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The 295 K powder neutron diffraction patterns and the temperature dependence of the Mossbauer spectra of Nd2Fe17−xTix and Nd2Fe17−xTixNy have been measured. A Rietveld refinement of the neutron diffraction patterns yields the Nd2Fe16.32Ti0.68 and Nd2Fe16.32Ti0.68N2.7 stoichiometries for the two compounds and indicates that titanium occupies only the 6c crystallographic site and nitrogen only the 9e site in the rhombohedral Th2Zn17 structure. The insertion of interstitial nitrogen into Nd2Fe16.32Ti0.68 produces a 6.8% increase in the unit cell volume. The relative areas of the Mossbauer spectral components indicate that iron–iron, iron–titanium, and titanium–titanium 6c–6c dumbbell pairs exist in both of these materials. The magnetic hyperfine fields observed for the iron on the 6c site in the iron–titanium dumbbell pair in both compounds is substantially reduced from that found in Nd2Fe17 and Nd2Fe17N2.6 because of the titanium dumbbell near neighbor. For all the remaining hyperfine parameters there is a ...

The magnetic properties of a series of Ce2Fe17−xAlx solid solutions with x equal to 0.00, 0.88, 2.06, 2.81, 3.98, 5.15, 6.08, 7.21, 8.20, 9.08, 9.84, and 10.62 have been studied by magnetic measurements, neutron diffraction, and Mossbauer spectroscopy. The compounds crystallize in the rhombohedral Th2Zn17‐type structure. Magnetization studies indicate that the Curie temperature increases uniformly from 238 K for Ce2Fe17 to 384 K for Ce2Fe14Al3 and then decreases at higher aluminum content. Powder neutron diffraction results, obtained at 295 K, indicate that aluminum avoids the 9d site for all x values and preferentially occupies the 18h site at low aluminum content. Aluminum shows a marked preference for the 6c site for x≳6. The room‐temperature iron magnetic moments increase from x=0 to 2 and then decrease for x≳2. The Mossbauer spectra have been fit with a binomial distribution of the near‐neighbor environments in terms of a maximum hyperfine field, Hmax, for an iron with zero aluminum near neighbors, a...

A series of Nd2−yDyyFe17−xSix solid solutions with x=0, 1, 2, and 3 and y=0, 0.5, 1.0, 1.5, and 2.0 were prepared by induction melting stoichiometric amounts of high-purity elements. The x-ray diffraction data confirmed that the postannealed samples are 2:17 intermetallics of the R3m space group. The lattice parameters and unit-cell volumes were calculated using FULLPROF to analyze the neutron diffraction (ND) data. It was observed that for a particular y, the unit-cell volume decreased almost linearly with increasing silicon content (x⩽3), as is observed for single rare-earth 2:17 intermetallic compounds. For a given x, the cell volume decreased almost linearly with the increasing replacement of neodymium with dysprosium. The ND studies revealed additional density along the c-axis chains of Fe dumbells and rare-earth atoms. The perfect a-b-c stacking of the CaCu5 layers with a regular one third replacement of the rare-earth atoms by Fe dumbells appear to be broken, resulting in a disordered rhombohedral...

The magnetic properties of a series of Nd2Fe17−xAlx solid solutions, with x equal to 2.04, 4.01, 5.97, 7.94, and 9.06, have been studied by magnetic measurements, neutron diffraction, and Mossbauer spectroscopy. Magnetization studies indicate that the Curie temperature increases from 330 K in Nd2Fe17 to a maximum of ∼470 K at an x of 3.5. The compounds crystallize in the Th2Zn17 structure with lattice parameters and unit cell volumes which increase linearly with increasing aluminum content. The neutron diffraction results indicate that aluminum atoms are excluded from the 9d site, prefer the 18h site at low aluminum content, and prefer the 6c and 18f sites at high aluminum content. At 10 K the magnetic moments of the iron and neodymium atoms are collinear and take up a basal orientation at all aluminum contents. The moments decrease with increasing aluminum content and the magnetic moments per unit cell at 10 K are in excellent agreement with the 4.2 K saturation magnetization values. At 295 K the Nd2Fe17...

