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Activation of metal oxides by light is a robust yet facile approach to manipulating their surface chemistry for favorable reactions with target molecules in heterogeneous catalysis and gas sensors. However, a limited understanding of interface chemistry and the involved mechanism impedes the development of a rational design of oxide interfaces for light‐activated gas sensing. Herein, the TiOx‐assisted photosensitization of In2O3 toward NO2 sensing is investigated as a case study to elucidate the detailed mechanism of light‐activated surface chemistry at the metal/gas interface. The resultant heterogeneous oxides exhibit outstanding NO2 sensing performance under light irradiation thanks to abundant photoexcited electrons and holes that serve as adsorption and desorption sites, respectively, to accelerate both surface reactions. Furthermore, the facile transfer of electrons and holes across the TiOx‐In2O3 interface contributes to improving the reversibility of sensing kinetics. Through this study, the mechanistic understanding is established of how the surface chemistry of metal oxide surfaces can be tuned by light activation providing an effective route to the design fabrication of high‐performance gas sensors. [ABSTRACT FROM AUTHOR]

Gas Sensors In article number 2214008, Il‐Doo Kim and co‐workers investigated photosensitization of the TiO2‐In2O3 sensing layer to enhance the NO2 detection capabilities of oxides. The heterogeneous interface engineered between two dissimilar oxides improved the accumulation of photogenerated charge carriers, which accelerated the adsorption and desorption of NO2 molecules. The study elaborates on the light‐mediated modulation of the oxide surface chemistry and establishes a rational design of cost‐effective light‐activated gas sensors. [ABSTRACT FROM AUTHOR]

Gas sensors, heterojunctions, indium oxides, interfacial engineering, photocatalysts, semiconducting oxides Keywords: gas sensors; heterojunctions; indium oxides; interfacial engineering; photocatalysts; semiconducting oxides EN gas sensors heterojunctions indium oxides interfacial engineering photocatalysts semiconducting oxides 1 1 1 04/27/23 20230425 NES 230425 B Gas Sensors b In article number 2214008, Il-Doo Kim and co-workers investigated photosensitization of the TiO SB 2 sb -In SB 2 sb O SB 3 sb sensing layer to enhance the NO SB 2 sb detection capabilities of oxides. Imparting Metal Oxides with High Sensitivity Toward Light-Activated NO2 Detection Via Tailored Interfacial Chemistry (Adv. Funct. [Extracted from the article]