for Kazhdumi Formation. By contrast, a poor correlation between TOC and other Rock–Eval-derived parameters for the Pabdeh Formation at a depth of more than 2100 m may demonstrate the inert organic matter and mineral matrix effects at this depth interval. However, biomarkers show differences in lithology and depositional environment for the Kazhdumi Formation in well numbers 55 and 83. On the other hand, the Pabdeh Formation has a mixed lithology (carbonate-shale) deposited in a marine setting under suboxic–anoxic condition. Moreover, thermal maturity indicators suggest that Pabdeh and Kazhdumi Formations are immature and early mature, respectively.

The crustal structure around the Islas Marías Archipelago has been debated for a long time. An important unresolved question is where the Rivera-North American plate subduction ends and the Tamayo fracture zone begins, from SE to NW. Results from the TsuJal project have shed light on the northwesternmost part of the Jalisco block structure. It is now clear that Sierra de Cleofas and the Islas Marías Escarpment comprise the northwestern continuation of the Middle America trench. However, other questions remain. In this paper, we present the structure of the shallow and deep crust and the upper mantle of the Islas Marías western region through the integration of multichannel seismic reflection, wide-angle seismic bathymetric and seismicity data, including records of an amphibious seismic network, OBS, and portable seismic stations, purposely deployed for this project, providing an onshore-offshore transect of 310km length. Our findings disclose new evidence of the complex structure of the Rivera plate that dips 8°–9° underneath the NW Jalisco block as revealed by two seismic profiles parallel to the Islas Marías Escarpment. Moreover, we find five sedimentary basins and active normal faults at the edges of tectonic structures of the E-W oriented West Ranges and the N-S trending Sierra de Cleofas. Furthermore, the Sierra de Cleofas is the beginning of the active subduction of the Rivera plate beneath North America. The oceanic crust thickens and submerges towards the south while is coupled with the continental crust, from 6km at the northern ends of the seismic profiles to 15km in the contact region and 24km at the coast and southern ends of them. The continental Moho was not fully characterized because of the geometry of the seismic transects, but a low-velocity layer associated with Rivera Plate subduction was observed beneath the Jalisco Block. Our results constrain the complexity of the area and reveal new structural features from the oceanic to continental crust and will be pivotal to assess geohazards in this area.

Palynological analysis and radiocarbon dating of a short sediment core from a high-altitude mire in the Arasbaran area of northwestern Iran reveals long-term vegetation dynamics, climate change and anthropogenic impact. Our findings indicate the prevalence of semi-desert steppe vegetation, with a variety of Asteraceae - mainly Lactuceae - species from 3000 to 1440 cal yr BP. This period is followed by a higher occurrence of Artemisia spp. and Brassicaceae (1440-1330 cal yr BP), a re-expansion of Lactuceae (1330-1030 cal yr BP) and Brassicaceae (1030-330 cal yr BP) and, finally, Caryophyllaceae species (since 330 cal yr BP). The reconstructed millennia-long dry climate in the highlands of northwestern Iran is in good accordance with climate reconstructions from other east Mediterranean sites. Two phases of moister conditions between 2100-1400 and 1000-350 cal yr BP would correspond to altitudinal Quercus-Carpinus forest expansion in the Arasbaran area. The earliest indication of anthropogenic activity in the area dates back to the onset of the record, around 3000 cal yr BP. The occurrence of small maxima of Juglans regia, Corylus avellana and Cornus mas pollen at around 1350 cal yr BP is interpreted to reflect a temporary expansion of fruit cultivation. For the last millennium the occurrence of pollen attributable to Polygonum, Euphorbia, Plantago and Rumex suggests a diversification of steppe vegetation, which may reflect intensified agropastoral activities in the Arasbaran highlands. Based on our pollen record, the regional vegetation in the Kalan area remained largely stable over the last three millennia. However, changes in local hydrology caused substantial changes in wetland vegetation.

