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The growing consumption of natural resources to meet the needs of road construction has become a significant challenge to environmental sustainability. Additionally, the increase in industrial by-products has raised global concerns due to their environmental impacts. The utilization of industrial by-products in asphalt mixtures offers an effective solution for promoting sustainable practices. The objective of this article is to conduct a bibliometric analysis and citation-based review to characterize and analyze the scientific literature on the use of steel slag aggregates, copper slag, phosphorus slag, bottom ash, fly ash, red mud, silica fume, and foundry sand in asphalt mixtures. Another aim is to identify research gaps and propose recommendations for future studies. The bibliometric analysis was conducted using VOSviewer software version 1.6.18, focusing on authors, co-authorship, bibliographic coupling, and countries. A total of 909 articles were selected for the bibliometric analysis. The findings indicate that more effort is needed to expand the application of industrial by-products in asphalt mixtures. Furthermore, these by-products should be utilized in different types of asphalt mixtures. The incorporation of industrial by-products into asphalt mixes also requires field validation and further laboratory investigations, particularly concerning aging and moisture resistance. In addition, the effects of chemical reactions involving industrial by-products on the long-term performance of asphalt layers should be evaluated. Finally, this article encourages engineers and researchers to intensify their efforts in utilizing industrial by-products for environmental sustainability. [ABSTRACT FROM AUTHOR]

Utilizing waste materials in road construction has become a compelling alternative owing to the availability of high-quality natural aggregates and the challenges associated with disposing of industrial waste. This study delves into the potential of class F fly ash from coal combustion, which is not self-cementing, requiring additional activators for stabilization. Activators such as lime, ground granulated blast furnace slag (GGBS), and bottom ash were incorporated in diverse proportions. The experimental analysis included tests like modified Proctor compaction, unconfined compressive strength (UCS), California bearing ratio (CBR), and repeated load triaxial tests. Results revealed that the introduction of 1–3% lime, 3–21% ground granulated blast furnace slag, and 10–30% bottom ash, combined with extended curing durations, augmented both compressive strength and California bearing ratio values. The resilient modulus of these mixtures showed an improvement of roughly 70% compared to traditional Wet Mix Macadam. Advanced microscopic studies using X-Ray diffraction (XRD), field emission scanning electron microscopy (FESEM) equipped with energy dispersive spectroscopy (EDS), and thermogravimetric analysis (TGA) identified the formation of calcium silicate hydrates and ettringite as contributing factors to the increased strength. The optimally formulated mixtures met the requirements outlined by the Indian Roads Congress, suggesting their suitability for inclusion in base, subbase courses of flexible pavements, and the dry lean concrete layer of rigid pavements. [ABSTRACT FROM AUTHOR]

Rare earth elements are an essential critical raw material in the development of modern technologies and are highly sensitive to both supply chain disruptions and market turbulence. The presented study examines the characteristics of fuel, fly ash, and bottom ash from lignite combustion in power plant units. Also, we attempted to determine the amount of amorphous glass in the ashes and whether and to what extent the glass from the ash samples is bound to REY. The suitability of the ash was assessed as an alternative source of REY. The fuel and ash samples were acquired from power plants in Poland. The tests determined the fuel quality parameters, including the chemical and phase composition, of amorphous glass using ICP-MS and XRD methods, respectively. The study showed that all ash samples dissolved in 4% HF were enriched in REY. The efficiency of REY enrichment varied, and its presence in the residue samples was found to be in similar proportions compared to the raw sample. All ash residue samples were enriched in critical elements. The obtained values of the Coutl prospective coefficient allowed for the classification of some of the analyzed ashes and their residues after dissolution in 4% HF as prospective REY raw materials. [ABSTRACT FROM AUTHOR]

