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The petrogenesis of the ungrouped iron meteorite Lewis Cliffs (LEW) 86211 and its proposed pair LEW 86498 has remained elusive in the decades since their discovery in Antarctica. Wasson (1990) and Kracher et al. (1998) noted the enrichment in the siderophile refractory elements, fine-grained texture, and high abundances of sulfides in LEW 86211 as features that are both difficult to explain and that set it apart from other iron meteorites. In this work, we investigate the pairing and formation of these two ungrouped iron meteorites using a combination of petrography, electron microprobe analyses, and secondary ion probe analyses of oxygen-three isotope of olivine. Similarities in petrographic features and phase compositions further support the initial pairing of LEW 86211 and 86498. The bulk composition of LEW 86211 (Wasson, 1990) closely resembles those of separated chondritic metallic components (e.g., Kong and Ebihara, 1997), which indicates this pairing group formed directly from this portion of a chondrite. The metal-sulfide cellular textures and mineral compositional trends are consistent with LEW 86211 and 86498 forming by rapid cooling of the FeNiS immiscible liquid of a larger chondritic impact melt unit. Previous bulk oxygen-three isotope analyses (Clayton and Mayeda, 1996) combined with the in situ oxygen-three isotope analyses from this work are consistent with LEW 86211 having a carbonaceous chondrite provenance. LEW 86211 is most similar to CR chondrites in its oxygen-three isotope signatures, but may not be from an established carbonaceous chondrite group. The silicate inclusions in LEW 86211 and 86498 record evidence of pre-impact metamorphism and later reduction related to contact with the metal-sulfide impact melt liquid. The silicate inclusions appear to have been engulfed by metal-sulfide liquids rather than part of the impact melted unit. Additionally, the size of this sulfide-dominated pairing group compared to the volume of sulfides and metal in unmelted CR chondrite suggests that these meteorites originated from a much larger carbonaceous chondrite impact melt body than has been previously recognized (e.g., Lunning et al., 2016).

Thirteen phosphate minerals are found in IIIAB iron meteorites. Four of these (sarcopside, graftonite, johnsomervilleite, and galileiite) constitute the majority of occurrences. The IIIB iron meteorites are confined to occurrences of only these four phosphates. The IIIA iron meteorites may contain one or more of these four phases; they may also contain other rarer phosphates, and silica (in two instances) and a silicate rock (in one instance). Thus, the IIIA lithophile chemistry is more varied than that of the IIIB meteorites. Based on petrographic relations, sarcopside appears to be the first phosphate to form. Graftonite is probably formed by recrystallization of sarcopside. Johnsomervilleite and galileiite exsolved as enclaves in sarcopside or graftonite at lower temperatures, although some of these also nucleated as separate crystals. The IIIAB phosphates are carriers of a group of incompatible lithophile elements: Fe, Mn, Na, Ca, and K, and, rarely, Mg as well as Pb. These elements (and 0) were concentrated in a residual, S-rich liquid during igneous fractional crystallization of the IIIAB core mass. The phosphates formed by oxidation of P as the core solidified and excluded 0, which increased its partial pressure in the residual liquid. The trace siderophile trends in bulk IIIAB metal are paralleled by a mineralogical trend of the phosphate minerals that formed. For IIIAB meteorites with low-Ir contents in the metal, the phosphates are mainly Fe-Mn phases; at intermediate Ir values, more Na-bearing phosphates appear; at the highest Ir values, the rarer Na-, K-, Mg-, Cr-, and Pb- bearing phosphates appear. The absence of significant amounts of Mg, Si, Al, and Ti suggest depletion of these elements in the core by the overlying mantle.

The mineral chemistry of several Pliocene alkali basaltic rocks from Burgenland and Styria (Eastern Austria) have been investigated in order to determine the evolution path of the basalt magmas prior to eruption. With their wide range of substitutions, clinopyroxenes provide the best records of the evolution history of rocks. Pyroxene phenocrysts of the investigated basalts show both concentric and sector zoning. The investigation of sector zoned crystals shows, that not only Ti, Al and Fe contents are different in different sectors but there can be significant differences also in their Cr content. This fact apparently suggests that the distribution of Cr between clinopyroxene and melt could be influenced by crystallization kinetics. The depth of crystallization and differentiation of the basalts can be estimated from Ti and Al contents of clinopyroxene phenocrysts. From a combination of data on clinopyroxene composition, compatible trace element contents and mg-values of the rocks, it is concluded, that the alkali basalts of Pauliberg and Steinberg underwent slight olivine and clinopyroxene fractionation in shallow magma chambers prior to eruption, while the nephelinite of Stradnerkogel evolved mainly through clinopyroxene fractionation under high pressure conditions, probably in the upper mantle.

Ruhobobo is a new meteorite which fell in Rwanda, Africa, in 1976. We found and analyzed olivine (Fa 23.4), opx (Fs 19.7, Wo 1.4), cpx (Fs 7.5, Wo 44.0), plagioclase (An 11.7, Or 5.6), chromite, “whitlockite”, kamacite, taenite and troilite. Based on these analyses and on microscopic observation, Ruhobobo is an unshocked L6 chondrite.

New data on trace element partitioning in the Fe-Ni-S-P system suggest that iron meteorites of groups IAB and IIICD come from one or more S-rich parent bodies. Heating of the IAB parent body melted all troilite, but caused only very minor partial melting of silicates. Cocrystallization of metal and troilite produced the high-Ni "tail" of group IAB. The trace element patterns are consistent with a parent body with CI sulfur and siderophile abundances. Compositionally the parent body was intermediate between ordinary and E4 chondrites, its thermal history was in between ordinary chondrite and fully differentiated (achondrite, group IIIAB iron) parent bodies. IAB and IIICD may be complementary fractional crystallization/partial melting suites from the same parent body. Since the model also explains some unusual irons, it seems for the first time possible to understand the genesis of almost all irons, and link them to the major groups of primitive and differentiated meteorites.

