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The Clarence Stream intrusion-related gold deposit is hosted within metasedimentary and metavolcanic sequences of the Ordovician Cookson and Silurian Mascarene groups that were intruded by several phases of the Late Silurian to Early Devonian Saint George Plutonic Suite. Based on geochemical and geochronological data, the intrusive rocks in the deposit are categorized into three distinct suites, including gabbroic, granitoid, and Whittier Ridge Granite (WRG). The gabbroic suite is the same as the East Branch Brook metagabbro intrusion, which exhibits a subalkaline mafic composition fractionated from a depleted mantle in a suprasubduction zone setting. The granitoid suite shows the same geochemical characteristics and age as the metaluminous to slightly peraluminous Magaguadavic Granite and its fractionated phases. The WRG suite reflects characteristics of calc-alkaline, metaluminous to peraluminous I-type granites in the area, such as Sorrel Ridge and Mount Douglas granitic plutons. In situ U-Pb zircon geochronology yielded an age of 419.5 ± 3.8 Ma for a monzodiorite from the gabbroic suite. Porphyritic granite and alkali granite from granitoid suite yielded U-Pb zircon age of 402.4 ± 1.8 Ma and 394.3 ± 3.8 Ma, respectively. Geochronologic data from the WRG suite reflect two different crystallization ages of 383.8 Ma (382.4 ± 3.1 to 385.1 ± 4) and 372.4 Ma (367.4 ± 1.3 to 377.1 ± 1.9). Several pieces of evidence demonstrate that the gold mineralizing events occurred after the emplacement of the East Branch Brook metagabbroic dykes and are linked to the various intrusive phases of the nearby syntectonic Early Devonian Magaguadavic Granite. The absence of gold and sulphide mineralization in felsic dykes related to the WRG confirms that this plutonic body formed adjacent to the gold zones after the main gold mineralizing event. [ABSTRACT FROM AUTHOR]

In situ LA‐ICP‐MS/MS U‐Pb and Rb‐Sr geochronology combined with geochemical analysis and electron microscopy have been performed on ejecta components sampled from the Mid‐to‐Late Triassic Mercia Mudstone Group at Churchwood Quarry, SW England. The layer comprises altered impact spherules, melt‐rich and fragment‐rich accreted grain clusters (AGCs), along with shocked mineral phases. Late Triassic ages are obtained: a U‐Pb age of 219 ± 72 Ma from variably shock‐metamorphosed apatite and a Rb‐Sr age of 213 ± 31 Ma from melt‐rich AGCs. A post‐depositional U‐Pb age of 200 ± 7.5 Ma obtained from the carbonate host matrix correlates with an early Jurassic dolomitization event associated with regional marine transgression. Several links to the Manicouagan impact structure, Canada, are identified that complement previous provenance studies: (1) rare earth element compositions of impact spherules and melt‐rich AGCs match those of the Manicouagan impact melt sheet; (2) the preservation of Archean and Paleo‐ to Neoproterozoic target rock U‐Pb ages in zircon and apatite match those recorded within Manicouagan basement lithologies; and (3) impact spherules and melt‐rich AGCs record initial 87Sr/86Sr compositions that overlap with those of the Manicouagan impact melt sheet and the target rocks involved in their generation. [ABSTRACT FROM AUTHOR]

