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Project: Environmental isotope applications in Latin America and the Caribbean region This Special Issue illustrates the use of environmental isotopes in studying and assessing hydrogeological and ecohydrological issues in the Latin America and the Caribbean (LAC) region. The issue includes twenty selected papers, which have been peer-reviewed in Isotopes in Environmental and Health Studies. Although the LAC region concentrates a third of the world’s freshwater resources [1], access to safe water supplies and sanitation remains unevenly distributed, with water scarcity affecting most arid and semiarid areas and serious water quality issues across the region [2]. About 82% of the LAC population lives in urban centres, including some megacities, creating major challenges to water authorities [3]. Water security is often compromised due to a fast-growing water demand near urban centres (i.e. domestic supply, irrigation and industrial uses) along with the expected impacts of climate change [4] on both water availability and quality [5–7]. In many parts of the LAC region, groundwater resources have become the main or the only source of water to cover basic human needs and the maintenance of ecosystems [8–10]. This rapid increase of water demand is generally translated into intensive and unsustainable exploitation of water resources, having a profound impact on local hydrological cycles. In order to assess the availability of local resources for the near future and adopt sustainable management practices, sound and precise hydrological information is required. Este número especial ilustra el uso de isótopos ambientales en el estudio y evaluación de problemas hidrogeológicos y ecohidrológicos en la región de América Latina y el Caribe (ALC). El número incluye veinte artículos seleccionados, que han sido revisados ​​por pares en Isotopes in Environmental and Health Studies. Aunque la región de ALC concentra un tercio de los recursos de agua dulce del mundo [1], el acceso al suministro de agua potable y al saneamiento sigue distribuido de manera desigual, con la escasez de agua que afecta a la mayoría de las áreas áridas y semiáridas y graves problemas de calidad del agua en toda la región [2]. Aproximadamente el 82% de la población de ALC vive en centros urbanos, incluidas algunas megaciudades, lo que crea grandes desafíos para las autoridades del agua [3]. La seguridad hídrica a menudo se ve comprometida debido al rápido crecimiento de la demanda de agua cerca de los centros urbanos (es decir, el suministro doméstico, el riego y los usos industriales) junto con los impactos esperados del cambio climático [4] tanto en la disponibilidad como en la calidad del agua [5-7]. En muchas partes de la región de ALC, los recursos hídricos subterráneos se han convertido en la principal o única fuente de agua para cubrir las necesidades humanas básicas y el mantenimiento de los ecosistemas [8-10]. Este rápido aumento de la demanda de agua se traduce generalmente en una explotación intensiva e insostenible de los recursos hídricos, con un profundo impacto en los ciclos hidrológicos locales. Para evaluar la disponibilidad de recursos locales para el futuro cercano y adoptar prácticas de gestión sostenible, se requiere información hidrológica sólida y precisa. Universidad Nacional, Costa Rica Escuela de Química

Recharge environmental conditions and residence time, can be studied by the application of different tracers. Several tracers are useful as proxies of the environmental recharge conditions, such as water stable isotopes deuterium and oxygen-18, and the dissolved noble gases. Other tracers are applied in order to know when the recharge occurred. Carbon-14 dating is a widely applied method for dating old groundwater, having an application range up to around 30 ky. Noble gases, as non-reactive and water-soluble substances, constitute useful tracers for studying different processes in hydrologic cycles. One of the applications is dating very old groundwater beyond the range of 14C. It can be done in a semi-quantitative way by the accumulation of 4He, and quantitatively through the radionuclide 81Kr (t1/2 = 229,000 y), a more robust method for dating groundwater up to 1.3 million years.The province of Buenos Aires, Argentina, hosts three deep sedimentary basins, from north to south, Salado, Claromecó and Colorado, with areas of 85,000 km2, 3,100 km2 and 125,000 km2, respectively. In these basins, a thick continental sequence of Neogene sediments contains confined thermal aquifers, at depths from hundreds meters to more than 1 km. The recharge conditions and the water age of the Neogene aquifers are studied through water stable isotopes, 4He and 81Kr tracers. 10 deep wells were sampled for δ2H, δ18O, 3H, 14C, for noble gases using clamped copper tubes, and for 81Kr with a gas extractor. 4He analyses were performed at the IAEA laboratory by mass spectrometry, and 81Kr at the ATTA laboratory of USTC.3H contents were not detectable in all of the cases, thus no young water components exist. By plotting the isotopic results in a δ2H vs δ18O diagram, four groups of samples can be recognized. Group 1 includes Colorado basin isotopically depleted samples (δ18O from -6.5 to -7.5 ‰) along a line parallel to the GMWL and the present LMWL, but with a higher deuterium-excess (d). Samples in G1 have a Ne/He ratio around 0.6. 14C and 81Kr ages were from 10 ky to 40 ky. Group 2 includes the samples of the borders of the Salado basin, being isotopically more enriched (δ18O from -3 to -4.5 ‰) and with a lower d than present precipitation, a Ne/He ratio from 0.2 to 0.8 and one sample with 81Kr age of 640 ky. Group 3 is formed by brines from the Colorado basin, a Ne/He ratio in the range of 1E-02 to 1E-04, and 81Kr in ages around 900 ky, and are along a line of slope 1.9, showing a 18O shift. Finally the Group 4 formed by samples at the axis of Salado basin, are isotopically enriched (δ18O from -0.5 to -3.7 ‰) along a line of slope 3.9 resembling and evaporation line. However, these samples of 81Kr ages of 1000 ky and Ne/He ratio of 2E-03, showed a high correlation Cl- vs δ18O, with increasing values from West to East. This suggest a mixing with a brine or an increasing water-rock interaction.

