12 results on '"Yang, Charles Q."'
Search Results
2. NEW DEVELOPMENT IN NONFORMALDEHYDE DURABLE PRESS FINISHING OF COTTON FABRICS.
- Author
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Yang, Charles Q.
- Subjects
COTTON textiles ,COTTON finishing ,FINISHES & finishing ,FORMALDEHYDE ,CARBOCYCLIC acids ,CATALYSTS ,CROSSLINKING (Polymerization) ,MALEIC acid ,CREASING of textiles - Abstract
The article presents a study on nonformaldehyde durable press finishing of cotton fabrics. It states that the toxicity of formaldehyde have prompted researchers to find nonformaldehyde alternatives, and butanetetracarbocylclic acid (BTCA) has proved the most promising durable press agent for cotton when sodium hypophosphite is used as a catalyst. It discusses the performance of BTCA which has reportedly demonstrated various advantages as a press finishing agent for cotton. It concludes that the industrial grade BTCA and the reagent grade BTCA are similar in crosslinking cotton cellulose and in adding wrinkle resistance to cotton fabrics. It adds that polymaleic acid also showed efficiency as a durable press finishing agent for cotton and causes no adverse effect on fabric shade.
- Published
- 2002
3. A DURABLE LOW FORMALDEHYDE FLAME RETARDANT FINISH FOR COTTON FABRICS.
- Author
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Stowell, Jeffrey K. and Yang, Charles Q.
- Subjects
FIREPROOFING agents ,RESEARCH & development projects ,FINISHES & finishing ,SURFACE active agents ,SILICON ,RESIN custom compounds ,MAGNESIUM chloride ,KNIT goods ,TEXTURED woven textiles ,FORMALDEHYDE - Abstract
The article presents the findings of the research and development (R&D) project at the Akzo Nobel Coatings Inc. which investigates flame retardant (FR) finishing chemistries and their durability. It uses several chemicals such as a surfactant, silicon softener, DMDHEU resins, and an activated magnesium chloride solution, woven and knit fabrics. It reports that the finish is durable and performs well in burn tests with the low formaldehyde characteristics of FR/DMDHEU application chemistry. It concludes that the finishes are durable through multiple laundering cycles and depends on the type of binding resin used.
- Published
- 2002
4. Nonformaldehyde durable press finishing of cotton fabrics using the combination of maleic acid and sodium hypophosphite
- Author
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Peng, Huitao, Yang, Charles Q., and Wang, Shanyuan
- Subjects
- *
COTTON textiles , *FABRIC finishing , *FORMALDEHYDE , *HYPOPHOSPHITES , *MALEIC acid , *CROSSLINKING (Polymerization) , *ESTERIFICATION - Abstract
Abstract: Polycarboxylic acids have been used as nonformaldehyde crosslinking agents for cotton with sodium hypophosphite (NaH2PO2) as the catalyst to replace the formaldehyde-based dimethyloldihydroxyethleneurea (DMDHEU). Maleic acid (MA), an α, β-unsaturated bifunctional carboxylic acid, can esterify cotton but is not able to form crosslinking between two cellulose molecules by itself. In this research, we discovered that the wrinkle resistance of the cotton fabric treated with MA and NaH2PO2 was significantly increased and phosphorus was bound to cotton when the treated fabric was exposed to temperatures higher than that required for esterification of cotton by MA. Elevation of the fabric wrinkle resistance and increase in quantity of the phosphorus bound to cotton had similar dependency on curing temperature, on MA concentration, and on NaH2PO2 concentration. All the data support the hypothesis that H–P–(residual of NaH2PO2) added to >Cf the MA already bound to cotton by esterification, thus forming a new crosslink between two cotton cellulose molecules. The cotton fabrics treated by MA/NaH2PO2 showed fabric wrinkle resistance similar to that treated with DMDHEU, but the breaking strength and tearing strength of the MA-treated cotton fabrics were significantly improved. [Copyright &y& Elsevier]
- Published
- 2012
- Full Text
- View/download PDF
5. NONFORMALDEHYDE WRINKLE-FREE GARMENT FINISHING OF COTTON SLACKS.
- Author
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Weishu Wei, Yanqiu Jiang, and Yang, Charles Q.
- Subjects
TEXTILE finishing ,TEXTILE finishing agents ,COTTON textiles ,FORMALDEHYDE ,HIGH performance textiles - Abstract
The article discusses the development of nonformaldehyde durable press finishing system that provides cotton fabrics with superior durable press performance, good laundering durability and high fabric strength retention. Formaldehyde-based reagents used by the textile and garment industries include dimethyloldihydroxylethyleneurea (DMDHEU) and etherified DMDHEU. The experimental materials and methods are discussed, including garment treatment and fabric performance evaluation. The study looks at the effect of finish bath pH, total finish concentration and different catalyst systems on the finished garments performance.
- Published
- 1997
6. POLYMERS OF MALEIC ACID AS NONFORMALDEHYDE WRINKLE-FREE FINISHING AGENTS.
- Author
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Yang, Charles Q. and Chang, Kelvin Y.
