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Fe/Cr/Fe trilayers were epitaxially grown on atomically flat GaAs(001). For the thickness of Cr spacer layer corresponding to antiferromagnetic coupling, “reversed” minor hysteresis loops were measured with longitudinal magneto-optical Kerr effect(MOKE), i.e., a negative “magnetization” signal was detected when the thicker bottom Fe layer was saturated along the applied field. This behavior is interpreted by depth variations of the MOKE sensitivity. Magnetization reversal shows that both antiferromagnetic switching and spin–flop transition fields depend on the ratio of both Fe film thicknesses. The shape of the MOKE loops becomes more complex with further deposition of MgO and Fe layers on the top of the Fe/Cr/F/GaAs(001) stack. Superconducting quantum interference device measurements confirm the interpretation of the MOKE loops and demonstrate homogeneity and sharpness of the interfaces in the structures.

The effect of electron confinement on the magnetocrystalline anisotropy of ultrathin bcc Fe films is explored by combining photoemission spectroscopy, x-ray magnetic circular dichroism, and magneto-optical Kerr effect measurements. Pronounced thickness-dependent variations in the magnetocrystalline anisotropy are ascribed to periodic changes in the density of states at the Fermi level, induced by quantization of ${d}_{xz}$, ${d}_{yz}$ out-of-plane orbitals. Our results reveal a direct correlation between quantum well states, the orbital magnetic moment, and the magnetocrystalline anisotropy.

The analysis of complex magnetic profiles throughout an ultrathin magnetic films by soft X-ray resonant magnetic reflectivity is discussed. Subnanometer resolution can be achieved allowing the separation of interface and inner layer magnetic contributions as well as the determination of antiferromagnetic and non-collinear spin structures. Reflectivity measurements are carried out up to large scattering angles allowing the determination of the depth-resolved profiles of the out-of-plane magnetic component.

Tetragonal distortion in Fe 1-x Cox alloy films grown epitaxially on Rh(001) substrates results in a strong perpendicular magnetic anisotropy. Since the perpendicular magnetic anisotropy varies with the Fe 1-x Co x film composition, one can grow multilayer structures with ferromagnetic films sequentially showing either an in-plane (e.g., Fe) or out-of-plane (e.g., Fe 0.5 Co 0.5 ) easy-magnetization axis. The Rh spacers mediate an interlayer coupling which couples the magnetizations either ferromagnetically or antiferromagnetically, depending on the spacer thickness. When the anisotropy energy is compatible to the coupling, it produces nonorthogonal magnetization configurations which vary under a small change of the external magnetic field.

A self-corrugated Cu(3)N-Cu(110) molecular network shows the potential to overcome the element dependence barrier as demonstrated by epitaxial growth of atomic nanowires (approximately 1 nm in width) among various 3d, 4d, and 5d elements. Scanning tunneling microscopy shows that all of the investigated atomic nanowires share an identical structure, featuring uniform width, height, orientation and the same minimum separation distance. Ab initio study reveals that the formation mechanism of atomic nanowires can be directly attributed to a strain relief guided asymmetric occupation of atoms on the originally symmetric crest zone of the corrugated network.

The magnetic anisotropy of Fe film grown on vicinal Ag(1,1,10) surfaces was studied with the in situ magneto-optic Kerr effect. Below 200 K, strong oscillations of the uniaxial magnetic anisotropy as a function of Fe thickness with a period of 5.7 monolayers are found, which can even cause the easy magnetization axis to oscillate between perpendicular and parallel to the steps. Such novel oscillation of the anisotropy is attributed to the quantum well states of d-band electrons at the Fermi level in the Fe film. This is unlike the previously observed oscillatory behaviors of ferromagnetic films caused by the quantum well states in nonmagnetic interfacing layers.

Using soft-x-ray resonant magnetic scattering in combination with first-principles calculations for noncollinear magnetic configurations we present a new model of the magnetism in ultrathin fcc Fe films on Cu(001). We find the presence of blocks with robust magnetic structure, while the relative directions of the moments of different blocks are sensitive to the detailed atomic structure and temperature. The magnetic noncollinearity is directly demonstrated, which has not been possible so far.

