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The temporal distribution of enriched source components and magmatism in continental collision zones provides critical information about mantle dynamic processes in collision-related environments. This paper presents petrology, mineralogy, K-Ar ages and whole-rock major and trace elements, as well as Sr-Nd-Pb-Hf isotopic compositions of Melikler volcanism in Kars Plateau (KP) in the East Anatolia Collision Zone, NE Turkey, with the aim to understand the role of the subducting slab, the origin of magmatism and the geodynamic evolution in the collision-related environments. Our K-Ar dating results show the Melikler volcanism erupted between 5.29 and 1.7 Ma and allows us to divide it into an early (5.29–2.53 Ma) and a late (2.24–1.7 Ma) stage. Major-trace element abundances, isotopic compositions, EC(R) AFC (energy-constrained recharge, assimilation, and fractional crystallisation) and MELTS model calculations of both stages indicate that the least evolved samples were not affected by significant crustal contamination and fractional crystallisation. More evolved samples of the late stage underwent AFC processes with up to 6–9% crustal assimilation; however, those of the early stage were differentiated from a parental magma composition via AFC (up to 2–7.5% crustal assimilation) and experienced magma replenishment at pressure of 0.5 kbar; thus, both early and late stages have experienced open system conditions. The least evolved samples of both stages across the KP have arc-enriched geochemical and isotopic signatures, characterised by prevalent negative Nb–Ta anomalies and moderately radiogenic Sr, unradiogenic Nd-Hf and highly radiogenic Pb isotopic compositions. These primary melts could be derived from a depleted MORB mantle source metasomatised by sediment melt from the subducting Neotethys oceanic slab. Combined trace elemental and isotopic modelling results suggest that the least evolved samples of the early stage were formed by 2–4% melting of an amphibole-bearing garnet lherzolitic mantle source, which was metasomatised by 0.3–0.5% contribution of subducted slab component with a ratio of sediment melt/AOC (altered oceanic crust) melt about 90:10. A depleted lherzolitic mantle source containing apatite and garnet through inputs of 0.6–0.8% melts derived from the subducted oceanic slab, with 5–10% partial melting degree, could produce the least evolved samples of the late stage. Thermobarometric calculations reveal that the least evolved samples of the late stage are derived from the lithosphere-asthenosphere boundary at a depth of 77–82 km; in contrast, those of the early stage are produced from the lithosphere at a depth of 66–69 km. Literature data and the findings obtained from this study indicate that the onset of the Arabian-Eurasian collision may have occurred in the Oligocene and lithospheric dripping caused by the hard collision that occurred around the Late Miocene-Early Pliocene may produce the Melikler volcanic rocks. [ABSTRACT FROM AUTHOR]

Geochemical and isotopic markers of the most primitive basaltic melts allow us to understand the temporal evolution of the lithospheric mantle and geodynamic processes. This paper presents the geochemical, Sr-Nd-Pb-Hf isotopic data, K Ar dating and the petrological evolution of the petrogenesis of the late Miocene-early Pliocene basaltic volcanism observed in the Baltacık-Günkoru region in the northeastern of Lake Van in Eastern Anatolia Collision Zone (EACZ). These data allow us to understand the origin of collision-related magmatism and the geodynamic processes in the late Miocene-early Pliocene in the EACZ. Geochronological age data (K Ar) indicate that basaltic volcanism erupted between ∼7.63 and 5.24 Ma. Major-incompatible trace element contents, Sr Nd isotopic compositions of the studied samples and EC-AFC (energy-constrained recharge, assimilation, and fractional crystallization), and MELTS model calculations point out that basaltic volcanism has undergone fractional crystallization but unaffected crustal contamination. Petrological models created using 87Sr/86Sr, ℇNd and ℇHf isotopic data, together with calculated primary melt compositions of basaltic lavas, indicate that the DMM-type (Depleted Morb Mantle) mantle source is metasomatized by melts rather than fluids derived from subducted oceanic lithosphere. Combined trace element and isotopic modelling results indicate that the calculated primary melts were formed by 2.5–5% melting of a metasomatised spinel-garnet lherzolitic mantle source, including amphibole and 1% residual rutile. This mantle source has been metasomatised by a 1–3% contribution of subducted slab component, with a sediment melt/AOC (altered oceanic crust) melt ratio of about 90:10. Thermobarometric calculations based on calculated primary melts compositions indicate that the lithosphere-asthenosphere boundary (LAB) is a depth of 67 ± 4 km for 7.53–5.24 Ma. Literature data and the findings obtained from this study indicate that the late Miocene to early Pliocene basaltic volcanism in the south of the EACZ) is progressed by the delamination of the mantle lithosphere. This delamination occurred in a fragmented/patched or dripping manner rather than whole-scale delamination in the 3–4 million years between ∼9 Ma and 5–6 Ma. [Display omitted] • Studied basalts erupted in the Late Miocene to Early Pliocene. • LAB under EACZ decreased from Late Miocene to Early Pliocene via delamination. • Delamination emerged fragmented/patched or dripping rather than a whole scale. [ABSTRACT FROM AUTHOR]

