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Most future growth in the Alberta bituminous sands will be based on thermal in-situ recovery technologies. To date, however, most attention on the environmental effects of bitumen recovery has focused on surface mining in the Athabasca region. Recent uncontrolled bitumen flow-to-surface incidents (FTS; appearance at the surface of bitumen emulsions from deep subsurface recovery zones) reported at the Cold Lake heavy oil fields highlight the need to better understand the potential role of in-situ extraction as a source of contaminants to landscapes and surface waters. We analyzed sediment cores from a lake located ∼2 km away from a recent bitumen FTS incident to provide a long-term perspective on the delivery of metals, polycyclic aromatic compounds (PACs), and polychlorinated biphenyls (PCBs) to surface freshwaters, and to assess whether the onset of local in-situ bitumen extraction can be linked to contaminant increases in nearby lakes. An increase in alkyl PACs coincided with the onset and expansion of commercial in-situ bitumen extraction, and multiple lines of evidence indicate a petrogenic source for recent alkyl PAC enrichment. However, no coincident increase in vanadium (enriched in bitumen) occurred that would suggest the source of petrogenic PAC enrichment is direct input of bituminous particles. Our results show that, similar to surface mining in the Athabasca region, activities associated with in-situ extraction can increase the burden of petrogenic PACs in nearby lakes, but many questions still remain regarding the exact sources and pathways of PACs into the environment. Given that more than 80% of Alberta's bitumen reserves can only be accessed using in-situ technologies, we recommend that this be made a research priority., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Human activities over the last several centuries have transferred vast quantities of mercury (Hg) from deep geologic stores to actively cycling earth-surface reservoirs, increasing atmospheric Hg deposition worldwide. Understanding the magnitude and fate of these releases is critical to predicting how rates of atmospheric Hg deposition will respond to future emission reductions. The most recently compiled global inventories of integrated (all-time) anthropogenic Hg releases are dominated by atmospheric emissions from preindustrial gold/silver mining in the Americas. However, the geophysical evidence for such large early emissions is equivocal, because most reconstructions of past Hg-deposition have been based on lake-sediment records that cover only the industrial period (1850-present). Here we evaluate historical changes in atmospheric Hg deposition over the last millennium from a suite of lake-sediment cores collected from remote regions of the globe. Along with recent measurements of Hg in the deep ocean, these archives indicate that atmospheric Hg emissions from early mining were modest as compared to more recent industrial-era emissions. Although large quantities of Hg were used to extract New World gold and silver beginning in the 16th century, a reevaluation of historical metallurgical methods indicates that most of the Hg employed was not volatilized, but rather was immobilized in mining waste.

Anthropogenic activities have increased the amount of mercury (Hg) transported atmospherically to the Arctic. At the same time, recent climate warming is altering the limnology of arctic lakes and ponds, including increases in aquatic primary production. It has been hypothesized that climate-driven increases in aquatic production have enhanced Hg scavenging from the water column, and that this mechanism may account for much of the recent rise in lake sediment Hg. Here, we test the relationship between climate, algal production, and sediment Hg using a well-dated and multiproxy lake sediment record spanning the Holocene from Lake CF3 (Baffin Island, Nunavut, Canada). During the early Holocene, peak (summer) insolation drove July air temperatures higher than present, and resulted in increased autochthonous primary production as recorded by total organic matter, spectrally inferred Chl-a, diatom abundance, and carbon stable isotopic signatures. However, there are no relationships between any of these proxies and sediment Hg concentrations during this interval. Given that the behavior of preindustrial Hg was relatively stable during past intervals of naturally mediated high production, we surmise that postindustrial increases in Hg accumulation within CF3 reflect a multiplicative effect of atmospheric deposition of anthropogenic Hg and increased sedimentation rates.

