1. Vibrationally Resolved Inner-Shell Photoexcitation of the Molecular Anion C2
- Author
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S. Schippers, P.‐M. Hillenbrand, A. Perry‐Sassmannshausen, T. Buhr, S. Fuchs, S. Reinwardt, F. Trinter, A. Müller, and M. Martins
- Subjects
Atomic Physics (physics.atom-ph) ,FOS: Physical sciences ,Physical and Theoretical Chemistry ,Atomic and Molecular Physics, and Optics ,Physics - Atomic Physics - Abstract
Carbon $1s$ core-hole excitation of the molecular anion C$_2^-$ has been experimentally studied at high resolution by employing the photon-ion merged-beams technique at a synchrotron light source. The experimental cross section for photo--double-detachment shows a pronounced vibrational structure associated with $1\sigma_u\to3\sigma_g$ and $1\sigma_g \to 1\pi_u$ core excitations of the C$_2^-$ ground level and first excited level, respectively. A detailed Franck-Condon analysis reveals a strong contraction of the C$_2^-$ molecular anion by 0.2~\AA\ upon this core photoexcitation. The associated change of the molecule's moment of inertia leads to a noticeable rotational broadening of the observed vibrational spectral features. This broadening is accounted for in the present analysis which provides the spectroscopic parameters of the C$_2^-$ $1\sigma_u^{-1}\,3\sigma_g^2\;{^2}\Sigma_u^+$ and $1\sigma_g^{-1}\,3\sigma_g^2\;{^2}\Sigma_g^+$ core-excited levels., Comment: 8 pages, 5 figures, 1 table, accepted for publication in ChemPhysChem
- Published
- 2023