Dating low‐grade metamorphism is challenging since such rocks commonly lack suitable target minerals for acquiring pressure–temperature–time–deformation (P–T–t–d) data. Herein a new geochronological method termed 'bulk inclusion dating' is applied to a chloritoid‐bearing schist from the Staufen‐Höllengebirge Nappe (SHN, Austroalpine Unit, Eastern Alps, Austria) for which Cretaceous metamorphism is imprecisely constrained. Thermodynamic modelling of the phase relations and mineral chemistry predicts the stability of the equilibrium assemblage in a P–T field between 450–490℃ and 0.5–0.7 GPa, which agrees with peak temperature constraints ~490℃ derived from Raman spectroscopy of carbonaceous material. Chemical zoning of, and the zonation of inclusions within, chloritoid confirm porphyroblast growth at these conditions. High‐resolution imaging reveals thousands of minute (length: 0.1–3 µm), euhedral micro‐zircon crystals included in chloritoid porphyroblasts and in the matrix. The morphological and microstructural characteristics of micro‐zircon as well as the crystal size distributions indicate that it nucleated and grew at greenschist facies conditions most likely from a Zr‐saturated fluid. In situ laser ablation inductively coupled plasma mass spectroscopy bulk inclusion dating of metamorphic zircon in the chloritoid rim using a laser spot diameter of 120 μm yields a U–Pb age of 116.7 ± 9.1 Ma (MSWD: 1.5, n: 79). We interpret zircon precipitation and progressive coarsening coeval with chloritoid growth during prograde metamorphism and thus link the age to the late prograde part of the P–T evolution. The contribution of other U‐bearing phases (apatite, epidote, rutile) does not significantly disturb the U–Pb age. The data provide clear evidence for Early Cretaceous metamorphism in the SHN and indicates that metamorphism started at least 20 m.y. before the formation of eclogites in the Austroalpine Unit. The method introduced here allows integration between metamorphic conditions and age constraints in low‐grade metamorphic rocks and opens up new potential applications in petrochronology. [ABSTRACT FROM AUTHOR]

In situ LA-ICP-MS U–Pb geochronology has been performed on apatite and zircon within thermally recrystallized clast-laden and clast-poor impact melt rocks from the Brent impact structure. A total of 377 laser analyses on 120 impact melt-grown (n = 9) and impact-recrystallized zircon grains (n = 111) were obtained, from which a concordia age of 452.8 ± 2.7 Ma (MSWD 0.57, n = 11), and a weighted average mean 206Pb/238U age of 453.2 ± 2.9 Ma (MSWD 0.60) (n = 11) are calculated. A total of 300 laser analyses from 100 relict apatite grains were obtained, with an unanchored regression through all data yielding a lower intercept age of 453.2 ± 6.0 Ma (MSWD 5.8, n = 300), that overlaps within error of zircon. 207Pb/206Pb ratios obtained from feldspar clasts within clast-laden impact melt retain the same initial Pb composition as the target rocks from which they are derived, while feldspars that crystallized from impact melt have 207Pb/206Pb ratios indicative of isotopic re-equilibration between basement lithologies of two different ages. A similar variability in 207Pb/206Pb is recorded by apatite. This provides evidence for the involvement of Neoproterozoic Lake Nipissing alkaline suite, as well as Mesoproterozoic Grenville gneisses in the production of impact melt at Brent. Recrystallized apatite grains exhibit enrichments in light rare earth elements (LREEs) along neoblast grain boundaries, indicative of trace element substitution and phase precipitation during impact-induced recrystallization. An age of 452.8 ± 2.7 Ma from zircon and 453.2 ± 6.0 Ma from apatite places the impact event in the Late Ordovician, at or near the Sandbian–Katian boundary, confirming Brent's involvement in the Middle to Late Ordovician crater cluster event—a period of enhanced impactor flux to Earth related to the L-Chondrite parent body disruption. [ABSTRACT FROM AUTHOR]