The Early Miocene Taşkapı-Mecitli granitoid that is located in the northern section of the Eastern Anatolia Collision Zone has typical I-type, metaluminous and calk-alkaline characteristics. It also contains mafic microgranular / magmatic enclaves (MMEs). New Ar-Ar dating results show that the age of the Taşkapı-Mecitli granitoid is ∼23 Ma and it crystallised in the Early Miocene, in contrast to its previously known Cretaceous age. Identical crystallisation ages (∼23 Ma), similar mineral assemblages and geochemical compositions, and indistinguishable isotopic compositions of MMEs and host rocks imply that the MMEs are most consistent with a cumulate origin formed at earlier stages of the same magmatic system that produced the Taşkapı-Mecitli granitoid. MELTS modelling suggests that magma of the Taşkapı-Mecitli granitoid was the result of fractionation under a crustal pressure of 4 kbar, with a H 2 O content of 1.5%. EC-AFC model calculation reveals that the Taşkapı-Mecitli granitoid includes from 0.5% to 2% crustal assimilation rates. These rates indicate that crustal contamination can be negligible when compared to fractional crystallisation in the evolution of the magma beneath the Taşkapı-Mecitli granitoid. The partial melting model calculations and MORB-normalised trace element concentrations of the least evolved samples of the Taşkapı-Mecitli granitoid are consistent with those of mafic melts obtained from partial melting of interacting mantle- lower crust with a melting degree of 18%. The age (23 Ma) of the post- or syn-collisional Taşkapı-Mecitli granitoid suggests that the collision between Arabian and Eurasian plates could be before/around ∼23 Ma (Late Oligocene to Early Miocene). [ABSTRACT FROM AUTHOR]

Collision-related Quaternary mafic volcanism to the north of Lake Van (Eastern Anatolia, Turkey) occurred by eruptions from both volcanic centres and extensional fissures trending approximately north-south. We report new major, trace and rare earth element abundances, Sr-Nd-Pb isotope ratios and K-Ar ages for basaltic and more evolved hawaiitic and mugearitic lava flows. The new K-Ar ages indicate that magmatic activity occurred between 10 and 04 Ma. The volcanic products consist of mildly alkaline lavas, ranging in composition from basalt to hawaiite and mugearite. Energy-constrained assimilation and fractional crystallization (EC-AFC) model calculations suggest that the least evolved basaltic samples were unaffected by the combined effects of fractional crystallization and crustal contamination processes, in contrast to the more evolved hawaiitic and mugearitic lavas, which have experienced up to 2-3% crustal assimilation. Calculations based on crustal temperatures and Curie point depths indicate that the magma chamber, from which the basic to evolved lavas were derived, might be located at a depth of around 6-8 km, within the upper crust. Enrichment of large ion lithophile elements and light rare earth elements relative to high strength field elements, and higher 87Sr/86Sr and Pb isotopic ratios and lower 144Nd/143Nd of the least evolved basaltic samples indicate that the mantle source region of the Quaternary mafic magmas might have been enriched by melts that were derived from subducted sediments with a partial melting degree of around 10% rather than from Altered Oceanic Crust melts and fluids. Our model melting calculations show that the basaltic melts might have been produced by melting of a mantle source containing both amphibole and garnet with a partial melting degree of 3%. Results of our petrological models indicate that a metasomatized mantle source, which was infiltrated by a mixture of 93% mantle melt and 7% sediment melt plus 001% residual rutile, added to mantle melt, could have been the source composition of the basaltic melts that produced the Quaternary mafic volcanism. [ABSTRACT FROM AUTHOR]

In Eastern Anatolia, the Karayazı–Göksu basaltic plateau is one of the basaltic eruption centers of post-collisional volcanism, located between the convergence zone of the Arabian and Anatolian plates. The geological and geochemical evolution of the plateau is documented using new 40Ar/39Ar age data, major-and trace element abundances, mineral geochemistry, and isotope compositions (Sr–Nd–Hf) for better understanding the petrogenesis and mantle source characteristics. Samples yield whole-rock 40Ar/39Ar ages of 12.53 ± 0.05 and 12.68 ± 0.05 Ma for transitional basalts (Middle Miocene), 5.88 ± 0.20 Ma for tholeiitic lavas (Late Miocene), and 2.28 ± 0.03 and 2.48 ± 0.12 Ma for alkali members (Early Quaternary). The results suggest that the fractional crystallization of olivine and clinopyroxene in transitional, tholeiitic and lower alkaline lavas, and clinopyroxene in upper alkaline lavas, played a crucial role in their magmatic evolution without significant crustal contamination. Clinopyroxene-liquid equilibria indicate that the crystallization of transitional basalts occurred at the Moho and lower crust (temperature range 1157–1215 °C), tholeiitic basalts at the lower crust (temperature range 1154–1195 °C), alkaline basalts at lower to mid-crustal depths (temperature range 1083–1195 °C). The subduction-related metasomatism is in the form of melts derived from subducted sediments and decrease from Middle Miocene transitional to alkaline Early Quaternary basalts, as indicated by the Sr–Nd–Hf isotopes and Ba/La and Th/Yb contents. The Early Quaternary alkaline basalts contain contributions from isotopically depleted but chemically enriched (enriched-MORB-like) asthenospheric mantle domain. Major elements–based parameters and olivine mineral chemistry yield that Karayazı–Göksu basalts could not be derived from a sole peridotite mantle source; the pyroxenite/eclogite-like mantle component would have contributed to the members of the plateau. Three-component mixing results using Sr Nd isotopes indicate that the altered oceanic crust contributes to 0.5%–1% of the melt (crust vs. sediment about 65:35) for tholeiitic and alkaline basalts and reach up to 4% for transitional basalts (crust vs. sediment about 55:45). Melt equilibration depths of the basalts indicate that the lithospheric thickness of the region has not been changed on a large scale since the Middle Miocene to the Early Quaternary. [Display omitted] • Middle-Miocene to Early-Quaternary basaltic rocks. • Decreasing subduction influence from Middle Miocene to Early Quaternary. • E-MORB like asthenospheric mantle component for younger members. • Localized removal of Eastern Anatolian lithospheric mantle. [ABSTRACT FROM AUTHOR]