The northern North Sea rift evolved through multiple rift phases within a highly heterogeneous crystalline basement. The geometry and evolution of syn‐rift depocenters during this multiphase evolution and the mechanisms and extent to which they were influenced by preexisting structural heterogeneities remain elusive, particularly at the regional scale. Using an extensive database of borehole‐constrained 2D seismic reflection data, we examine how the physiography of the northern North Sea rift evolved throughout late Permian‐Early Triassic (RP1) and Late Jurassic‐Early Cretaceous (RP2) rift phases, and assess the influence of basement structures related to the Caledonian orogeny and subsequent Devonian extension. During RP1, the location of major depocenters, the Stord and East Shetland basins, was controlled by favorably oriented Devonian shear zones. RP2 shows a diminished influence from structural heterogeneities, activity localizes along the Viking‐Sogn graben system and the East Shetland Basin, with negligible activity in the Stord Basin and Horda Platform. The Utsira High and the Devonian Lomre Shear Zone form the eastern barrier to rift activity during RP2. Toward the end of RP2, rift activity migrated northward as extension related to opening of the proto‐North Atlantic becomes the dominant regional stress as rift activity in the northern North Sea decreases. Through documenting the evolving syn‐rift depocenters of the northern North Sea rift, we show how structural heterogeneities and prior rift phases influence regional rift physiography and kinematics, controlling the segmentation of depocenters, as well as the locations, styles, and magnitude of fault activity and reactivation during subsequent events. publishedVersion

A 59 m-thick section of a freshwater oil shale interbedded with marlstone of Lower Carboniferous (Tournaisian) age from the Big Marsh area in Antigonish Basin, Nova Scotia, Canada, was examined using reflected light microscopy, Rock-Eval pyrolysis, X-ray diffractometry analysis, inductively coupled plasma-mass spectrometry for elemental analysis, and prompt y for boron concentration. The oil shale was deposited in a lacustrine environment based on geology, sedimentology, variation in organic matter, and boron content (28-54 ppm). Organic petrology classified the oil shale into three broadly distinct types. Type A oil shale is a coastal facies shale containing terrestrially derived macerals, such as vitrinite and inertinite, sporinite, with some lamalginite, and amorphous bituminous matrix. Type B oil shale was deposited in a shallow-water facies and contains mostly lamalginite and some vitrinite and sporinite. Type C oil shale is a relatively deep-water facies, associated with open-water Torbanite-type oil shale and contains mostly Botryococcus colonial telalginite. The oil shale is thermally mature (T-max is 441-443 degrees C). Total organic carbon (TOC) varies from 5.8 to 7.3 wt %, and the hydrogen index is between 507 and 557 mg HC/g TOC. The rate of sedimentation as determined by the Th/U ratio indicates possibility of three sedimentation periods: an irregular but mostly slow rate of sedimentation from the base of the section up to 68 m, followed by a regular and slow rate between 68 and 53 m, and a regular and fast rate between 53 m and the top of the section. The higher Th/U ratio during deposition of the shallow-water facies was due to the input of allochthonous U. The redox conditions, as reflected in the variation of Cr to Mo, U, and Ni + V, indicate that the oil shale was deposited under suboxic-dysoxic conditions. The high organic productivity by phytoplankton and bacteria is characterized by a low Cr and high V/Cr ratio and suboxic conditions. In contrast, the well-oxygenated and uniform, warm-temperature upper water level supports a dysoxic environment. Variation of Sr/Ca vs Mn/Ca ratios indicates that most samples have low values, a characteristic of colder water and high terrigenous influx. The post-Archean Australian shale (PAAS)-normalized rare earth elements (REEs) follow three trends. Type A oil shale has the highest concentration of total REEs (648 ppm) and light REEs (LREEs, 605 ppm) as compared with type C (269 and 233 ppm), which are less than half of type A. Type B oil shale has the lowest total REEs (184 ppm) and LREEs (152 ppm). The concentration of heavy REEs decreased from 43 ppm in type A oil shale to 36 ppm in type C oil shale. Comparison of PAAS-normalized REEs for the three oil shale types indicates a reduction of the negative Eu anomaly with depth, which is possibly related to sedimentary sorting as a result of accumulation of fine sediments in the deeper water zone of the lake. The concentration of most elements of environmental concern is similar to and/or lower than the world shale. However, there are instances of higher concentrations of hazardous elements (e.g., As, Cd, Mo, and Se ).

