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Time-of-flight secondary ion mass spectrometry ( TOF- SIMS) is a well-established surface technique that provides both elemental and molecular information from several monolayers of a sample surface while also allowing depth profiling or image mapping to be performed. Static TOF- SIMS with improved performances has expanded the application of TOF- SIMS to the study of a variety of organic, polymeric, biological, archaeological, and forensic materials. In forensic investigation, the use of a minimal sample for the analysis is preferable. Although the TOF- SIMS technique is destructive, the probing beams have microsized diameters so that only small portion of the questioned sample is necessary for the analysis, leaving the rest available for other analyses. In this study, TOF- SIMS and attenuated total reflectance Fourier transform infrared ( ATR- FTIR) were applied to the analysis of several different pen inks, red sealing inks, and printed patterns on paper. The overlapping areas of ballpoint pen writing, red seal stamping, and laser printing in a document were investigated to identify the sequence of recording. The sequence relations for various cases were determined from the TOF- SIMS mapping image and the depth profile. TOF- SIMS images were also used to investigate numbers or characters altered with two different red pens. TOF- SIMS was successfully used to determine the sequence of intersecting lines and the forged numbers on the paper. [ABSTRACT FROM AUTHOR]

Document authentication is one of the most important fields in forensic science and includes analysis of handwriting, seal imprint, and printed materials. In this study, we investigated intersection lines by pen inks, red stamping ink, and laser toner using time-of-flight secondary ion mass spectrometry (TOF-SIMS) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR). TOF-SIMS is very useful when the quantity of the sample is insufficient or the sample is very precious. Each ink showed specific ion peaks from inorganic species such as Al, Si, Ti, Cr, Mn, Fe, Zn, and Pb and from organic components at a mass range of m/z 200-450 in TOF-SIMS spectra. ATR FTIR results also revealed different spectra for ink and toner samples. The overlapped area of ballpoint pen writing, red sealing stamping, and laser printing in a document was investigated in order to identify the sequence of recording. The sequence relations for various cases were studied from TOF-SIMS mapping image and ATR FTIR spectra. This study indicated that TOF-SIMS and ATR FTIR are useful techniques to determine the sequence of writing and printing under question. Copyright © 2014 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

Seals are traditionally used in the Far East Asia to stamp an impression on a document in place of a signature. In this study, an accuser claimed that a personal contract regarding mining development rights acquired by a defendant was devolved to the accuser because the defendant stamped the devolvement contract in the presence of the accuser and a witness. The accuser further stated that the seal ink stamped on the devolvement contract was the same as that stamped on the development rights application document. To verify this, the seals used in two documents were analyzed using micro-attenuated total reflectance Fourier transform infrared spectroscopy and infrared spectra. The findings revealed that the seals originated from different manufacturers. Thus, the accuser's claim on the existence of a devolvement contract was proved to be false. [ABSTRACT FROM AUTHOR]

A guidebook detailing the process of forensic investigation was written in 1440 A.C.E. It outlines the fundamentals and details of each element of criminal investigation during the era of the Chosun dynasty in Korea. Because this old guidebook was written in terms of personal experience rather than on scientific basis, it includes many fallacies from the perspective of modern forensic science. However, the book describes methods to form a scientific basis for the experiments performed. We demonstrate the modern scientific basis for ancient methods to monitor trace amounts of blood and detect lethal arsenic poisoning from a postmortem examination as described in this old forensic guidebook. Traces of blood and arsenic poisoning were detected according to the respective color changes of brownish red, due to the reaction of ferric ions in blood with acetic ions of vinegar, and dark blue, due to the reaction of silver with arsenic sulfide. [ABSTRACT FROM AUTHOR]

Questioned documents examined in a forensic laboratory sometimes contain signatures written with ballpoint pen inks; these signatures were examined to assess the feasibility of micro-attenuated total reflectance ( ATR) Fourier transform infrared ( FTIR) spectroscopy as a forensic tool. Micro- ATR FTIR spectra for signatures written with 63 ballpoint pens available commercially in Korea were obtained and used to construct an FTIR spectral database. A library-searching program was utilized to identify the manufacturer, blend, and model of each black ballpoint pen ink based upon their FTIR peak intensities, positions, and patterns in the spectral database. This FTIR technique was also successfully used in determining the sequence of homogeneous line intersections from the crossing lines of two ballpoint pen signatures. We have demonstrated with a set of sample documents that micro- ATR FTIR is a viable nondestructive analytical method that can be used to identify the origin of the ballpoint pen ink used to mark signatures. [ABSTRACT FROM AUTHOR]