The Chadormalu magnetite-apatite deposit in Bafq metallogenic province, Central Iran, is hosted in the late Precambrian-lower Cambrian volcano-sedimentary rocks with sodic, calcic, and potassic alterations characteristic of iron oxide copper-gold (IOCG) and iron oxide-apatite (IOA) ore systems. Apatite occurs as scattered irregular veinlets and disseminated grains, respectively, within and in the marginal parts of the main ore-body, as well as apatite-magnetite veins in altered wall rocks. Textural evidence (SEM-BSE images) of these apatites shows primary bright, and secondary dark areas with inclusions of monazite/xenotime. The primary, monazite-free fluorapatite contains higher concentrations of Na, Si, S, and light rare earth elements (LREE). The apatite was altered by hydrothermal events that led to leaching of Na, Si, and REE + Y, and development of the dark apatite. The bright apatite yielded two U-Pb age populations, an older dominant age of 490 ± 21 Ma, similar to other iron deposits in the Bafq district and associated intrusions, and a younger age of 246 ± 17 Ma. The dark apatite yielded a U-Pb age of 437 ± 12 Ma. Our data suggest that hydrothermal magmatic fluids contributed to formation of the primary fluorapatite, and sodic and calcic alterations. The primary apatite reequilibrated with basinal brines in at least two regional extensions and basin developments in Silurian and Triassic in Central Iran. [ABSTRACT FROM AUTHOR]

The high-grade metamorphic metasedimentary rocks that comprise the Wollaston Domain, northern Saskatchewan, are host to numerous REE-mineralized pegmatite bodies, including the Kulyk Lake monazite-apatite-Fe(Ti)-oxide occurrence. This occurrence, which is defined by a 3-5 cm wide sinouous zone of granoblastic monazite, apatite, and titanomagnetite, is enclosed within aplitic monzonite and granitic pegmatite dikes. Monazite in this dike was studied in detail using in situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and LA-multi-collector(MC)-ICP-MS. A combination of in situ LA-ICP-MS trace element mapping, trace-element quantification, and U-Pb dating were used to identify a significant volume of partial resorbed xenocyrstic monazite and zircon cores within the monazite-apatite-Fe(Ti)-oxide zone. This xenocrystic monazite is locally characterized by anomalously high As, V, Mo, and Eu concentrations and high (La/Yb)CN (i.e., >1000) consistent with their derivation from metalliferous black shales. The U-Pb age distribution of the inherited monazite and zircon populations matches that of the middle- to upper-Wollaston Group sedimentary succession. The latter was confirmed by in situ Sm-Nd isotope systematics measured by LA-MC-ICP-MS that yielded εNd(1830Ma) between -5.0 and -5.7 consistent with derivation from Wollaston Group metasediment. The crystallization of ~1830 Ma anatectic overgrowths on xenocrystic cores is indistinguishable from monazite crystallization in the aplitic monzonite dike hosting the monazite-apatite-Fe(Ti)-oxide bodies. This study reveals the potential importance of metalliferous monazite-rich lithologies in the anatectic zone to these pegmatite-hosted REE occurrences and suggests that entrainment and magmatic segregation mechanisms may have helped to concentrate monazite, apatite, and Fe(Ti)-oxide prior to final emplacement of the aplite-pegmatite dikes. Similar processes may have occurred regionally and in other high-grade metamorphic terrains worldwide that are endowed with metalliferous metasedimentary protoliths. [ABSTRACT FROM AUTHOR]