An x‐ray diffraction study of the substitution of gallium in Tb2Fe17 to form the Tb2Fe17−xGax solid solutions indicates that the compounds adopt the rhombohedral Th2Zn17 structure. The unit cell volume and the a‐axis lattice parameter increase linearly with increasing gallium content. The c‐axis lattice parameter increases linearly from x=0 to 6 and then decreases between x=7 and 8. Magnetic studies show the Curie temperature increases by ∼150° above that of Tb2Fe17 to reach a maximum between x=3 and 4, and then decreases with further increases in x. Neutron diffraction studies of Nd2Fe15Ga2 and Tb2Fe17−xGax, with x equal to 5, 6, and 8, indicate that the gallium completely avoids the 9d site, occupies the 6c ‘‘dumbell’’ site only at high values of x and strongly prefers the 18f site at high values of x. The magnetic neutron scattering indicates both that the terbium sublattice magnetization couples antiferromagnetically with the iron sublattice and that there is a change in easy magnetization direction f...

The Mossbauer spectra of Th2Fe17 and Th2Fe17N2.6 have been measured at various temperatures between 85 and 295 K and analyzed with a model that is based on the Wigner–Seitz cell environment of each iron site, the orientation of the magnetization, and the magnetic moments as determined from either neutron‐diffraction measurements or band‐structure calculations. Upon nitrogenation of Th2Fe17, the 85 K weighted average isomer shift increases from 0.037 to 0.156 mm/s and further the isomer shifts of the four crystallographically distinct sites increase in agreement with the increase observed in their Wigner–Seitz cell volumes and the presence of a nitrogen near neighbor for two of the sites. The nonmagnetic thorium in Th2Fe17N2.6 yields an easy axis of magnetization which, in contrast to magnetic rare earths in R2Fe17 and R2Fe17Nx, is in a general basal direction and not oriented along one of the basal axes. The isomer shift and its temperature dependence for both Th2Fe17 and its nitride are very similar to those observed in related rare‐earth R2Fe17 compounds and their nitrides. Upon nitrogenation of Th2Fe17, the 85 K weighted average hyperfine field increases from 256.3 to 336.5 kOe. However, the increases on the 6c and 18f sites are smaller than those observed on the 9d and 18h sites; changes which are in agreement with changes in the magnetic moments observed by neutron diffraction and calculated for the nitrogenation of Nd2Fe17, Gd2Fe17, and Y2Fe17.The Mossbauer spectra of Th2Fe17 and Th2Fe17N2.6 have been measured at various temperatures between 85 and 295 K and analyzed with a model that is based on the Wigner–Seitz cell environment of each iron site, the orientation of the magnetization, and the magnetic moments as determined from either neutron‐diffraction measurements or band‐structure calculations. Upon nitrogenation of Th2Fe17, the 85 K weighted average isomer shift increases from 0.037 to 0.156 mm/s and further the isomer shifts of the four crystallographically distinct sites increase in agreement with the increase observed in their Wigner–Seitz cell volumes and the presence of a nitrogen near neighbor for two of the sites. The nonmagnetic thorium in Th2Fe17N2.6 yields an easy axis of magnetization which, in contrast to magnetic rare earths in R2Fe17 and R2Fe17Nx, is in a general basal direction and not oriented along one of the basal axes. The isomer shift and its temperature dependence for both Th2Fe17 and its nitride are very similar to t...

A neutron‐diffraction study of Nd2Fe14−xSixB has shown that silicon preferentially occupies the 4c site in the transition‐metal sublattice in Nd2Fe14B. Silicon also exhibits a moderate preference for the 8j1 site, is almost excluded from the 16k2 site, and avoids the 16k1, 8j2, and 4e sites. The silicon site occupancy is correlated with a preference for a silicon atom to have rare‐earth atoms in its coordination environment. The Mossbauer spectra of Nd2Fe14−xSixB have been fit with a model which takes into account the distribution of near‐neighbor environments of an iron atom due to the presence of silicon. These fits show that the substitution of silicon in the near‐neighbor environment of an iron atom primarily influences the long‐range contributions to the hyperfine field experienced by the iron. The mechanism for the increase in the Curie temperature when silicon is added to Nd2Fe14B‐type magnets is more subtle than previously believed, but can be explained by the relative decrease in the proportion o...