The renewable energy industry is heavily reliant on rare earth elements, underscoring the need to develop resources and production. The objective of this work was to estimate coal ash resources and potential for extraction of rare earth elements using data for the US. Data on spatiotemporal variability in coal ash resources and disposition were compiled from various federal databases and rare earth elements levels in ash were compiled from the literature. Results show that ~ 52 gigatons (Gt) of coal were produced in the US (1950–2021). Power plants account for most of the coal use, particularly since 1980. Coal ash (5.3 Gt) represents a mean of 10% of coal by weight, ranging from 6% for subbituminous to 14% for lignite. About 70% of coal ash is potentially accessible for rare earth element extraction (1985–2021) and was disposed in landfills and ponds with the remaining coal ash used onsite or sold. Median values of total rare earth elements are much higher in ashes derived from the Appalachian Basin (median 431 mg/kg) than in the Illinois (282 mg/kg) or Powder River basins (264 mg/kg). Considering the market value of rare earth oxides, potentially accessible ash volumes, and percent rare earth element extraction (30% Appalachian and Illinois Basins; 70% Powder River Basin) results in an estimated $8.4 billion value. This study provides fundamental information on accessible coal ash resources in the US, linkages to coal sources, and preliminary estimates of rare earth element levels for future development within the US. [ABSTRACT FROM AUTHOR]

Industrial solid residual waste (ISRW) generated during and/or due to the making of energy, heat, and raw materials poses a major threat to a sustainable future due to its large production quantities and complex characteristics. Especially improper disposal of ISRW (e.g., coal ashes, municipal waste residue, and biomass ashes) not only threatens human health but can also cause environmental hazards such as water, soil, and air pollution, upsetting the global balance. Given the environmental impacts as well as increasingly stringent disposal regulations, lack of landfills, and economic constraints, more sustainable and naturally friendly management strategies are being adopted for ISRW. While numerous studies in the literature have considered various characteristics of ISRW, a complete appraisal of the entire practice, from making to disposal, is still lacking. This paper presents an overview of the making, features, and traditional and innovative managing tactics of ISRW within the context of a general legal framework. This paper provides a scientific review of the various production types, global production quantities, and characteristics of ISRW. Additionally, the orthodox management strategies of ISRWs are scrutinized from a sociological and ecological standpoint, and diverse techniques for more viable and secure management are elucidated. This review culminates in an examination of the global impact and advantages of ISRW management policies based on legislation and regulations. Consequently, this paper seeks to elucidate the extant practices and a few recent advancements pertaining to ISRWs. Additionally, it underscores the ecological, sociological, and economic issues engendered by ISRWs and proposes innovative applications and production technologies. [ABSTRACT FROM AUTHOR]

The aim of the research was to assess the potential of bottom ash from Polish coal-fired power plants as an alternative source of rare earth elements (REY). The potential of these ashes was compared with fly ash from the same coal combustion cycle. The phase and chemical composition, as well as REY, were determined using: X-ray diffraction and inductively coupled plasma mass spectrometry. The tested ashes were classified as inert-low pozzolanic and inert-medium pozzolanic, as well as sialic and ferrosialic, with enrichment in detrital material. The phase and chemical composition of bottom ash was similar to fly ash from the same fuel combustion cycle. The REY content in the ash was 199–286 ppm and was lower than the average for global deposits, and the threshold value was considered profitable for recovery from coal. Bottom ash's importance as a potential source of REY will increase by recovering these metals from separated amorphous glass and mullite and grains rich in Al, Mg, K, and P. The industrial value of bottom ash as an alternative source of REY was similar to fly ash from the same fuel combustion cycle. [ABSTRACT FROM AUTHOR]

Abstract The renewable energy industry is heavily reliant on rare earth elements, underscoring the need to develop resources and production. The objective of this work was to estimate coal ash resources and potential for extraction of rare earth elements using data for the US. Data on spatiotemporal variability in coal ash resources and disposition were compiled from various federal databases and rare earth elements levels in ash were compiled from the literature. Results show that ~ 52 gigatons (Gt) of coal were produced in the US (1950–2021). Power plants account for most of the coal use, particularly since 1980. Coal ash (5.3 Gt) represents a mean of 10% of coal by weight, ranging from 6% for subbituminous to 14% for lignite. About 70% of coal ash is potentially accessible for rare earth element extraction (1985–2021) and was disposed in landfills and ponds with the remaining coal ash used onsite or sold. Median values of total rare earth elements are much higher in ashes derived from the Appalachian Basin (median 431 mg/kg) than in the Illinois (282 mg/kg) or Powder River basins (264 mg/kg). Considering the market value of rare earth oxides, potentially accessible ash volumes, and percent rare earth element extraction (30% Appalachian and Illinois Basins; 70% Powder River Basin) results in an estimated $8.4 billion value. This study provides fundamental information on accessible coal ash resources in the US, linkages to coal sources, and preliminary estimates of rare earth element levels for future development within the US.

