1. In-situ construction of Au NPs decorated hierarchical In2O3/SnIn4S8 microcubes for enhanced trace NO2 sensing performance at room-temperature.
- Author
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Hou, Yuchen, Sun, Yongjiao, Dong, Yimeng, Wang, Bingliang, Lu, Zhiyuan, Wei, Zihan, Tong, Zhaomin, Zhang, Wendong, Suematsu, Koichi, and Hu, Jie
- Subjects
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GAS detectors , *NITROGEN dioxide , *DETECTION limit , *HETEROSTRUCTURES , *TEMPERATURE sensors - Abstract
A series of Au NPs decorated hierarchical In 2 O 3 /SnIn 4 S 8 microcubes were prepared by in-situ growing SnIn 4 S 8 nanosheets on the surface of In 2 O 3 microcubes and followed by reducing Au NPs on the surface of the hierarchical composite. The gas sensing performance of the sensors based on the as-prepared materials were systematically assessed. And the results showed that coverage of SnIn 4 S 8 and introduction of appropriate amount of Au NPs improved the gas sensing response of In 2 O 3 toward NO 2 at room temperature (RT). In particular, the sensor fabricated with 3 wt% Au NPs decorated In 2 O 3 /SnIn 4 S 8 exhibited excellent selectivity (S NO2 /S other > 12.6), high response (155.65–7 ppm NO 2), low theoretical limit of detection (LOD, 21.43 ppb), fast response/recovery time (132/191 s), good anti-interference performance, as well as repeatability and stability. The outstanding sensing performance at RT might be associated with a synergistic effect of heterostructures and the spillover effect of Au NPs, which could enlarge the electron depletion layer and promote the adsorption and dissociation of oxygen and nitrogen dioxide molecules. • Hierarchical In 2 O 3 /SnIn 4 S 8 microcubes were prepared for NO 2 sensing. • The In 2 O 3 /SnIn 4 S 8 -based gas sensor exhibited high response to trace NO 2 at RT. • Au NPs decoration further improve the sensing performance of In 2 O 3 /SnIn 4 S 8. • The excellent sensing properties of Au decorated In 2 O 3 /SnIn 4 S 8 stems from the synergistic effect. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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