The North China craton was stabilized in the late Paleoproterozoic but experienced significant removal of ancient lithospheric keel in the late Mesozoic that resulted in the formation of numerous world-class gold deposits with combined reserves of more than 7000 t of gold. However, it remains uncertain whether the North China craton contains older gold deposits formed during generation and final stabilization of the craton. Here, we show that the Shanggong gold deposit (105 t Au at 5.31 g/t) on the southern margin of the North China craton formed in the late Paleoproterozoic during the collision between the Eastern and Western blocks that led to formation of the Trans-North China orogen and final stabilization of the craton. The Shanggong deposit is hosted in amphibolite-facies rocks of the Neoarchean to early Paleoproterozoic Taihua Group and overlying volcanic rocks of the late Paleoproterozoic Xiong'er Group. Gold mineralization is structurally controlled by NE-striking faults and occurs in four segments: the Liuxiugou, Hugou, Shanggong, and Qiliping segments. The ores consist mainly of quartz-ankeritesulfide stockworks and sulfide disseminations in hydrothermally altered wall rocks. Gold is mostly contained in arsenian pyrite that is variably associated with minor sphalerite, galena, and chalcopyrite. Ore-related alteration assemblages comprise mainly quartz, ankerite, K-feldspar, sericite, and tourmaline. Both the stockworks and mineralized alteration assemblages contain hydrothermal accessory minerals, including monazite, apatite, and rutile. Paragenetic relations and textural data show that these accessory phases precipitated synchronously with gold-bearing sulfides. Laser ablation-inductively coupled plasma-mass spectrometry spot analyses of monazite and apatite from the Shanggong segment yielded reproducible U-Pb dates of 1747 ± 20 Ma (2σ, mean square of weighted deviates [MSWD] 0.46) and 1788 ± 200 Ma (2σ, MSWD = 11.3), respectively. These dates are indistinguishable within errors from an apatite U-Pb date of 1743 ± 79 Ma (2σ, MSWD = 1.6) at the Liuxiugou segment and a rutile U-Pb date of 1804 ± 52 Ma (2σ, MSWD = 0.77) at the Hugou segment. These new dates suggest that the Shanggong deposit formed at ca. 1.80-1.74 Ga, coeval with or immediately after formation of the Trans-North China orogen and final stabilization of the North China craton. Sulfides from the Shanggong gold deposit have δ34S values ranging from -18.5‰ to -6.9‰, whereas the coexisting ankerite has δ13CPDB of -6.81‰ to -1.61‰ and δ18OSMOW of 15.70‰-17.62‰. The stable isotope data are distinctively different from values of the Early Cretaceous gold deposits in the southern North China craton, indicating contrasting hydrothermal systems responsible for these two categories of gold deposits. The results presented here, combined with independent geologic evidence, allow Shanggong to be the first confirmed Paleoproterozoic orogenic gold deposit in the North China craton. Recognition of Paleoproterozoic orogenic gold mineralization provides significant new insights into the gold metallogeny of the well-endowed North China craton and has implications for future gold exploration along the three Paleoproterozoic orogenic belts in this craton. [ABSTRACT FROM AUTHOR]

The Lake George antimony mine was at one time North America's largest producer of antimony. Despite being widely known for the antimony mineralization, the deposit also hosts a range of styles of mineralization such as multiple generations of W-Mo bearing quartz veins as well as a system of As-Au bearing quartz–carbonate veins. In situ U-Pb zircon geochronology, using LA ICP-MS, of the Lake George granodiorite yielded a weighted mean 206Pb/238U age of 419.6 ± 3.0 Ma. Step heating of phlogopite separated from the lamprophyre dykes produced a 40Ar/39Ar plateau segment date of 419.4 ± 1.4 Ma. Single molybdenite crystal analysis for Re-Os geochronology was conducted on two W-Mo-bearing quartz veins, which cross-cut altered granodiorite and altered metasedimentary rocks and yielded two dates of 415.7 ± 1.7 Ma and 416.1 ± 1.7 Ma respectively. 40Ar/39Ar geochronology of muscovite from alteration associated with Au-bearing quartz–carbonate veins yielded one representative plateau segment date of 414.1 ± 1.3 Ma. The dates produced in this study revealed that the different magmatic–hydrothermal events at the Lake George mine occurred over approximately a 10-million-year period at the end of the Silurian and the start of the Devonian following the termination of the Acadian orogeny. [ABSTRACT FROM AUTHOR]