The neutron diffraction powder patterns of Pr2Fe17 and Pr2Fe17N2.6 have been measured at 295 K and refined within the Th2Zn17 structure type to give the structural changes which occur upon nitrogenation; changes which include a 6.4% expansion of the unit cell volume. The Mossbauer spectra of Pr2Fe17 and Pr2Fe17N2.6 have been measured between 85 and 295 K and analyzed with a model which is based on the Wigner–Seitz cell environment of each iron site, the basal orientation of the magnetization, and a comparison with the Mossbauer spectra of Nd2Fe17 and Nd2Fe17N2.6. Upon nitrogenation of Pr2Fe17, the 85 K‐weighted average isomer shift increases from 0.049 to 0.156 mm/s, and the isomer shifts of the four crystallographically distinct iron sites increase in agreement with the increase found in their Wigner–Seitz cell volumes and the presence of a nitrogen near‐neighbor for the 18f and 18h sites. The temperature dependence of the isomer shifts indicates an increase in covalency upon the formation of the nitride...

A systematic study of the magnetic moments and hyperfine interactions of the LaNi5–xFex compounds was performed using the spin-polarized tight-binding-linear-muffin-tin-orbital methods (TBLMTO). The calculated results were compared with neutron diffraction and Mossbauer experimental data and found to be in good agreement. Fe atoms exhibit more localized magnetic moments in LaNi5–xFex when the Fe content x is lower than 1.0. The calculated magnetic moments of the Fe atoms approach values as large as 2.5μB due to the dilution effect. The strong s–d hybridization between the Ni and La atoms and the neighboring Fe in the Fe-substituted samples results in a large transferred valence contribution to the total hyperfine field. It is found that the Fe and Ni magnetic moments decrease abruptly at a unit cell volume which is 5% smaller than the observed volume in LaNi4Fe due to the instability of the Fe magnetic moment. LaNi5 becomes ferromagnetic when the unit cell volume is larger than its original volume.

The Mossbauer spectra of Nd2Fe17 and Nd2Fe17N2.6 have been measured at various temperatures between 78 and 295 K and analyzed with a model that is based on the Wigner–Seitz cell environment of each iron site, the orientation of the magnetization, and the magnetic moments as determined from either neutron‐diffraction measurements or band‐structure calculations. Upon nitrogenation of Nd2Fe17, the weighted average isomer shift increases from 0.060 to 0.164 mm/s and further the isomer shifts of the four crystallographically distinct sites increase in agreement with the increase observed in their Wigner–Seitz cell volumes and the presence of a nitrogen near neighbor for two of the sites. Upon nitrogenation of Nd2Fe17, the weighted average hyperfine field increases from 292.3 to 333.8 kOe. However, the increases on the 6c and 18f sites are much smaller than those observed on the 9d and 18h sites; changes which are in agreement with calculated changes in the magnetic moments upon nitrogenation of Nd2Fe17, Gd2Fe17, and Y2Fe17. The temperature dependence of the isomer shifts indicates an increase in covalency upon the formation of the nitride.

The crystallographic and magnetic properties of LaNi5−xMnx with x=1, 1.5, and 2, have been investigated using x-ray and neutron diffraction, vibrating sample magnetometer and superconducting quantum interference device measurements. All the samples crystallize in the hexagonal CaCu5-type (P6/mmm) structure. Manganese atoms preferentially occupy the 3g site in the LaNi5 structure. The bulk magnetization of the LaNi5−xMnx powder samples decreases rapidly as nickel is replaced by manganese. A ferrimagnetic model is applied to describe the magnetic structure of the LaNi5−xMnx samples for x=1.5 and 2. A ferromagnetic model gives the best fit of the neutron diffraction data for the LaNi4Mn sample.

A series of Nd2Fe17−xMnx solid solutions with x values between 0 and 6 were prepared and analyzed using magnetic measurements, neutron diffraction, and Mossbauer spectroscopy. All of the Nd2Fe17−xMnx samples crystallized in the Th2Zn17−x-type rhombohedral structure. The lattice parameters and unit cell volumes decrease with increasing manganese content up to ∼x equal to 2, and then increase for higher manganese content. The magnetizations of Nd2Fe17−xMnx decrease with increasing manganese content and Nd2Fe17−xMnx is paramagnetic at room temperature for x greater than 3. The Curie temperature in Nd2Fe17−xMnx solid solutions is maximum for x equal to 0.5 and decreases at a rate of ∼10° per substituted manganese up to x equal to 3, after which it drops sharply. These results are discussed in terms of the manganese site occupancies in Nd2Fe17−xMnx.