We studied tetragonally distorted ${\mathrm{Fe}}_{1\ensuremath{-}x}{\mathrm{Co}}_{x}$ alloy films on Rh(001), which show a strong perpendicular anisotropy in a wide thickness and composition range. Analyzing x-ray magnetic circular dichroism spectra at the ${L}_{3,2}$ edges we found a dependence of the Co magnetic orbital moment on the chemical composition of the ${\mathrm{Fe}}_{1\ensuremath{-}x}{\mathrm{Co}}_{x}$ alloy films, with a maximum at $x=0.6$. For this composition, we observed an out-of-plane easy axis of magnetization at room temperature for film thickness up to 15 monolayers. Since both the magnetic orbital moment and the anisotropy energy show similar composition dependence, it confirms that both quantities are directly related. Our experiments show that the adjustment of the Fermi level by a proper choice of the alloy composition is decisive for the large magnetic orbital moment and for a large magnetic anisotropy in a tetragonally distorted lattice.

We grew tetragonally distorted FexCo1-x alloy films on Pd(001). Theoretical first-principles calculations for such films predicted a high saturation magnetization and a high uniaxial magnetic anisotropy energy for specific values of the lattice distortion c/a and the alloy composition x. The magnetic anisotropy was investigated using the magneto-optical Kerr effect. An out-of-plane easy axis of magnetization was observed for Fe0.5Co0.5 films in the thickness range of 4 to 14 monolayers. The magnetic anisotropy energy induced by the tetragonal distortion is estimated to be almost 2 orders of magnitude larger than the value for bulk FeCo alloys. Using LEED Kikuchi patterns, a change of the easy axis of magnetization can be related to a decrease of the tetragonal distortion with thickness.

We present experimental and theoretical studies of Pd/Cu(100) and Cu/Pd(100) heterostructures in order to explore their structure and misfit strain relaxation. Ultrathin Pd and Cu films are grown by pulsed laser deposition at room temperature. For Pd/Cu, compressive strain is released by networks of misfit dislocations running in the [100] and [010] directions, which appear after a few monolayers already. In striking contrast, for Cu/Pd the tensile overlayer remains coherent up to about 9 ML, after which multilayer growth occurs. The strong asymmetry between tensile and compressive cases is in contradiction with continuum elasticity theory, and is also evident in the structural parameters of the strained films. Molecular Dynamics calculations based on classical many-body potentials confirm the pronounced tensile-compressive asymmetry and are in good agreement with the experimental data., Comment: 4 pages, 5 figures, to appear in Phys. Rev. Lett

Magnetization configuration in Fe/Rh/Fe0.5Co0.5/Rh(001) can be non-orthogonal due to competition between the anisotropy and the exchange coupling. Soft x-ray resonant magnetic reflectivity allows us to probe the magnetic profile along the growth axis with in-plane and perpendicular magnetization components. By using different modes of acquisition, we show that it is possible to determine separately the magnetic profile of both magnetization components. Measurements at the Co L3-edge enable us to investigate the magnetism of the alloy layer independently from the layer of Fe.

Magnetic anisotropy depends strongly on the density of states at the Fermi level. If significant contributions to magnetocrystalline anisotropy energy (MAE) are due to spin-polarized quantum well states (QWS), a significant increase of MAE can occur periodically as a function of film thickness. The oscillation period L is determined by the wavelength of the corresponding electron waves. The uniaxial magnetic anisotropy of fcc-Co is found to oscillate with a period of 2.3 ML. In contrast, in bcc-Fe, the uniaxial magnetic anisotropy oscillates with a period of 5.9 ML. We attribute such oscillations to QWS in a minority-spin d-band at the Fermi level.

Tetragonal distortion in Fe0.5Co0.5 alloy films grown epitaxially on Rh(001) substrates results in an easy magnetization axis perpendicular to the film plane up to the thickness of 17 ML. The distortion is supported by a Rh-overlayer; thus the strong perpendicular anisotropy can be kept when another Fe0.5Co0.5 film is grown on top of the Rh/Fe0.5Co0.5/Rh(001) structure. Depending on the thickness of the Rh spacer, the top and bottom Fe0.5Co0.5 films are either ferro- or antiferromagnetically coupled. The net magnetization of the antiferromagnetically coupled Fe0.5Co0.5/Rh/Fe0.5Co0.5 bilayer switches at the field which depends on the difference between magnetizations of both the Fe0.5Co0.5 layers. The final covering of the Fe0.5Co0.5/Rh/Fe0.5Co0.5/Rh(001) structure with Rh increases the switching field. The effect is explained by a locally enhanced magnetization in the Rh/Fe1−xCox interfaces.