The S contents of iron meteorite parent bodies are estimated on the basis of cosmochemical relationships to undifferentiated meteorites, the results are compared to observations on the major magmatic iron meteorite groups, and evidence is presented that S/Ni ratios in their parent melts were much lower than those inferred for the parent body. Several alternative models to account for the discrepancy are offered, including volatilization of S from the IIAB parent body, liquid immiscibility, and metastable liquid layers produced by episodic melting. Finally, the fate of the S-rich meteoroidal material is discussed, as well as the question of why it seems to be missing from meteorite collections.

We describe three lithic fragments from the Lancé carbonaceous chondrite which apparently are of igneous origin and of basaltic parentage. They consist of large enstatite grains (pheno-crysts ?) which poikilitically include some olivine and abundant Fe-Ni metal and Fe sulfide blebs. These enstatites are set into a matrix of partly ophitic and partly porphyritic plagioclase (~ an71) and interstitial clinopyroxene and clinopyroxene plus plagioclase intergrowths. Mineral compositions are highly variable and reflect a complex genesis. Olivine compositions range from fo5 to fo60 and sometimes exhibit compositional zoning. Enstatites are mostly of en 98 com-position with some Fe-enrichment towards grain surfaces and cracks. Plagioclases have about an71 but mostly are altered to nonstoichiometric high-alkali compositions (with original Al/Si ratios corresponding to ~ an 70) or are partly replaced by K-free nepheline. Generally two clinopyroxenes are present within the plagiophyric portions of the fragments: One low Fe/Mg augite (~ en53 wo44) rich in Ti, Al, Cr, and Mn (Fe/Mn ≦ 2) and a ferrosalite (~ en15 wo47) poor in Ti, Cr, and Mn (Fe/Mn ~ 100). One fragment also contains spinel (hercynite) which apparently is xenocrystic in nature. Our investigation indicates: (1) The fragments are of igneous origin. (2) The original melt was of basaltic composition, crystallizing the primary mineral association ol + en + plag + low-Fe augite. (3) During crystallization the melt suffered strong reduction which led to segregation of Fe-Ni droplets from the melt and which continuously lowered the Fe/Mn ratio of successively crystallizing silicates from nearly chondritic (~ 100) to 0.6. (4) Probably after incorporation into the Lancé breccia the fragments suffered to different degrees metasomatic alterations which were caused by the addition of Na, K, and Fe to the system. The origin of the pre-Lancé basaltic melt cannot yet be established.

Oktibbeha County, the most Ni-rich iron meteorite, has been analyzed for Ni, Co, Cu, Ga, Ge, As, Sb, Ir, and Au. Cu and Sb are higher than in any other iron, but other trace elements are within the ranges typically found in iron meteorites. Extrapolation of trace element trends in group IAB indicates that Oktibbeha County is a member of this group. This sheds light on the origin of groups IAB and IIICD, which are thought to be derived from impact melts on parent bodies of chondritic composition. Lafayette (iron), another sample reported in the literature to have a similarly high Ni content, is probably a pseudometeorite.

Some of the properties of IAB and IIICD iron meteorites thought to be derived from partially differentiated planetesimals are summarized, and the physical aspects that may have controlled parent body differentiation and affected the composition of the sulfide melt are outlined. The chemical evolution of the parent body is then discussed, and observations supporting the partial differentiation model are examined. Finally, an attempt is made to reinterpret barometric and chronometric data in light of the partial differentiation model, and tentative conclusions are presented.

Relict olivine and pyroxene grains have been identified in chondrules from ordinary and carbonaceous chondrites that probably did not crystallize in situ. Some of these olivines are clear, but others contain fine-grained Fe, Ni ('dusty olivines') and resemble previously described occurrences in ordinary chondrites. There are also chondrules in which all olivine is dusty. It is concluded that: (1) not all relict olivines are dusty, (2) not all dusty olivines crystallized outside the chondrule in which they occur, and (3) some dusty olivines were produced during chondrule formation by a reduction process that affected the whole chondrule. The occurrence of dusty olivines and relict pyroxenes and olivines in chondrules from carbonaceous as well as ordinary chondrites supports the argument that chondrules from all chondrites had similar origins and histories. It is proposed that chondrules and mineral fragments were transported across f(O2) gradients in the solar nebula while they were hot, or were reheated in an environment different from the one in which they formed. Partially molten chondrules sometimes incorporated mineral grains or chondrules with different redox states, producing compound chondrules and chondrules containing anomalous grains. Dusty olivines may also have formed when hot chondrules were transported to regions of lower oxygen fugacity.

Leoville is a CV3 chondrite that containsn a large variety of inclusion, besides refractory incusions resembling those in Allende, fine-grained, dark inclusions are especially prominent. Some of these are xenoliths of material very similar to CM chondrites in texture, bulk composition, and oxygen isotopes. However, they show an unusually large range in the degree of hydrous alteration. Other dark inclusions are similar to host matrix. The CV3 host of this breccia is similar to other CV chondrites, although less metamorphosed than Allende. It is suggested that Leoville is a typical accretionary breccia whose parent body accreted after the Cm-like material represented by the xenoliths had formed and undergone alteration. After accretion Leoville suffered servere deformation, leading to foliation stronger than in any other chondrite, but the nature of the event that caused this remains unclear.