Fluxes between fractured-karstified and detritic aquifers are commonly poorly understood in many environments. These two types of aquifers are in contact in the southeastern Pampean region in the Argentine Buenos Aires province, and the aim of this work is to analyze their relationship contributing to improve the hydrological model. A joint application of hydrochemical and multi-isotope (δ2H, δ18O, δ13C-TDIC, δ18O-TDIC, 87Sr/86Sr) tools was used. TDIC, δ2H, δ18O and δ13C-TDIC allowed differentiating two main end members. Water in the Pampeano aquifer (PA) which is transferred from the fractured-karstic aquifer (F-KA) is characterised by high TDIC around 500–700 mg/L, isotopically depleted in 18O (about −5.5 ‰) and high δ13C-TDIC (around −10.0 ‰). The other end member is direct recharge water infiltrated into the PA with TDIC ranging from 400 to 500 mg/L, slightly enriched in 18O (δ18O = −4.8 ‰), and δ13C-TDIC in the range of soil CO2 as a result of reactions with calcrete concretions (from −20.0 to −9.0 ‰). Dolomite dissolution is the main process controlling the chemistry of the low-mineralized (Mg–Ca-HCO3) waters, whereas high-mineralized (Na-HCO3) waters are strongly influenced by ion-exchange reactions with adsorbed Ca2+ and Mg2+ and by evaporation.

The Pampean Plain in Argentina is one of the most extended plain regions of the world with numerous wetland systems and very shallow lakes. Certain anomalies related to geomorphology and shallow lakes’ hydrology are particularly present in a sector of the southern Pampean Plain, specifically, in the southwestern limit of the Quequen Grande River Basin. Here, shallow lakes can be defined as upland-embedded wetlands, characterized by the lack of observable hydrological connectivity due to the absence of surface water flows. The aim of this study was to identify groundwater connectivity of Pampean shallow lakes considered as upland-embedded wetlands and classify them according to their water presence frequency over time and their water source origin based on natural tracers (18O–H2O, 2H–H2O, electrical conductivity and Cl− content). In this work, a methodological framework involving a multitemporal analysis of the Normalized Difference Vegetation Index (NDVI) and the Normalized Difference Water Index (NDWI) derived from Landsat data, in addition to field data is proposed. According to water presence frequency, shallow lakes were classified in four categories: occasionally (89.0 %), regularly (6.7 %), usually (1.9 %) and permanently (2.3 %) with water. Obtained results allowed identifying shallow lakes having low, moderate or high mineralized water due to both different evaporation degree and water sources.