We present unambiguous records of preindustrial atmospheric mercury (Hg) pollution, derived from lake-sediment cores collected near Huancavelica, Peru, the largest Hg deposit in the New World. Intensive Hg mining first began ca. 1400 BC, predating the emergence of complex Andean societies, and signifying that the region served as a locus for early Hg extraction. The earliest mining targeted cinnabar (HgS) for the production of vermillion. Pre-Colonial Hg burdens peak ca. 500 BC and ca. 1450 AD, corresponding to the heights of the Chavín and Inca states, respectively. During the Inca, Colonial, and industrial intervals, Hg pollution became regional, as evidenced by a third lake record approximately 225 km distant from Huancavelica. Measurements of sediment-Hg speciation reveal that cinnabar dust was initially the dominant Hg species deposited, and significant increases in deposition were limited to the local environment. After conquest by the Inca (ca. 1450 AD), smelting was adopted at the mine and Hg pollution became more widely circulated, with the deposition of matrix-bound phases of Hg predominating over cinnabar dust. Our results demonstrate the existence of a major Hg mining industry at Huancavelica spanning the past 3,500 years, and place recent Hg enrichment in the Andes in a broader historical context.

To date, few studies have investigated the environmental legacy associated with industrialization in the South American Andes. Here, we present an environmental archive of industrial pollution from (210)Pb-dated lake cores recovered from Laguna Chipian, located near the Cerro de Pasco metallurgical region and Laguna Pirhuacocha, located near the Morococha mining region and the La Oroya smelting complex. At Laguna Chipian, trace metal concentrations increase beginning ~1900 AD, coincident with the construction of the central Peruvian railway, and the rapid industrial development of the Cerro de Pasco region. Trace metal concentrations and fluxes peak during the 1950s before subsequently declining up-core (though remaining well above background levels). While Colonial mining and smelting operations are known to have occurred at Cerro de Pasco since at least 1630 AD, our sediment record preserves no associated metal deposition. Based on our (14)C and (210)Pb data, we suggest that this is due to a depositional hiatus, rather than a lack of regional Colonial pollution. At Laguna Pirhuacocha, industrial trace metal deposition first begins ~1925 AD, rapidly increasing after ~1950 AD and peaking during either the 1970s or 1990s. Trace metal concentrations from these lakes are comparable to some of the most polluted lakes in North America and Europe. There appears to be little diagenetic alteration of the trace metal record at either lake, the exception being arsenic (As) accumulation at Laguna Pirhuacocha. There, a correlation between As and the redox-sensitive element manganese (Mn) suggests that the sedimentary As burden is undergoing diagenetic migration towards the sediment-water interface. This mobility has contributed to surface sediment As concentrations in excess of 1100 microg g(-1). The results presented here chronicle a rapidly changing Andean environment, and highlight a need for future research in the rate and magnitude of atmospheric metal pollution.

To date, information concerning pre-Colonial metallurgy in South America has largely been limited to the archaeological record of artifacts. Here, we reconstruct a millennium of smelting activity in the Peruvian Andes using the lake-sediment stratigraphy of atmospherically derived metals (Pb, Zn, Cu, Ag, Sb, Bi, and Ti) and lead isotopic ratios (206Pb/ 207Pb) associated with smelting from the Morococha mining region in the central Peruvian Andes. The earliest evidence for metallurgy occurs ca. 1000 A.D., coinciding with the fall of the Wari Empire and decentralization of local populations. Smelting during this interval appears to have been aimed at copper and copper alloys, because of large increases in Zn and Cu relative to Pb. A subsequent switch to silver metallurgy under Inca control (ca. 1450 to conquest, 1533 A.D.) is indicated by increases in Pb, Sb, and Bi, a conclusion supported by further increases of these metals during Colonial mining, which targeted silver extraction. Rapid development of the central Andes during the 20th century raised metal burdens by an order of magnitude above previous levels. Our results represent the first evidence for pre-Colonial smelting in the central Peruvian Andes, and corroborate the sensitivity of lake sediments to pre-Colonial metallurgical activity suggested by earlier findings from Bolivia.