The magnetic properties of a series of Tb2Fe17−xAlx solid solutions, with nominal x compositions of 0, 2, 3, 4, 5, 6, 7, and 8, have been studied by neutron diffraction and Mossbauer spectroscopy. Neutron‐diffraction data indicate that the compounds all crystallize with the Th2Zn17 structure and that the aluminum atoms are excluded from the 9d site and show a distinct preference for the 6c site only for an aluminum content greater than 6. The unit‐cell volume increases by approximately 1% per aluminum atom substituted in the formula unit. The magnetic moment per formula unit, measured at 295 K, shows very little change for x less than or equal to 4, but decreases rapidly with increasing aluminum content for higher values of x. Mossbauer spectral results indicate that all the samples are ferromagnetically ordered at 85 K. However, at 295 K Tb2Fe9Al8 is paramagnetic and Tb2Fe10Al7 is either paramagnetic or has at most very small ferromagnetic moments. An analysis of the magnetic spectra with a basal magneti...

The Mossbauer spectra of Sm2Fe17 and Ho2Fe17 and their nitrides have been measured between 295 and 85 K and analyzed with a model which is consistent with our earlier work on R2Fe17 and R2Fe17Nx compounds, where R is Pr, Nd, and Th. This model is completely consistent throughout these rare‐earth compounds and is in agreement with the crystallographic changes occurring upon nitrogenation and with the prediction of band structure calculations. The dramatic increase in Curie temperature in the nitrides results from the expansion of the crystallographic lattice, an expansion which is mainly centered on the 9d and 18h iron sites as is indicated by the increase of their Wigner–Seitz cell volumes upon nitrogenation. The 9d and 18h sites show a larger enhancement of their hyperfine fields as compared to the 6c and 18f sites as a result of improved ferromagnetic exchange between these sites and their near neighbors because of the lattice expansion and the consequent reduced iron 3d‐iron 3d overlap.

The magnetic structures of a series of Y2(Fe1−xMnx)14B samples, with x equal to 0.03, 0.10, 0.25, and 0.37, have been studied by powder neutron diffraction and Mossbauer spectroscopy. Y2(Fe0.97Mn0.03)14B and Y2(Fe0.9Mn0.1)14B are ferromagnetic at both 295 and 85 K, Y2(Fe0.63Mn0.37)14B is paramagnetic at both 295 and 85 K, whereas Y2(Fe0.75Mn0.25)14B is paramagnetic at 295 K and is partially ordered at 78 K. The magnetic structure of Y2(Fe0.75Mn0.25)14B is explained in terms of the preferential Mn occupancy of the transition metal 8j2 site in the Y2Fe14B structure. Small amounts of Mn located in this site are very effective in disrupting the long‐range ferromagnetic coupling.

The 57Fe Mossbauer‐effect spectra of the series of hard magnetic materials, R2Fe14C, where R is Nd, Gd, Tb, Dy, Ho, and Lu, have been measured at 295 K. All of these carbides exhibit uniaxial magnetic anisotropy. The spectra resemble those obtained for the related R2Fe14B compounds and have been fit with the model used earlier for Nd2Fe14B. The magnitude of the hyperfine field on each site, as a function of rare earth, parallels the Curie temperature; the maximum hyperfine fields and the maximum Curie temperature are observed for Gd2Fe14C. A linear correlation is observed between the hyperfine fields on the six sites in the analogous borides and carbides; however, these fields are systematically smaller in the carbides. The decrease in the tetragonal unit cell c‐axis length in the carbides apparently reduces the exchange interactions between the 8j and 16k iron layers and hence reduces the moments. The isomer shift on each site decreases as the atomic number of the rare earth increases, whereas the quadru...

A neutron‐diffraction investigation of a series of Pr2(Fe1−xMnx)14B samples, with x values of 0.00, 0.11, 0.22, 0.30, and 0.35, reveals a preference for the manganese to occupy the 8j2 transition‐metal site,the transition‐metal site with the largest Wigner–Seitz cell volume. Similar site occupancies have been reported previously for Er2(Fe1−xMnx)14B and Y2(Fe1−xMnx)14B. An analysis of the 295‐K Mossbauer spectrum of Pr2(Fe0.89Mn0.11)14B indicates that the internal hyperfine fields on the six iron sites are more substantially reduced from those found in Pr2Fe14B than would be expected from a simple magnetic dilution with manganese. The extent of the field reduction for a specific site increases with the number of manganese near neighbors for the site. Fits of the Mossbauer spectra of Pr2(Fe0.78Mn0.22)14B, Pr2(Fe0.70Mn0.30)14B, and Pr2(Fe0.65Mn0.35)14B, which are paramagnetic at room temperature, give quadrupole splittings consistent with the quadrupole interactions in Pr2Fe14B.