The urban growth of the southern neighborhoods of Mar del Plata City provoked significant changes in the groundwater balance of the loessic sequences. These regional loessic levels with a significant portion of volcanic ash layers were reported subject to fluoride and nitrate concentrations. Residential houses pump from sands located 70 m depth and withdraw the sewages to depths less than 5 m. These effects cause significant local and seasonal (summer) increments of the water table outcropping via springs at certain unconformities of the coastal cliffs. A mathematical model was applied to analyze the water level lowering at the productive levels, while there is a decrease in the quality of the upper levels subject to waste discharges. Much of this groundwater flow is concentrated in unconformities between different types of sediments. Human activities have affected the aquifer dynamics increasing the groundwater pumping rates and the return velocity of the sewages. This should be considered in the management strategies of coastal hydric resources. Fil: Isla, Federico Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina Fil: Quiroz Londoño, Orlando Mauricio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina Fil: Cortizo, Luis Camilo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina

Bioactive substances in the Biobio River Basin in Chile were examined by deploying Semi Permeable Membrane Devices (SPMDs) upstream and downstream of 4 pulp mill effluent discharges. Androgenic and estrogenic activity of SPMD extracts were then evaluated using in vitro fish sex steroid receptor binding assays. The results indicated the occurrence of estrogenic type compounds associated with one of the mill discharges. A significant correlation among the presence of these compounds, an increase in gonadosomatic index GSI and induction of hepatic EROD activity of two native fish species was observed. However, no significant presence of mature oocytes in female gonads was detected. Although EROD induction was observed in sites impacted by mill effluents, an increase of its activity occurred towards the downstream areas, suggesting other non-mill sources. More research is needed to understand the environmental changes in context of the new technological improvements in treatment systems to MBBR (Moving Bed Biofilm Reactor) recently implemented by the pulp mill industries.

This study aims to determine the wetland potential on a pixel basis on the floodplain of the Leon River: hydrology, hydrophytic vegetation and hydromorphic soils were taken into account. Field measurements and spatially explicit models were used to model surface hydrology and piezometric levels. Satellite data were used to derive inundated areas and vegetation. Existing maps from the national geographic institute (IGAC) were used to define the spatial distribution of hydromorphic soils. Special attention was paid to agricultural infrastructure, levees and diversion channels used to modify surface hydrology in order to promote plantations and cattle grazing. A total of 536 km2 meet one or more wetland conditions according to biophysical variables, but only 393 km2 were selected, using logical rules, as wetland pixels. The combination of biophysical variables to define wetland potential is discussed in terms of the spatial distribution and the implications for environmental resource management. El presente estudio tiene como fin determinar el potencial de humedales a nivel de pixel en la llanura de inundación del Río León, se consideraron aspectos de hidrología, vegetación hidrofítica y suelos hidromórficos. Se utilizaron mediciones en campo y modelos distribuidos espacialmente para modelar la hidrología superficial y los niveles piezométricos. También se utilizaron imágenes de satélite para determinar áreas inundadas y vegetación. Los mapas existentes del instituto geográfico Agustín Codazzi fueron utilizados para definir la distribución espacial de los suelos hidromórficos. Se prestó atención especial a la infraestructura agrícola, donde los diques artificiales y trasvases han sido utilizados para modificar la hidrología superficial con el fin de promover el establecimiento de plantaciones y pastoreo. Un total de 536 km2 cumplieron una o más condiciones de humedal según las variables biofísicas, pero solo 393 km2 fueron seleccionados mediante reglas lógicas como pixeles de humedal. La combinación de variables biofísicas para la definición del potencial de humedal es discutida en términos de la distribución espacial y las implicaciones para el manejo de los recursos naturales. Fil: Anaya Acevedo, Jesús Adolfo. Universidad de Medellin; Colombia Fil: Escobar Martínez, John Fernando. Universidad de Antioquia; Colombia Fil: Massone, Hector Enrique. Universidad Nacional de Mar del Plata; Argentina Fil: Booman Zugarramurdi, Gisel Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata; Argentina. Universidad Nacional de Mar del Plata; Argentina Fil: Quiroz Londoño, Orlando Mauricio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata; Argentina. Universidad Nacional de Mar del Plata; Argentina Fil: Cañón Barriga, César Camilo. Pontificia Universidad Javeriana de Cali; Colombia Fil: Montoya Jaramillo, Luis Javier. Universidad de Medellin; Colombia Fil: Palomino Ángel, Sebastián. Universidad de Medellin; Colombia