Peat soil is a problematic soil that has very high compressibility and water content. Peat soil also has a low soil carrying capacity so repair techniques are needed. In this research, a mixture of Fly Ash, Bottom Ash, and Fly Ash+Bottom Ash was used. The use offly ash and bottom ash as a mixture is because this material has fine grains, is grayish in color and is obtained from burning coal containing chemical elements including silica (SiO2), alumina (Al2O3), ferrous oxide (Fe2O3) and calcium oxide (CaO) and contains other elements. This research uses variations in fly ash and bottom ash levels, namely 0%, 10%, 15%, 20%, 25%. The location for taking peat soil samples was taken in Parit Village, North Indralaya District, Ogan Ilir Regency, South Sumatra Province. Laboratory testing includes soil properties testing and California Bearing Ratio (CBR) Unsoaked. Soil properties results (location 1) are: Water content (ω) 550.64%, Organic Content (OC) 49.54%, Ash Content (AC) 50 .46%, Fiber Content (FC) 42.03%, Specific Gravity (Gs) 1.754 gr/cm3, and pH Value 3. CBR Test Results for original peat soil were 4.73% (Location 1) and 4.55% (Location 2). The CBR value of Unsoaked Peat Soil + fly ash is 3.99%; 4.94%; 7.30%; 9.86%; 12.16%; 15.97%. Peat + bottom ash, namely 3.99%; 4.44%; 6.66%; 8.32%; 10.57%; 13.86%. Peat + fly ash + bottom ash, namely 3.99%; 5.43%; 7.84%; 10.03%; 12.95%; 18.72%. [ABSTRACT FROM AUTHOR]

The more economically viable and environmentally sustainable approach for treating the by-products of coal combustion from thermal power plants entails their collective disposal as opposed to individual disposal methods. This aligns with pertinent EU directives and domestic regulations, ensuring compliance with established standards while optimizing resource utilization and minimizing environmental impact. This study evaluated the resistance to wind erosion of the binding properties of a mixture (fly ash (FA), bottom ash (BA), and additives) using an indoor wind tunnel under simulated ambient conditions. Investigations of the mutual impact of ash, bottom ash, and additives (CaO and Ca(OH)2) with a certain percentage of water were carried out with eighteen samples. The samples consisted of the water at six addition rates 5, 8, 10, 15, 20, and 25% (w/w), and additive at three addition rates (1, 2, and 3% (w/w). Based on the obtained results, the optimal ratios of additives (3% (w/w)) and water (15% (w/w)) were determined. Prior to the wind tunnel experiments, and according to the different addition rates of additives and water, eight samples were prepared with different addition rates of ash. The mass concentrations of suspended particles (PM10) and total suspended particles (TSPs) in these samples were measured at three distinct wind velocities: 1 m/s, 3 m/s, and 5 m/s, respectively. The results indicate that the samples containing the optimal content of additives and water demonstrate a maximum increase in PM10 emission zero values of no more than 1.9 times. This finding can be considered satisfactory from the standpoint of environmental protection. [ABSTRACT FROM AUTHOR]

Incineration plants for electricity generation have offered a solution to the challenges of domestic solid waste treatment in many countries. However, their emissions, fly ash (FA) and bottom ash (BA), have had a detrimental impact on environmental quality. This study investigated the morphology, element composition, and concentration of metals in FA and BA from municipal solid waste incineration plants using scanning electronic microscopy/energy-dispersive X-ray and inductively coupled plasma mass spectrometry techniques. It also evaluated the distribution ratios of metal species across five fractions: exchangeable, carbonate-bound, oxide-bound, organic-bound, and sulfide-bound, and residual. The total metal content in both FA and BA was comparable, with calcium having the highest concentration (28,170–135,130 mg·kg−1 dry weight) and silver having the lowest (5.26–19.3 mg·kg−1 dry weight). However, the percentage proportion of metals differed between the extracted fractions. Except for cadmium in FA, ecological risk assessment indicated low direct bioavailability and potential risk of metals in both FA and BA. These findings contribute to the hazard assessment of FA and BA generated from waste incinerators and provide a scientific basis for developing treatment techniques for this type of waste.

