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1. Reductive desulfurization using tributyltin hydride

Author

John M. McIntosh and Calvin K. Schram

Subjects
Inert, chemistry.chemical_compound, Chemistry, Organic Chemistry, Inorganic chemistry, Organic chemistry, Tributyltin hydride, General Chemistry, Catalysis, Dowd–Beckwith ring-expansion reaction, Flue-gas desulfurization
Abstract

Reaction of tributyltin hydride with a variety of organic sulfides gives results which depend on the structure of the starting material. Acyclic sulfides undergo desulfurization leading to hydrocarbons in varying yields. However, 2,5-dihydrothiophenes give dienes and 3,6-dihydro-2H-thiopyrans are inert.

Published
1977
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