In situ U–Pb geochronology has been performed via laser ablation inductively coupled mass spectrometry on shocked apatite, titanite and zircon from the ~ 8-km-diameter Lac La Moinerie impact structure, Canada. The three analyzed phases are inherited from target rocks that were transformed to impact melt-bearing breccias and clast-laden impact melts. Apatite yields an array of U–Pb ratios populating a region between a younger regression with a refined age of 453 ± 5 Ma, and an older regression with a lower intercept age of 1708 ± 10 Ma. Titanite defines a younger regression with an age of 444 ± 15 Ma, and an older array with a lower intercept at 1844 ± 24 Ma. Zircon yields an upper intercept age of 1810 ± 13 Ma and a lower intercept age of 433 ± 21 Ma, within error of apatite and titanite. The oldest ages from all three phases define Paleoproterozoic igneous–metamorphic events in granitoid target rocks of the De Pas Suite. Isotopic resetting in apatite and titanite, with relatively high Pb-diffusion rates, was controlled by a combination of proximity to impact-generated superheated melt and the formation of fast diffusion pathways facilitated by shock effects and dynamic recrystallization. Zircon resetting was controlled by shock effects and metamictization, which resulted in significant Pb loss. We outline an approach for discriminating 'true' impact ages from metamict zircons with high common Pb that have experienced post-impact Pb loss. Lower intercept ages of all phases constrain the age of formation for the Lac La Moinerie impact structure, with apatite yielding the most precise age of 453 ± 5 Ma. With an age of 453 Ma, Lac La Moinerie joins a growing cluster of more than 12 terrestrial impact structures formed in the Middle-to-Late Ordovician, with potential connection to the L-chondrite parent body breakup event and a period of enhanced bombardment on Earth. [ABSTRACT FROM AUTHOR]

A combination of in situ laser ablation inductively coupled plasma–mass spectrometry (LA ICP–MS) analyses guided by Scanning Electron Microscope–Back-Scattered Electron imaging (SEM–BSE) was applied to hydrothermal monazite from greisen veins of the Late Devonian, highly evolved, uraniferous Mount Douglas Granite, New Brunswick, Canada. Understanding the uraniferous nature of the suite and characterizing the hydrothermal system that produced the associated mineralized greisen veins were the main goals of this study. The uraniferous nature of the Mount Douglas Granite is evident from previous airborne radiometric surveys, whole-rock geochemical data indicating high U and Th (2–22 ppm U; 19–71 ppm Th), the presence of monazite, zircon, xenotime, thorite, bastnaesite, and uraninite within the pluton and the associated hydrothermal greisen veins, as well as anomalous levels of U and Th in wolframite, hematite, and martite within greisen veins. New U–Pb geochronology of hydrothermal monazite coexisting with sulfide and oxide minerals yielded mineralization ages ranging from 344 to 368 Ma, with most of them (90%) younger than the crystallization age of the pluton (368 ± 3 Ma). The younger mineralization age indicates post-magmatic hydrothermal activities within the Mount Douglas system that was responsible for the mineralization. The production of uraniferous greisen veins by this process is probably associated with the High Heat Production (HHP) nature of this pluton, resulting from the radioactive decay of U, Th, and K. This heat prolongs post-crystallization hydrothermal fluid circulation and promotes the generation of hydrothermal ore deposits that are younger than the pluton. Assuming a density of 2.61 g/cm3, the average weighted mean radiogenic heat production of the Mount Douglas granites is 5.9 µW/m3 (14.1 HGU; Heat Generation Unit), in which it ranges from 2.2 µW/m3 in the least evolved unit, Dmd1, up to 10.1 µW/m3 in the most fractionated unit, Dmd3. They are all significantly higher than the average upper continental crust (1.65 µW/m3). The high radiogenic heat production of the Mount Douglas Granite, accompanied by a high estimated heat flow of 70 mW/m2, supports the assignment of the granite to a 'hot crust' (>7 HGU) HHP granite and highlights its potential for geothermal energy exploration. [ABSTRACT FROM AUTHOR]