© 2019 Author(s). Worldwide, groundwater resources are under a constant threat of overexploitation and pollution due to anthropogenic and climatic pressures. For sustainable management and policy making a reliable prediction of groundwater levels for different future scenarios is necessary. Uncertainties are present in these groundwater-level predictions and originate from greenhouse gas scenarios, climate models, conceptual hydro(geo)logical models (CHMs) and groundwater abstraction scenarios. The aim of this study is to quantify the individual uncertainty contributions using an ensemble of 2 greenhouse gas scenarios (representative concentration pathways 4.5 and 8.5), 22 global climate models, 15 alternative CHMs and 5 groundwater abstraction scenarios. This multi-model ensemble approach was applied to a drought-prone study area in Bangladesh. Findings of this study, firstly, point to the strong dependence of the groundwater levels on the CHMs considered. All groundwater abstraction scenarios showed a significant decrease in groundwater levels. If the current groundwater abstraction trend continues, the groundwater level is predicted to decline about 5 to 6 times faster for the future period 2026-2047 compared to the baseline period (1985-2006). Even with a 30% lower groundwater abstraction rate, the mean monthly groundwater level would decrease by up to 14m in the southwestern part of the study area. The groundwater abstraction in the northwestern part of Bangladesh has to decrease by 60% of the current abstraction to ensure sustainable use of groundwater. Finally, the difference in abstraction scenarios was identified as the dominant uncertainty source. CHM uncertainty contributed about 23% of total uncertainty. The alternative CHM uncertainty contribution is higher than the recharge scenario uncertainty contribution, including the greenhouse gas scenario and climate model uncertainty contributions. It is recommended that future groundwater-level prediction studies should use multi-model and multiple climate and abstraction scenarios. ispartof: HYDROLOGY AND EARTH SYSTEM SCIENCES vol:23 issue:5 pages:2279-2303 status: published

Shallow marine to peritidal carbonates of the Triassic Csukma Formation in the Mecsek Mts. of SW Hungary are made up of dolomites, limestones and dolomitic limestones that show evidence of a complex diagenetic history. Integration of petrographic, conventional stable oxygen and carbon isotope, clumped isotope, and strontium isotope data with the paleogeography, paleoclimate, and burial history of the region revealed four major diagenetic stages. Stage 1: The peritidal carbonates were dolomitized penecontemporaneously during the Middle Triassic by refluxing evaporatively concentrated brines. Stage 2: Increasing burial during the Late Triassic–Jurassic resulted in recrystallization of the Kan Dolomite Member in an intermediate burial setting. Stage 3: During the Early Cretaceous seawater was drawn down and circulated through rift-related faults, causing renewed recrystallization of the Kan Dolomite Member as well as dolomitization of the Kozar Limestone Member and the underlying limestones in a deep burial setting, but only in the vicinity of the faults. Stage 4: During the Late Cretaceous and Cenozoic thrusting resulted in tectonic expulsion of basinal fluids and precipitation of multiple saddle dolomite cement phases near the faults. The results of this study imply that the clumped isotope method integrated with other geochemical data can successfully be applied to identify the nature and potential sources of extra-formational diagenetic fluids responsible for dolomitization and recrystallization. This study provides conclusive evidence for multi-phase dolomitization and dolomite recrystallization over several millions of years (Middle Triassic through Early Cretaceous) and several thousands of meters of burial in the Csukma Formation in SW Hungary. Furthermore, this study is the first to identify fault-controlled dolomitization by circulating Cretaceous seawater within Triassic carbonates of central Europe, further supporting the viability of the interpretation of dolomitization by seawater initially drawn down and then geothermally circulated through faults in extensional basins.

ispartof: BASIN RESEARCH vol:33 issue:5 pages:2605-2635 status: published

The Eocene Harwich Formation, underlying the Greater London (UK) area, presents many construction problems for design and location of tunnels, pipelines and other engineering infrastructure projects. Variable deposits make up the sequence of the Harwich Formation. These include cemented fault zones, hard grounds, loose gravel and sand that, when unexpectedly encountered, can cause construction delays and increase costs. Here, we interpret borehole cores and logs, and in situ observations coupled with borehole-derived samples, and calculate particle-size distributions to develop a general facies model that accounts for the lithological distribution within the Harwich Formation. This provides an improved geological framework for proposed subsurface construction that can reduce inherent engineering uncertainties, not only in the London region but potentially also in other similar geological environments.

