1. A facile synthesis of novel ε-Fe2O3 grafted 2D h-BN nanostructures for enhanced visible active photocatalytic applications
- Author
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Thiripuranthagan Sivakumar, Ramasamy Jayavel, Durai Mathivanan, Durai Mani, Erusappan Elangovan, Kumaravel Sakthivel, Mukannan Arivanandhan, and Ho Chang
- Subjects
Nanostructure ,Chemistry ,Nanoparticle ,Heterojunction ,General Chemistry ,Crystal structure ,Catalysis ,symbols.namesake ,Chemical engineering ,X-ray photoelectron spectroscopy ,Materials Chemistry ,Photocatalysis ,symbols ,High-resolution transmission electron microscopy ,Raman spectroscopy - Abstract
Novel nanostructures of h-BN and e-Fe2O3 grafted h-BN (h-BN/e-Fe2O3) have been synthesized by solvothermal method. The prepared h-BN/e-Fe2O3 nanostructures are highly reproducible. XRD analysis confirmed the phase and crystal structure of synthesized h-BN and h-BN/e-Fe2O3 nanostructures. The sheet like morphology of the nanostructured h-BN and h-BN/e-Fe2O3 are confirmed by SEM, TEM and HRTEM analyses. Moreover, the uniform distributions of e-Fe2O3 on the surface of h-BN nanosheets are confirmed by SEM and TEM images. FT-IR and Raman studies are used to identify the functional groups and structure of h-BN and h-BN/e-Fe2O3 nanostructures. The optical absorption spectra show a clear red shift in the h-BN/e-Fe2O3 nanostructure compared to pure h-BN nanosheets which shows the electronic band structure modification in BN caused by grafting of e-Fe2O3 nanoparticles onto the surface of h-BN. The chemical composition of prepared h-BN/e-Fe2O3 heterostructure is analyzed by XPS. The photo oxidative performance of pure h-BN and h-BN/e-Fe2O3 nanostructure has been studied for oxidative decomposition of formic acid under visible light irradiation. The h-BN/e-Fe2O3 nanostructure showed relatively high photo oxidative performance compared to pure h-BN.
- Published
- 2020
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