In tetragonally distorted Fe0.5Co0.5 alloy films grown epitaxially on Pd(001), Ir(001), and Rh(001) substrates the crystal field locates the electronic states near the Fermi level (EF) with one being below EF and the other above EF with an energy separation smaller than in bulk nondistorted material. This results in a strong uniaxial anisotropy and an easy magnetization axis perpendicular to the film plane up to the thickness up to which the films remain tetragonally distorted. The strongest perpendicular anisotropy is achieved when the Fe0.5Co0.5 films are grown on Rh(001) (c/a=1.24); it systematically decreases for Ir(001) (c/a=1.18) and Pd(001) (c/a=1.13) substrates. The phenomenon can be understood as a result of an increasing uniaxial anisotropy with an increasing c/a ratio up to the maximum at c/a=1.24 for which the maximum uniaxial magnetic anisotropy has been theoretically predicted.

Fe/MgO/Fe single-crystalline magnetotunneling structures were epitaxially grown on GaAs(001). An independent magnetization switching in the Fe electrodes was achieved by pinning the magnetization of the Fe-top electrode by antiferromagnetic coupling across a Cr spacer to another Fe film. Such Fe/Cr/Fe/MgO/Fe/GaAs(001) structures exhibit in-plane anisotropy, which ensures a discrete switching behavior of magnetization simplifying the shape of the hysteresis loop. The field dependence of magnetization was measured along the [110] and [100] crystallographic directions of GaAs(001) substrate and modeled by minimizing the total magnetic energy of the system. A peculiar magneto-optical behavior (similar to a reversed hysteresis loop) is explained by magneto-optical phase angles, which are determined mainly by the optical properties of the semiconducting GaAs substrate.

We have grown Fe films on an epitaxial Pd monolayer on Cu(001) single crystals at room temperature, both Fe and Pd by pulsed laser deposition. The presence of the Pd interlayer influences growth, structure, and magnetism of the Fe films. Up to the thickness of 1.6 ML the Fe films show an out-of-plane easy axis of magnetization which changes to in-plane above. A linear dependence of the longitudinal Kerr rotation on the Fe thickness is obtained despite existing structural transformations. A strong increase of the Curie temperature TC is observed for the Fe films on Pd/Cu(001) compared to the Fe films grown directly on Cu(001). A correlation of the magnetic properties with possible structural changes and the role of Pd monolayer is discussed.

Thermal deposition (TD) and pulsed laser deposition (PLD) techniques were used to prepare GaAs∕Fe(001) crystalline ultrathin films. The magnetic environment of Fe at the Fe∕GaAs(001) interface was investigated by means of conversion electron Mossbauer spectroscopy using an Fe57 probe layer having the equivalent thickness of two atomic layers. The magnetic anisotropies were measured using ferromagnetic resonance. PLD samples were affected by an appreciably higher degree of interface alloying compared with the TD films. The interface in-plane fourfold (cubic) anisotropy is significantly increased and the in-plane interface uniaxial anisotropy is significantly decreased in the PLD samples compared to those prepared using TD. The effective perpendicular demagnetizing field in the PLD films is significantly decreased compared to the TD samples due to an unexpected increase in the interface uniaxial perpendicular anisotropy at the Fe∕Au(001) interface.

Fe ∕ Mg O ∕ Fe ∕ Cr ∕ Fe tunneling structures were epitaxially grown directly on GaAs(001) without buffer layer. Interdiffusion in the Fe ∕ Ga As interface was investigated using conversion electron Mossbauer spectroscopy. An independent magnetization switching in the Fe electrodes was achieved by pinning the magnetization of the Fe-top electrode by antiferromagnetic coupling across a Cr spacer to another Fe film. For transport measurements, optical lithography and ion etching were applied to reduce the junction area. A tunneling magnetoresistance of 10%–12% at room temperature was found.

We show that for some ultrathin multilayer structures the proportionality of the longitudinal Kerr ellipticity signal to the magnetic film thickness does not take place. Instead, thinner magnetic layers give even twice larger contributions than the thicker ones located a few monolayers deeper. This effect is demonstrated both experimentally and theoretically on ultrathin Fe∕Cr∕Fe sandwich systems prepared on GaAs(001) surfaces. Such a behavior is explained by a depth variation of phase relations between the optically reflected wave and the wave generated by the magneto-optical interaction. This mechanism becomes very effective close to the phase where the magneto-optical ellipticity cancels.