The Negro River extends from the Andes to the Atlantic Ocean supplying water to several cities and to the most important fruit-bearing productive region of Patagonia. Floodplains from the Upper Valley are artificially irrigated with water delivered from the main channel. Pesticides are increasingly used without strict government control. Dams constructed at the tributary rivers retain sediment and therefore the clean water delivered becomes free of sediment and therefore is able to erode certain levees during high-discharge events. Bedload–transport fraction (sand dunes) increases at the Upper Valley and is fixed at the levees of the Lower Valley by riparian vegetation. This riparian vegetation is dominated by Salix humboldtiana and Schoenoplectus californicus while Spartina sp is abundant at the estuarine marsh area. Organochlorine compounds (OCCs) were measured by GC-ECD including dichloro-diphenyl-trichloroethane (DDT), dichlorophenyl-dichloroethylene (DDE) and dichloro-dyphenyl-dichloroethane (DDD) en...

The southeast area of the Argentine Pampas is characterized by the presence of an unconfined aquifer in a wide plain. A methodology is proposed that deals with the aquifer vulnerability where the homogeneity of the hydrogeological variables used by traditional methods (in this case, DRASTIC-P) causes vulnerability maps to show more than 80% of the territory under the same class. This absence of discrimination renders vulnerability maps of little use to decision-makers. In addition, the proposed methodology avoids the traditional vague classification (high, low, and moderate vulnerability) which is highly dependent on subjectivity in its association of each class with hydrogeological considerations. That traditional vulnerability assessment methodology was adapted using a geographic information system to reclassify classes, based on the Natural Breaks (Jenks) method. The pixel-to-pixel comparison between the result obtained by the DRASTIC-P and the reclassified classes generates the so-called operational vulnerability index (OVI), which shows four classes, associating each with different hydrogeological requirements to make decisions. El área sudeste de las Pampas de Argentina está caracterizada por la presencia de un acuífero no confinado en una amplia llanura. Se propone una metodología que trata la vulnerabilidad del acuífero donde la homogeneidad de las variables hidrogeológicas usadas por los métodos tradicionales (en este caso, DRASTIC-P) produce mapas de vulnerabilidad que muestran más del 80% de territorio bajo la misma clase. Esta ausencia de discriminación da mapas de vulnerabilidad de poca utilidad para los tomadores de decisiones. Además, la metodología propuesta evita la clasificación ambigua tradicional (vulneralidad alta, baja y moderada) que es altamente dependiente de la subjetividad en su asociación de cada clase con consideraciones hidrogeológicas. Esta metodología tradicional de evaluación de la vulnerabilidad fue adaptada usando un sistema de información geográfica para reclasificar clases, basado en el método Natural Breaks (Jenks). La comparación pixel a pixel entre los resultados obtenidos por DRASTIC-P y el de las clases reclasificadas genera, los así llamados índices de vulnerabilidad operacional (OVI), que muestran cuatro clases, asociando cada una con diferentes requerimientos hidrogeológicos para la toma de decisiones. A região sudeste das Pampas Argentinas é caracterizada pela presença de um aquífero livre numa ampla planície. Propõe-se uma metodologia para calcular a vulnerabilidade do aquífero quando a homogeneidade das variáveis hidrogeológicas usadas pelos métodos tradicionais (como DRASTIC-P) fazem com que os mapas de vulnerabilidade mostrem que mais de 80% do território ficam sob a mesma classe. Esta ausência de discriminação torna os mapas de vulnerabilidade de pouca utilidade para os decisores. Adicionalmente, a metodologia proposta evita a tradicional classificação vaga (vulnerabilidade alta, moderada e baixa), a qual é extremamente dependente da subjectividade, pela associação de cada classe a considerações hidrogeológicas. A metodologia tradicional de avaliação de vulnerabilidade foi adaptada, tendo para o efeito sido utilizado um sistema de informação geográfica para reclassificar as classes, com base no método das quebras naturais de Jenks (Jenks’ Natural Breaks). A comparação pixel-a-pixel entre o resultado obtido com DRASTIC-P e com as classes reclassificadas dá origem a um designado índice de vulnerabilidade operacional (operational vulnerability index, OVI) que mostra quatro classes, associando-se cada uma delas a diferentes requisitos hidrogeológicos necessários para a tomada de decisões. Fil: Massone, Héctor. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales; Argentina Fil: Quiroz Londoño, Orlando Mauricio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales; Argentina Fil: Martinez, Daniel Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales; Argentina