We have studied the structural and magnetic properties of La0.7Sr0.3Mn1−xNixO3 (x = 0.05, 0.1, 0.20, 0.30, and 0.40) perovskites using x-ray and neutron diffraction and magnetic measurements. Our data consist of neutron (λ = 1.479 A) and x-ray (λ = 1.5481 A; Cu Kα) powder diffraction and magnetization measurements. We previously suggested these systems transition from ferromagnetic to antiferromagnetic ordering with the intermediate concentrations containing coexisting domains of ferromagnetically and antiferromagnetically ordered states. Upon further detailed examination, we find that the samples are homogeneous and that neutron data can be fitted to a single long-range magnetically ordered state. The compositional dependent changes are driven by a shift in the dominant near neighbor interaction from ferromagnetic to antiferromagnetic. In the intermediate compositions, peaks previously identified as due to antiferromagnetic ordering, in fact arise from charge ordering; the system remains in a ferromagnet...

A series of Sm2−xTbxFe17−ySiy solid solutions with x=0, 1, and 1.5 and y=1, 2, and 3 were prepared by induction melting stoichiometric amounts of high purity elements. The x-ray diffraction data confirm that the postannealed samples are 2:17 intermetallics of the R3m space group. The lattice parameters and the unit cell volumes were calculated using a modified Rietveld program. The fitted intensities showed behavior related to a disordered rhombohedral structure as inferred from neutron data. It was observed that for a particular y, the unit cell volume decreased almost linearly with increasing Tb content (x=0, 1, and 1.5). The unit cell volume decreases with increasing Si content (y) for a particular x as is also observed for the single rare-earth 2:17 compounds. The Curie temperature measurements show that with increasing Tb content x a decrease in the Curie temperatures of about 3% for y=1, 10% for y=2, and 15% for y=3 was observed. For a particular x, a nearly linear type increase in the Curie temper...

Three samples of Nd2Fe16TiCx, with x equal to 0.0, 0.3, and 2.8, with the Th2Zn17‐type rhombohedral structure, have been studied by powder x‐ray and neutron diffraction, magnetic measurements, and Mossbauer spectroscopy. Nd2Fe16Ti and Nd2Fe16TiC0.3 were synthesized by induction melting stoichiometric amounts of the constituent elements, whereas Nd2Fe16TiC2.8 was synthesized by methane‐derived gas phase insertion of carbon into finely ground Nd2Fe16Ti at 600 K. The neutron diffraction determined titanium site occupancies are similar in both Nd2Fe16Ti and Nd2Fe16TiC2.8 in which titanium preferentially occupies the 6c transition metal site. In contrast, the titanium occupancies in Nd2Fe16TiC0.3 are markedly different in that titanium avoids the 6c transition metal site and randomly occupies the other three transition metal sites. This difference in occupancies most likely occurs because the titanium diffusion rate during the quenching of Nd2Fe16TiC0.3 is affected by the presence of carbon in the melt. Even t...

Six samples of Ce2Fe17−xGax with nominal Ga content x equal to 0, 0.3, 0.5, 0.7, 1.0, 2.0 have been studied by powder neutron diffraction at room temperature. Both crystalline and magnetic refinements have been carried out. All six samples adopt the Th2Zn17‐type rhombohedral structure. The only additional phase found is α‐iron. Gallium atoms are found to have high affinity for the iron 18h site, and are absent from the 9d and 18f sites. The Ga substitution for Fe leads to an expansion of both the a and c axes. The Curie temperature increases from 238 K for Ce2Fe17 to 406 K for Ce2Fe15Ga2. Magnetic refinements on the samples with x=0.3, 0.5, 0.7, 1.0, and 2.0 reveal that the magnetic moments of the four Fe sites are in the basal plane and that their values increase with increasing Ga content.

