1. Valence and Na content dependences of superconductivity in NaxCoO2.yH2O
- Author
-
Sakurai, H., Tsujii, N., Suzuki, O., Kitazawa, H., Kido, G., Takada, K., Sasaki, T., and Takayama-Muromachi, E.
- Subjects
Superconductivity (cond-mat.supr-con) ,Condensed Matter - Strongly Correlated Electrons ,Strongly Correlated Electrons (cond-mat.str-el) ,Condensed Matter - Superconductivity ,FOS: Physical sciences ,Condensed Matter::Strongly Correlated Electrons - Abstract
Various samples of sodium cobalt oxyhydrate with relatively large amounts of Na$^{+}$ ions were synthesized by a modified soft-chemical process in which a NaOH aqueous solution was added in the final step of the procedure. From these samples, a superconducting phase diagram was determined for a section of a cobalt valence of $\sim$+3.48, which was compared with a previously obtained one of $\sim$+3.40. The superconductivity was significantly affected by the isovalent exchanger of Na$^{+}$ and H$_{3}$O$^{+}$, rather than by variation of Co valence, suggesting the presence of multiple kinds of Fermi surface. Furthermore, the high-field magnetic susceptibility measurements for one sample up to 30 T indicated an upper critical field much higher than the Pauli limit supporting the validity of the spin-triplet pairing mechanism., 4 figures and 1 table
- Published
- 2005