Graphical abstract Hıghlıghts • HMS is the first sediment-related VMS deposit discovered in the Anatolia. • Containing more than 1% Cu-25 million tons reserve, ÇMC. • HMS mineralization may have formed in a back-arc rift tectonomagmatic environment. Abstract Hanönü massive sulfide (HMS) mineralization is the first sediment-hosted massive sulfide deposit discovered in Anatolia (Turkey). Containing more than 1% Cu and with more than 25 million tonnes reserve, the HMS mineralization is located in the Çangaldağ Metamorphic Complex (CMC) in the central Pontides within meta-volcaniclastic rocks with mafic sill and/or lava interlayers. Rocks related to mineralization were exposed to metamorphism under the greenschist facies conditions. Tectonism and metamorphic processes affected all units including ore. The HMS mineralization consists dominantly of Cu (0.2–6.9%) accompanied by Zn (239 ppm–1%) and comprises massive, banded and disseminated sulfide bodies. The main ore minerals include pyrite, chalcopyrite, with minor sphalerite and magnetite. The regular stratigraphy displaying uninterrupted layers of volcanoclastics contains mafic lava or sills within the sequence with the mineralization initially emplaced within immature clastics and then subjected to metamorphism as a package, which indicates that the ore and wall rocks formed in the same paleotectonic environment. Data obtained from melt models of mafic lava or sills related to the HMS mineralization indicate these rocks formed in back-arc basins from a mixture of 70% depleted MORB mantle and 30% asthenospheric melt with melting degrees possibly of 8–15%. According to isotope data, lead from the HMS mineralization may be sourced from an arc-related environment, with magmatic activity in the lower crust and upper mantle. Geologic and geochemical data indicate that the HMS mineralization may have formed in a back-arc rift tectonomagmatic environment. [ABSTRACT FROM AUTHOR]

• Zeybek massive sulfide deposit is one of the recent discoveries, which is located in Turkey. • The Zeybek VMS mineralization is similar with mafic-siliciclastic type VMS deposits. • Cu-rich massive ore samples yielded, 178 ± 2.2 Ma (MSWD: 4.1) by Re-Os geochronological age. • The Zeybek VMS occurred in an arc-back arc tectonic environment. Located in the north of Anatolia, the Pontide Orogenic Belt hosts Turkey's most important volcanogenic massive sulfide (VMS) deposits. Studies completed in the last ten years have discovered new massive sulfide deposits in the Central Pontide zone. The Zeybek VMS deposit is one of these newly-discovered deposits found in the Central Pontides. This deposit is associated with the Çangaldağ Metamorphic Complex occurring as east-west-striking tectonic slices. The Çangaldağ Metamorphic Complex is an allochthonous mass of metavolcanic, metavolcaniclastic and metaclastic rocks in the form of imbricated tectonic slices. Zeybek massive sulfide deposit is located within metaclastic rocks intercalated with mafic sills or lava flows in this complex. The major ore mineral paragenesis in the Zeybek VMS deposit comprises pyrite, chalcopyrite and sphalerite, with lower amounts of bornite, covelline, chalcocite and magnetite. With thirty thousand meters of drilling in the mineralized area, 20 million ton resources with 0.32 wt% Cu were determined. According to the wall-rock mineralization relationships, mineralization style and ore geochemistry of the Zeybek VMS mineralization, it is similar to a mafic-siliciclastic type volcanogenic massive sulfide formation. Re-Os geochronologic studies of chalcopyrites from the Cu-rich massive ore samples obtained a 178 ± 2.2 Ma (MSWD: 4.1) 187Re/188Os against 187Os/188Os isochron. Geochemical and isotopical age data associated with the Zeybek VMS deposit indicate that the mineralization occurred in an arc-back arc tectonic environment, which developed in Middle Jurassic age intra-ocean as a result of the closure of north-ward subduction that resulted the closure of the Tethys ocean. [ABSTRACT FROM AUTHOR]