The Late Silurian to Late Devonian Saint George Batholith in southwestern New Brunswick is a large composite intrusion (2000 km2) emplaced into the continental margin of the peri-Gondwanan microcontinent of Ganderia. The batholith includes: (1) Bocabec Gabbro; (2) equigranular Utopia and Wellington Lake biotite granites; (3) Welsford, Jake Lee Mountain, and Parks Brook peralkaline granites; (4) two-mica John Lee Brook Granite; (6) Jimmy Hill and Magaguadavic megacrystic granites; and (6) rapakivi Mount Douglas Granite. New LA ICP-MS in situ analyses of six samples from the Saint George Batholith are as follows: (1) U-Pb monazite crystallization age of 425.5 ± 2.1 Ma for the Utopia Granite in the western part of the batholith (2) U-Pb zircon crystallization ages of 420.4 ± 2.4 Ma and 420.0 ± 3.5 Ma for two samples of the Utopia Granite from the central part of the batholith; (3) U-Pb zircon crystallization age of 418.0 ± 2.3 Ma for the Jake Lee Mountain Granite; (4) U-Pb zircon crystallization age of 415.5 ± 2.1 Ma for the Wellington Lake Granite; and (5) U-Pb monazite crystallization age of 413.3 ± 2.1 Ma for the John Lee Brook Granite. The new geochronological together with new and existing geochemical data suggest that the protracted magmatic evolution of the Late Silurian to Early Devonian plutonic rocks is related to the transition of the Silurian Kingston arc-Mascarene backarc system from an extensional to compressional tectonic environment during collision of the Avalonian microcontinent with Laurentia followed by slab break-off. [ABSTRACT FROM AUTHOR]

Various styles of ore deposits may form from a single magmatic-hydrothermal system. Identification of a possible genetic link between different ore types in a region is not only of critical importance for a better understanding of the magmatic-hydrothermal processes, but can also help in successful mineral exploration. Both iron oxide-apatite (IOA) and iron skarn deposits are closely associated with intrusive rocks of intermediate to felsic in composition, but whether these two ore types can form from the same magmatic intrusion remains poorly understood. In this study, we present a comparative study between a newly identified subsurface IOA ore body located at the apex of a diorite porphyry and the iron skarn ore bodies located immediately above it in the Jinniu volcanic basin of the Daye district, Middle-Lower Yangtze River metallogenetic belt (MLYRMB), eastern China in order to highlight a genetic link between these two styles of mineralization. The IOA ores are dominated by Ti-rich magnetite with variable amounts of fluorapatite, diopside, and actinolite. This mineralogical assemblage is distinctly different from the iron skarn ores, which consist mainly of Ti-depleted magnetite and subordinate pre-ore garnet and diopside, and post-ore quartz, chlorite, calcite, and pyrite. In addition, magnetite from the IOA ores is characterized by well-developed ilmenite lamellae and has high concentrations of Ni, V, Co, and Ga, consistent with high temperature crystallization, whereas magnetite grains from the iron skarn ores usually exhibit oscillatory growth zones and contain much lower Ni, V, Co, and Ga, indicating their formation under relatively low temperatures. Titanite and fluorapatite from the IOA ores have U-Pb ages of 132.5 ± 2.4 Ma to 128.4 ± 3.0 Ma, which match a titanite U-Pb age for the associated iron skarn ores (132.3 ± 2.0 Ma), and are consistent with zircon U-Pb ages for the ore-hosting diorite porphyry (130.4 ± 0.7 Ma to 130.3 ± 0.5 Ma). This age consistency supports a possible genetic link among the diorite porphyry, IOA ores, and iron skarn ores. We propose that the IOA and skarn ores are the products of two consecutive mineralization stages of the same magmatic-hydrothermal system, involving a high-temperature, hypersaline fluid coexisting with the diorite porphyry magma during emplacement and a subsequent low temperature, diluted hydrothermal fluid. Other IOA and iron skarn deposits of similar ages (130 Ma) are found in a series of volcanic basins in the MLYRMB, which forms one of the world's largest IOA metallogenic belts. The close association of the two ore styles identified at Daye provides a useful exploration guide for IOA and iron skarn deposits both on a local and regional scale. [ABSTRACT FROM AUTHOR]