- Subjects
COTTON textiles ,CLOTHING & dress ,FINISHES & finishing ,ABRASION resistance ,STRENGTH of materials ,FORMALDEHYDE - Abstract
The increasing demand in the market place for easy care cotton apparels has made it urgent to find formaldehyde-free durable press finishes. In addition, the use of new finishing technology, such as garment finishing, requires better fabric strength retention and abrasion resistance than what is provided by the durable press finishing agents available. Extensive efforts have been made to use 1,2,3,4-butanetetracarboxylic acid (BTCA) as a nonformaldehyde durable press finish to replace the traditional formaldehyde-based dimethyloldihydroxylethyleneurea (DMDHEU). However, the exceedingly high cost of BTCA has prevented its applications on a commercial scale. In this research, we investigated the ester crosslinking of cotton fabrics by two polymers of maleic acid, i.e., a homopolymer (PMA) and a terpolymer of maleic acid, acrylic acid and vinyl alcohol (TPMA). When the cotton fabric is treated with a TPMA-based polycarboxylic acid blend, the finished cotton fabric showed significant improvement in durable press performance, breaking strength retention, tearing strength retention, and flex abrasion resistance compared with that treated with DMDHEU. This new finish system also demonstrated satisfactory laundering durability. This competitively priced nonformaidehyde finish system provides the textile industry with an alternative to meet the increasing demands in the market place for safe and high quality wrinkle-free cotton fabrics and garments. [ABSTRACT FROM AUTHOR]
- Published
- 1996
7. The Effect of pH on the Nonformaldehyde Durable Press Finishing of Cotton Fabrics Studied by FTIR Spectroscopy.
- Author
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Yang, Charles Q.
- Subjects
PH effect ,TEXTILE finishing ,FORMALDEHYDE ,COTTON ,FOURIER transform infrared spectroscopy ,PHOSPHORIC acid - Abstract
When the three sodium salts of phosphoric acid were used as the catalysts for the ester cross-linking of cotton cellulose, they showed different effectiveness under the same curing conditions. This was due to the different pH values of the finish baths. In this research, the effect of pH of finish baths on the esterification of cotton cellulose by 1,2,3,4-butanetetracarboxylic acid (BTCA) was investigated using Fourier transform infrared spectroscopy (FT-IR). When a cotton fabric was finished with BTCA without the presence of a catalyst, both the amount of the ester linkages formed in the cotton fabric and the effectiveness of the bonded BTCA molecules first increased, then decreased as the pH of the finish bath increased from 1.5 to 5.5. An optimum pH range for esterification was observed. A similar phenomenon was also observed when a phosphate was used as a catalyst. It is necessary to choose the optimum pH range of a finish bath in order to achieve the most effective esterification of cotton cellulose" by a polycarboxylic acid. The FT-IR data indicated that the esterification of cotton cellulose by polycarboxylic acids is not an acid-catalyzed reaction as reported by some researchers. [ABSTRACT FROM AUTHOR]
- Published
- 1992
8. The bonding of a hydroxy-functional organophosphorus oligomer to nylon fabric using the formaldehyde derivatives of urea and melamine as the bonding agents
- Author
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Yang, Hui, Yang, Charles Q., and He, Qingliang
- Subjects
- *
ORGANOPHOSPHORUS compounds , *CHEMICAL bonds , *OLIGOMERS , *NYLON , *FORMALDEHYDE , *ADHESIVES , *UREA , *MELAMINE , *FIREPROOFING agents - Abstract
Abstract: In this research, we studied the mechanism of bonding a hydroxy-functional organophosphorus oligomer (HFPO) to nylon 6.6 fabric using the formaldehyde derivatives of urea and melamine, including dimethyloldihydroxyethyleneurea (DMDHEU) and trimethylolmelamine (TMM), as the bonding agents. The nylon fabric treated with HFPO/DMDHEU or HFPO/TMM retained significant amount of phosphorus after multiple launderings. The laundering durability of the HFPO applied to nylon was probably attributed to the formation of a crosslinked polymeric network on the nylon fiber. The nylon fabric treated with HFPO/DMDHEU showed higher percent phosphorus retention than that treated with HFPO/TMM. The percent phosphorus retention of the treated nylon increased as the DMDHEU or TMM concentration was increased, and the nylon fabric''s stiffness follows the same trend. The micro-scale combustion calorimetry and thermal analysis data indicate that the HFPO bound to nylon reduced peak heat release rate and heat release capacity of the nylon fabric, decreased decomposition temperature and promoted the char formation of the treated fabric. The nylon/cotton blend military fabric treated with HFPO/DMDHEO or HFPO/TMM demonstrated flame retardant performance after 10 laundering cycles. [Copyright &y& Elsevier]
- Published
- 2009
- Full Text
- View/download PDF
9. Formaldehyde-free flame retardant finishing of silk using a hydroxyl-functional organophosphorus oligomer
- Author
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Guan, Jinping, Yang, Charles Q., and Chen, Guoqiang
- Subjects
- *
TEXTILE finishing , *SILK , *FIREPROOFING agents , *ORGANOPHOSPHORUS compounds , *OLIGOMERS , *CARBOXYLIC acids , *HYDROXYL group , *FORMALDEHYDE - Abstract
