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AlGaN/AlN/GaN and InAlN/AlN/GaN structures with 2D electron gas have been grown on sapphire substrates by metal-organic vapor-phase epitaxy. The suppression of the parasitic conductivity of buffer GaN layers was provided either by intentionally raising the density of edge dislocations or by doping with iron (GaN:Fe). It was shown that using GaN buffer layers with a better crystal perfection and more planar surface results in the electron mobility in the 2D channel for carriers becoming 1.2-1.5 times higher. [ABSTRACT FROM AUTHOR]

We have studied the pyrolysis of trimethylaluminum (TMA) in a nitrogen-containing atmosphere of a vapor phase epitaxy reactor. It is established that, in the presence of gallium nitride coatings in the reactor, the main product of TMA pyrolysis in a nitrogen-hydrogen atmosphere is aluminum nitride. Using this process (without introducing ammonia), we obtained perfect epitaxial aluminum nitride layers. [ABSTRACT FROM AUTHOR]

GaN-based structures with InGaN quantum dots in the active region emitting in the near-ultraviolet region are studied. In this study, two types of structures, namely, with InGaN quantum dots in a GaN or AlGaN matrix, are compared. Photoluminescence spectra are obtained for both types of structures in a temperature range of 80–300 K and at various pumping densities, and electroluminescence spectra are obtained for light-emitting (LED) structures with various types of active region. It is shown that the structures with quantum dots in the AlGaN matrix are more stable thermally due to the larger localization energy compared with quantum dots in the GaN matrix. Due to this, the LED structures with quantum dots in an AlGaN matrix are more effective. [ABSTRACT FROM AUTHOR]

InGaN quantum dot (QD) formation in a wide pressure range MOCVD reactor was studied. The existence of QDs and their lateral size (2–5 nm) were demonstrated using transmission electron microscopy and high spatial resolution (~ 100 nm) near-field magneto-photoluminescence spectroscopy. We found that an increase of the reactor pressure from 400 to 1000 mbar leads to an order of magnitude increase in light emission efficiency of the InGaN/GaN QDs accompanied by ~ 100 meV redshift of the emission wavelength. We explored stimulated phase separation (SPS) to control carrier localization and emission wavelength. The SPS was achieved by adding In in the matrix material. This leads to formation of extremely deep InGaN/InGaN QDs having energy localization up to ~ 0.8 eV, which was revealed from selectively excited far-field photoluminescence (PL) spectra. Without SPS the QD activation energy is found to be below 0.2 eV. A nonequilibrium carrier population strongly suppresses the temperature-induced shift of the PL emission in deep InGaN QDs. [ABSTRACT FROM AUTHOR]

GaN-based structures with InGaN quantum dots in the active region, which emit in the blue and green spectral ranges, are studied. The structures grown by both the conventional method and with the use of special procedures of the growth of the active region were compared. The use of these special growth modes stimulates the activated phase decomposition, which leads to the formation of quantum dots with substantially larger localization depth of electrons. It is shown that the formation of such deep quantum dots, like the formation of larger inhomogeneities of the active region, substantially suppresses the lateral carrier transport. This effect improves the characteristics of light-emitting diode structures at a low injection level and increases the temperature stability of quantum efficiency. [ABSTRACT FROM AUTHOR]

Structures with InGaN/GaN quantum dots have been studied using photocurrent spectroscopy. The dynamic range of measurements is found to amount to four orders of magnitude under preservation of the signal-to-noise ratio at a level higher than ten. Within the experimental accuracy, the shape of the spectrum is independent of an applied reverse external bias, whereas the spectrum itself shifts to shorter wavelengths, which is attributed to the Franz–Keldysh effect. Variation of the temperature brings about a change in the spectrum shape. This effect is found to be different for structures grown under different conditions. This behavior can be attributed to homogeneous broadening of the electronic states, the statistics of charge carriers at the levels of quantum dots, and the effect of temperature on the position of these levels. © 2005 Pleiades Publishing, Inc. [ABSTRACT FROM AUTHOR]

The influence of different growth conditions on the In distribution in ultrathin InGaN insertions in a GaN matrix is investigated by high-resolution transmission electron microscopy and an appropriate image evaluation technique. It is demonstrated that the indium distribution represents dense arrays of In-rich nanodomains inserted in a layer with a lower indium concentration. The sizes of the In-rich regions are about 4-5 nm at a growth temperature of 720 °C. Increasing the growth temperature leads to a strong decrease in the of nanoisland density and, also, a moderate decrease in their lateral size. Increasing the trimethylindium/trimethylgallium ratio strongly increases the density of the islands, but the lateral size remains weakly effected. The observations are in agreement with a thermodynamic model of island formation including entropy effects. [ABSTRACT FROM AUTHOR]

Conditions are investigated for the injection of arsenic into gallium nitride layers grown by metalorganic vapor-phase epitaxy. It is shown that the deposition of GaAs on a GaN surface relieves stresses in the GaN layer. The high-temperature overgrowth of a thin GaAs layer by a GaN layer causes As atoms to diffuse into the GaN, produces a thick, homogeneously doped GaN:As region, and creates a bright band in the photoluminescence spectrum with a maximum at ∼2.5 eV. [ABSTRACT FROM AUTHOR]