International audience; On February 18, 2021 NASA's Perseverance rover landed in Jezero crater, located at the northwestern edge of the Isidis basin on Mars. The uppermost surface of the present-day crater floor is dominated by a distinct geologic assemblage previously referred to as the dark-toned floor. It consists of a smooth, dark-toned unit overlying and variably covering light-toned, roughly eroded deposits showing evidence of discrete layers. In this study, we investigated the stratigraphic relations between materials that comprise this assemblage, the main western delta deposit, as well as isolated mesas located east of the main delta body that potentially represent delta remnants. A more detailed classification and differentiation of crater floor units in Jezero and determination of their relative ages is vital for the understanding of the geologic evolution of the crater system, and determination of the potential timeline and environments of habitability. We have investigated unit contacts using topographic profiles and DEMs as well as the distribution of small craters and fractures on the youngest portions of the crater floor. Our results indicate that at least some of the deltaic deposition in Jezero postdates emplacement of the uppermost surface of the crater floor assemblage. The inferred age of the floor assemblage can therefore help to constrain the timing of the Jezero fluviolacustrine system, wherein at least some lake activity postdates the age of the uppermost crater floor. We present hypotheses that can be tested by Perseverance and can be used to advance our knowledge of the geologic evolution of the area.

Mars is the first extraterrestrial planet with seismometers (Seismic Experiment for Interior Structure, SEIS) deployed directly on its surface in the framework of the Interior Exploration using Seismic Investigations, Geodesy and Heat Transport (InSight) mission. The lack of strong Marsquakes, however, strengthens the need of seismic noise studies to additionally constrain the Martian structure. Seismic noise autocorrelations of single-station recordings permit the determination of the zero-offset reflection response underneath SEIS. We present a new autocorrelation study which employs state-of-the-art approaches to determine a robust reflection response by avoiding bias from aseismic signals which are recorded together with seismic waves due to unfavorable deployment and environmental conditions. Data selection and segmentation is performed in a data-adaptive manner which takes the data root-mean-square amplitude variability into account. We further use the amplitude-unbiased phase cross-correlation and work in the 1.2-8.9 Hz frequency band. The main target are crustal scale reflections, their robustness and convergence. The strongest signal appears at 10.6 s, and, if interpreted as a P-wave reflection, would correspond to a discontinuity at about 21 km depth. This signal is a likely candidate for a reflection from the base of the Martian crust due to its strength, polarity, and stability. Additionally we identify, among the stable signals, a signal at about 6.15 s that can be interpreted as the P-wave reflection from the mid-crust at about 9.5 km depth., This is the InSight contribution number 144 and IPGP contribution number 4215. French authors are supported by ANR MAGIS (ANR-19-CE31-0008-08) and by CNES SEIS/InSight Phase E2. MS thanks SANIMS (RTI2018-095594-B-I00), Generalitat de Catalunya (2017SGR1022), and invitations for research stays at IPGP.

Trinil (Java, Indonesia) yielded the type fossils of Homo erectus and the world?s oldest hominin-made engraving. As such, the site is of iconic relevance for paleoanthropology. However, our understanding of its larger geological context is unsatisfactory. Previous sedimentological studies are around 100 years old and their interpretations sometimes contradictory. Moreover, the existing stratigraphic framework is based on regional correlations, which obscure differences in local depositional dynamics. Therefore, a new and more local framework is urgently needed. We carried out a comprehensive geological study of the Trinil area. Using a Digital Elevation Model, we identified seven fluvial terraces. Terrace deposits were described and OSL-dated and fluvial behaviour was reconstructed. The terraces were correlated with terraces of the Kendeng Hills (e.g. the hominin-bearing Ngandong terrace) and date back to the past -350 ka. Thus far, most of the Trinil terraces and their deposits had remained unidentified, confounding sedimentological and stratigraphic interpretations. The exposed pre-terrace series has a thickness of -230 m. Together with the terraces, it forms a -3 Ma record of tectonism, volcanism, climate change and sea-level fluctuations. We subdivided the series into five new and/or revised stratigraphic units, representing different depositional environments: Kalibeng Formation, Padas Malang Formation, Batu Gajah Formation, Trinil Formation and Solo Formation. Special attention was paid to erosional contacts and weathering profiles, forming hiatuses in the depositional series, and offering insight into paleoclimate and base-level change. The Trinil Formation provides a new landscape context of Homo erectus. Between -550 and 350 ka, the area was part of a lake basin (Ngawi Lake Basin), separated from the marine base level by a volcanic barrier, under dry, seasonal conditions and a regular supply of volcanic ash. An expanding and retreating lake provided favourable living conditions for hominin populations. After 350 ka, this role was taken over by the perennial Solo River. Landscape reconstructions suggest that the Solo formed by headward erosion and stream piracy, re-connecting the Ngawi Lake Basin to the plains in the west. Our study offers a local framework, but its Pleistocene landscape record has regional significance. Most of all, it forms a much-needed basis for future, detailed studies on the build-up of the hominin site of Trinil, its fossil assemblages and numerical ages. (c) 2021 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).