1. A 'Biconcave-Alleviated' Strategy to Construct Aspergillus niger-Derived Carbon/MoS2 for Ultrastable Sodium Ion Storage
- Author
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Xianbao Wang, Yao Zhou, Longze Zhao, Shi-Gang Sun, Chen-Xu Luo, Weixin Chen, Tao Mei, Yong Cheng, Xiang Xiao, Ming-Sheng Wang, Ling Huang, Hong-Gang Liao, Jing-Jing Fan, You-Hu Chen, Shiyuan Zhou, and Sangui Liu
- Subjects
Nanostructure ,Materials science ,Sodium ,General Engineering ,General Physics and Astronomy ,chemistry.chemical_element ,Anode ,Electron transfer ,chemistry ,Chemical engineering ,General Materials Science ,Lithium ,Current density ,Carbon ,Stress concentration - Abstract
Two-dimensional layered materials commonly face hindered electron transfer and poor structure stability, thus limiting their application in high-rate and long-term sodium ion batteries. In the current study, we adopt finite element simulation to guide the rational design of nanostructures. By calculating the von Mises stress distribution of a series of carbon materials, we find that the hollow biconcave structure could effectively alleviate the stress concentration resulting from expansion. Accordingly, we propose a biconcave-alleviated strategy based on the Aspergillus niger-derived carbon (ANDC) to construct ANDC/MoS2 with a hollow biconcave structure. The ANDC/MoS2 is endowed with an excellent long-term cyclability as an anode of sodium ion batteries, delivering a discharge capacity of 496 mAh g-1 after 1000 cycles at 1 A g-1. A capacity retention rate of 94.5% is achieved, an increase of almost seven times compared with the bare MoS2 nanosheets. Even at a high current density of 5 A g-1, a reversible discharge capacity around 400 mAh g-1 is maintained after 300 cycles. ANDC/MoS2 could also be used for efficient lithium storage. By using in situ TEM, we further reveal that the hollow biconcave structure of ANDC/MoS2 has enabled stable and fast sodiation/desodiation.
- Published
- 2021
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