Abstract: Flame retardancy is a desirable property for silk textiles, and it becomes necessity when silk textiles are for interior decorative use in building with public access. However, the flame retardant finishing technology available for silk has significant limitations. In this research, we studied the use of the combination of a hydroxyl-functional organophosphorus oligomer (HFPO) and 1,2,3,4-butanetetracarboxylic acid (BTCA) as a formaldehyde-free flame retardant finishing system for silk. When BTCA is applied to silk, most of BTCA reacts with the hydroxyl group on silk by single ester linkage. In the presence of HFPO, BTCA is able to bond HFPO onto silk by either a BTCA “bridge” between silk and HFPO or a BTCA–HFPO–BTCA cross-linkage between two silk protein molecules. We evaluated the flammability and physical properties of the silk fabric treated with HFPO and BTCA. The treated silk fabric demonstrated a high level of flame retardancy with modest loss in fabric tensile strength. The treated silk passed the vertical flammability test after 15 hand wash (HW) cycles. Increasing the HFPO concentration from 20% to 30% does not show significant improvement in the flame retardant performance of the treated silk. The thermal analysis data demonstrated that HFPO reduces silk''s initial thermal decomposition temperature and promotes char formation. [Copyright &y& Elsevier]
- Published
- 2009
- Full Text
- View/download PDF
10. Statistical analysis of the performance of the flame retardant finishing system consisting of a hydroxy-functional organophosphorus oligomer and the mixture of DMDHEU and melamine–formaldehyde resin
- Author
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Wu, Weidong and Yang, Charles Q.
- Subjects
- *
FIREPROOFING agents , *ORGANOPHOSPHORUS compounds , *OLIGOMERS , *FORMALDEHYDE , *PHOSPHORUS , *NITROGEN - Abstract
In our previous research, we developed flame retarding systems for cotton based on a hydroxy-functional organophosphorus oligomer (FR) and a binder, such as 1,2,3,4-butanetetracarboxylic acid (BTCA), dimethyloldihydroxyethyleneurea (DMDHEU) and melamine–formaldehyde (M–F), which are able to form covalent binding between FR and cotton. In this research, we used a factorial experimental design method to study the performance of the flame retarding system based on FR and the mixture of DMDHEU and M–F. We found that an increase in the DMDHEU/(DMDHEU + M–F) ratio in the mixture increases the amount of FR bound to cotton, increases the laundering durability of FR on cotton, and reduces the fabric tensile strength retention. DMDHEU and M–F also function as nitrogen providers and enhance the flame retarding performance of the treated fabric due to phosphorus–nitrogen synergism. M–F is a more efficient nitrogen provider than DMDHEU. The effect of reduced phosphorus–nitrogen synergism as a result of increasing the relative amount of DMDHEU in the mixture (DMDHEU + M–F) outweighs that of the improved bonding of FR to cotton. An increase in FR concentration in a formula increases the amount of FR bound to cotton, whereas it reduces the percent retention of FR on the fabric and also reduces the fabric strength loss. Desirable performance of treated cotton fabrics can be achieved by adjusting the concentrations of FR and the ratio of the two binders in a formula. [Copyright &y& Elsevier]
- Published
- 2004
- Full Text
- View/download PDF
11. Nonformaldehyde Wrinkle-Free Garment Finishing of Cotton Slacks.
- Author
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Weishu Wei, Yang, Charles Q., and Yanqiu Jiang
- Subjects
TEXTILE finishing ,COTTON textiles ,PANTS ,CELLULOSE ,FORMALDEHYDE ,COTTON - Abstract
The increasing demand for easy care cotton apparel in the marketplace has made it urgent to develop competitively priced formaldehyde-free durable press finishes to replace the traditional N-methylol reagents. A cost-effective nonformaldehyde durable press finishing system was developed based on citric acid and a terpolymer of maleic acid. This system was applied to garment finishing on both laboratory and industrial production scales and compared with the traditional DMDHEU systems as well as one commercial nonformaldehyde system. The durable press rating, crease retention rating, wrinkle recovery angle, mechanical strength, and abrasion resistance of the garments finished with the new system are comparable to those treated with the conventional DMDHEU systems. The garments finished with the new system maintained satisfactory fabric smoothness and crease retention after 30 home laundering washing/ drying cycles. [ABSTRACT FROM AUTHOR]
- Published
- 1999
12. Crosslinking: A Route to Improve Cotton Performance.
- Author
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Yang, Charles Q.
- Subjects
CROSSLINKING (Polymerization) ,COTTON ,COTTON fibers ,HYDROXYL group ,CARBOXYLIC acids ,FORMALDEHYDE - Abstract
The article discusses a method for improving cotton performance which involves crosslinking cotton cellulose using chemical agents with multiple functional groups reactive to cellulosic hydroxyl groups. Multi-functional carboxylic acids are cited as the most promising nonformaldehyde crosslinking agents when sodium hypophosphite was utilized as the catalyst. Information is also presented on the mechanism of cotton ester crosslinking and its catalysis.
- Published
- 2013
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