Stable isotopes and electrical conductivity in groundwater were used as natural tracers to adjust the hydrogeological conceptual model in one of the largest catchments within the inter-mountainous Pampa plain, Argentina. Geostatistical tools were used to define the model that best fitted the spatial distribution of each tracer, and information was obtained in areas where there was a lack of data. The conventional isotopic analysis allowed the identification of three groundwater groups with different isotopic fingerprints. One group containing 56 % of the total groundwater samples suggested a well-mixed system and soil infiltration precipitation as the main recharge source to the aquifer. The other two groups included samples with depleted (25.5 %) and enriched (18.5 %) isotopic compositions, respectively. The combination of δ18O, δ2H and electrical conductivities maps suggested ascending regional flows and water transfer from the Quequén Grande River catchment to the Moro creek. The spatial interpretation of these tracers modified the conceptual hydrogeological model of the Quequén Grande River. Fil: Quiroz Londoño, Orlando Mauricio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina Fil: Martinez, Daniel Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina Fil: Massone, Hector Enrique. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina Fil: Londoño Ciro, Libardo Antonio. Universidad de Antioquia; Colombia Fil: Dapeña, Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotópica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina

This paper gives an account of the implementation of hydrochemical and isotopic techniques to identify and explain the processes that govern solute exchange in two groundwater-dependent shallow lakes in the Southeastern Pampa Plain of Argentina. Water samples (lakes, streams, spring water and groundwater) for hydrochemical and stable isotopic determination were collected and the main physical-chemical parameters were measured. The combination of stable isotope data with hydrogeochemical techniques was used for the identification of sources and preferential recharge areas to these aquatic ecosystems which allowed the explanation of the lake water origin. The hydrochemical processes which explain Los Padres Lake water chemistry are evaporation from groundwater, CO2 input, calcite dissolution, Na+ release by Ca2+ and Mg2+ exchange, and sulfate reduction. The model that best aligns with La Brava Lake hydrochemical constraints includes: mixing, CO2 and calcite dissolution, cationic exchange with Na+ release and Mg2+ adsorption, and to a lesser extent, Ca/Na exchange. This model suggests that the fractured aquifer contribution to this water body is greater than 50 %. An isotopic-specific fingerprint for each lake was identified, finding a higher evaporation rate for La Brava Lake compared to Los Padres Lake. Isotopic data demonstrate the importance of these shallow lakes as recharge areas to the regional aquifer, becoming areas of high groundwater vulnerability. The Tandilia Range System, considered in many hydrogeological studies as the impermeable bedrock of the Pampean aquifer, acts as a fissured aquifer in this area, contributing to low salinity waters and with a fingerprint similar to groundwater isotopic composition. Fil: Romanelli, Asunción. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina Fil: Quiroz Londoño, Orlando Mauricio. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina Fil: Martinez, Daniel Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina Fil: Massone, Hector Enrique. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Geología de Costas y del Cuaternario. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Geología de Costas y del Cuaternario; Argentina Fil: Escalante, Alicia Haydee. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Marinas y Costeras. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Marinas y Costeras; Argentina

The Pampa in Argentina is a large plain with a quite obvious dependence on agriculture, water availability and its quality. It is a sensitive environment due to weather changes and slope variations. Supplementary irrigation is a useful practice for compensating the production in the zone. However, potential negative impacts of this type of irrigation in salinization and sodification of soils are evident. Most conventional methodologies for assessing water irrigation quality have difficulties in their application in the region because they do not adjust to the defined assumptions for them. Consequently, a new GIS-based methodology integrating multiparametric data was proposed for evaluating and delineating groundwater suitability zones for irrigation purposes in flat areas. Hydrogeological surveys including water level measurements, groundwater samples for chemical analysis and electrical conductivity (EC) measurements were performed. The combination of EC, sodium adsorption ratio, residual sodium carbonate, slopes and hydraulic gradient parameters generated an irrigation water index (IWI). With the integration of the IWI 1 to 3 classes (categories of suitable waters for irrigation) and the aquifer thickness the restricted irrigation water index (RIWI) was obtained. The IWI′s index application showed that 61.3 % of the area has “Very high” to “Moderate” potential for irrigation, while the 31.4 % of it has unsuitable waters. Approximately, 46 % of the tested area has high suitability for irrigation and moderate groundwater availability. This proposed methodology has advantages over traditional methods because it allows for better discrimination in homogeneous areas.