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Sediment characterization of Ridracoli reservoir, an artificial lake for water supply, and surroundings of the Fiumi Uniti catchment in the northern Apennines, Emilia-Romagna, Italy, is carried out to evaluate the overall status of the drainage basin encompassing the reservoir. The study area combines the reservoir catchment that is part of the Foreste Casentinesi-Monte Falterona-Campigna National Park, formed by the construction of a dam operating since 1982 for drinking water storage and electricity production, and the upstream side of Fiumi Uniti catchment that flows into the Adriatic Sea, including also nearby sub-catchments of Ridracoli reservoir, named Corniolo and Pietrapazza. We collected surface sediments within the area of the reservoir and riverbed sediments of surroundings catchments, analyzed grain size distribution and the chemical composition, including carbon and nitrogen. This work investigates the chemistry and distribution of elements within the study area, evaluates the dam's effect upstream and downstream, and studies the processes that happen in rivers and the reservoir. The bulk composition is mainly represented by SiO2, Al2O3, CaO, with high Corg content reflecting the Marnoso Arenacea Formation geology of the area. Statistical data analysis on the available parameters suggests the presence of two main types of sediment, namely clayey and carbonate-dominated sediments. On the reservoir area, the relationship between elements and clay matrix and organic matter, besides iron, points to a potential grain size influence, degradation of organic matter, and mineralization processes. The grain size analysis shows that silty and clayey sediments are in the bottom of the reservoir, and sand, is apparent in sediment samples from the tributaries, due to sorting effects and likely directly explained by metals concentrations. This reasoned investigation included further samples from the literature to consider the entire surrounding area and was supported by Principal Component Analysis and Cluster Analysis.

The Ridracoli artificial basin is the main water reservoir of the Emilia-Romagna region (Northeast Italy). The reservoir was made by construction of a dam on the Bidente River in 1982. It is used as the main drinking water supply of the region and for hydropower production. The physical and chemical parameterseters (temperature, pH, electrical conductivity, and dissolved oxygen) of shallow water are continuously monitored whereas vertical depth profiles of water chemical data (major anions and cations, as well as heavy metals) are available on a bimonthly base. The dataset used in this research is related to the years 2015 and 2016. Data show that the reservoir is affected by an alternation of water stratification and mixing processes due to seasonal change in water temperature, density, and the reservoir water level. In late summer and winter months, the water column is stratified with anoxic conditions at the bottom. During the spring, on the other hand, when storage is at its maximum, water recirculation and mixing occur. The reservoir is characterized by a dynamic system in which precipitation, dissolution, and adsorption processes at the bottom affect water quality along the reservoir depth column. The temperature stratification and anoxic conditions at the reservoir bottom influence the concentration and mobility of some heavy metals (i.e., Fe and Mn) and, consequently, the quality of water that reaches the treatment and purification plant. This study is relevant for water resource management of the reservoir. Assessing the seasonal changes in water quality along the reservoir water column depth is fundamental to plan water treatment operations and optimize their costs. The reservoir assessment allows one to identify countermeasures to avoid or overcome the high concentrations of heavy metals and the stratification problem (i.e., artificial mixing of the water column, new water intakes at different depths operating at different times of the year, blowers, etc.).