The neutron diffraction powder patterns of Pr2Fe17 and Pr2Fe17N2.6 have been measured at 295 K and refined within the Th2Zn17 structure type to give the structural changes which occur upon nitrogenation; changes which include a 6.4% expansion of the unit cell volume. The Mossbauer spectra of Pr2Fe17 and Pr2Fe17N2.6 have been measured between 85 and 295 K and analyzed with a model which is based on the Wigner–Seitz cell environment of each iron site, the basal orientation of the magnetization, and a comparison with the Mossbauer spectra of Nd2Fe17 and Nd2Fe17N2.6. Upon nitrogenation of Pr2Fe17, the 85‐K‐weighted average isomer shift increases from 0.049 to 0.156 mm/s, and the isomer shifts of the four crystallographically distinct iron sites increase in agreement with the increase found in their Wigner–Seitz cell volumes and the presence of a nitrogen near‐neighbor for the 18f and 18h sites. The temperature dependence of the isomer shifts indicates an increase in covalency upon the formation of the nitride...

The Mossbauer spectra of Y2Fe14B have been measured from 85 to 296 K. Analysis of the spectra indicates that the near‐neighbor rare‐earth atoms directly influence the orientation of the principal axis of the electric field gradient. The hyperfine parameters are very similar to those of Nd2Fe14B, but the internal fields are somewhat smaller at room temperature in the yttrium compound. The Mosssbauer spectra of Y2(Fe1−xAlx)14B, where x equals 0.00, 0.02, 0.04, 0.06, and 0.08, have been measured at 85 K. The average internal hyperfine field in these compounds decreases linearly with increasing aluminum content.

The crystallographic and magnetic properties of Y2(Fe1−xAlx) 14B, where x equals 0.00, 0.02, 0.04, 0.06, and 0.08, have been investigated by Mossbauer spectroscopy and magnetic measurements at room temperature and 85 K. Magnetic anisotropy and magnetization changes with aluminum substitution indicate that, because of size, the aluminum preferentially occupies the j2 site over the remaining five crystallographically nonequivalent iron sites. This preferential occupation has been confirmed by Mossbauer spectral studies, which indicate that the compositional variation of the hyperfine field for each site is related to the number of near‐neighbor aluminum atoms for the site. This compositional variation is helpful in assigning the different spectral components in these alloys as well as in the related Nd2(Fe1−xCox)14B and Y2(Fe1−xCox)14B alloys. In all cases these assignments are consistent with the local symmetry and coordination environment for each site.

We have used Moessbauer spectroscopy and neutron diffraction to study a series of Y/sub 2/(Fe/sub 1-//sub x/Mn/sub x/)/sub 14/B samples in the composition range from x = 0.0 to 0.4. Y/sub 2/(Fe/sub 0.6/Mn/sub 0.4/)/sub 14/B is paramagnetic at both room temperature and 85 K. The iron quadrupole splitting in this paramagnetic compound allows us to place an upper limit on the quadrupole shift in the magnetic Y/sub 2/(Fe/sub 1-//sub x/Mn/sub x/)/sub 14/B alloys. Refinement of Y/sub 2/(Fe/sub 1-//sub x/Mn/sub x/)/sub 14/B neutron diffraction data have been used to give the site occupancies of manganese on the transition-metal sublattice. Both neutron diffraction patterns and Moessbauer effect spectra indicate a marked preference for the manganese to occupy the 8j/sub 2/ site, which is the largest volume transition-metal site. Both experimental techniques give completely consistent results for the site occupancies in Y/sub 2/(Fe/sub 1-//sub x/Mn/sub x/)/sub 14/B.

The atomic and magnetic structures of Nd2(Fe1−xCox)14B, with x equal to 0.0, 0.1, 0.2, and 0.3, and Y2(Fe1−xCox)14B, with x equal to 0.0, 0.1, 0.2, 0.3, and 0.4, have been investigated by Mossbauer spectroscopy at room temperature and 85 K. A Mossbauer effect spectral component analysis, based on neutron diffraction site populations in Nd2(Fe1−xCox)14B, has revealed a stronger compositional dependence for the hyperfine field and magnetic moment on the j2 site than is observed for the other five iron sites. A similar analysis for the Y2(Fe1−xCox)14B compounds shows lower hyperfine fields and hence moments on the c and e sites, as well as a significant decrease in the hyperfine field at the j1 site as the cobalt concentration is increased. The iron site hyperfine fields, and their dependence on cobalt content, are consistent with the local site coordination environments in both series of compounds.