The construction industry is a leading sector for coal ashes utilization, including in cement manufacturing and soil stabilization applications. In soil stabilization, coal ashes, alongside Ordinary Portland Cement (OPC), are the most commonly used materials. However, the environmental impact of coal ashes, particularly the leaching of heavy metals from stabilized soil when exposed to rainfall, remains underexplored. There is a notable gap in assessing the environmental impacts of this utilization, particularly when the stabilized soil interacts with rainfall in real-world scenarios. Therefore, this study aimed to contribute to filling this gap. Accordingly, in this study, peat soil was stabilized by using fly ash, bottom ash, and OPC. The characterization of soil mixture materials, including physicochemical and engineering properties, was established and studied first. Following the environmental impact, simulations were conducted using a column to study soil leachate under different conditions and seasons (dry and wet) in response to its interaction with rainfall. The leachate was analyzed using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) to measure the concentrations of heavy metals, including copper (Cu), aluminum (Al), manganese (Mn), iron (Fe), and zinc (Zn). Additionally, Ion Chromatography (IC) was employed to determine the concentrations of major anions, including fluoride (F⁻), chloride (Cl⁻), nitrate (NO₃⁻), phosphate (PO₄³⁻), and sulfate (SO₄²⁻). The findings revealed the complex interaction of the chemical stabilization processes and environmental factors with the leaching behavior of heavy metals and anions, highlighting the significant impact of stabilization on leaching patterns. To conclude, this study provides a valuable contribution to understanding the environmental and engineering implications of utilizing coal ashes in soil stabilization.

Chlorinated benzenes (CBzs) are a group of organic pollutants, which have been industrially or unintentionally produced through various chemical and thermal processes. Studies on full congener profiles of CBzs in waste and environmental samples are relatively limited and not updated. In the present study, concentrations of 12 CBzs were determined in fly ash (FA) and bottom ash (BA) samples collected from one municipal waste incinerator (MWI) and one industrial waste incinerator (IWI) in northern Vietnam. Levels of Σ12CBzs were higher in bottom ash (median 25.3; range 1.59–45.7 ng/g) than in fly ash (median 7.30; range 1.04–30.0 ng/g). The CBz profiles were dominated by di- and tri-chlorinated congeners with the major congeners as 1,2,4-TCB, 1,2,3-TCB, 1,2-DCB, and 1,3-DCB. However, CBz profiles varied greatly between sample types and incinerators, implying differences in input materials, formation pathways, and pollutant behaviors. Incomplete combustion is possibly responsible for high levels of CBzs in industrial bottom ash. The emission factors of Σ12CBzs ranged from 21 to 600 µg/ton for fly ash and from 190 to 4570 µg/ton for bottom ash, resulting in annual emissions of about 6 and 3 g/year for the IWI and MWI, respectively. Our results suggest additional investigations on industrial emission and environmental occurrence of all 12 CBzs rather than solely focusing on regulated congeners like hexachlorobenzene and pentachlorobenzene. [ABSTRACT FROM AUTHOR]

This study explores for the first time the potential use of carbonation as a method for managing cork ash, a byproduct of biomass waste incineration. Additionally, the cork ash was combined with fly ash from municipal solid waste incineration to leverage the carbonation reaction's ability to stabilize heavy metals. The findings suggest that subjecting biomass ash to carbonation can lead to the formation of mineral carbonates, effectively capturing CO2 and reducing its release into the atmosphere. The combination of various alkaline wastes and the stabilization of leachable heavy metals through carbonation reactions also opens opportunities for synergies between different industrial sectors. Finally, the study proposes a route for the obtained materials valorisation via ‘end of waste’: the reuse of the resulting materials as substitutes for natural resources, particularly in applications like building materials and polymer composites, can further enhance carbon dioxide savings.

Rare earth elements are an essential critical raw material in the development of modern technologies and are highly sensitive to both supply chain disruptions and market turbulence. The presented study examines the characteristics of fuel, fly ash, and bottom ash from lignite combustion in power plant units. Also, we attempted to determine the amount of amorphous glass in the ashes and whether and to what extent the glass from the ash samples is bound to REY. The suitability of the ash was assessed as an alternative source of REY. The fuel and ash samples were acquired from power plants in Poland. The tests determined the fuel quality parameters, including the chemical and phase composition, of amorphous glass using ICP-MS and XRD methods, respectively. The study showed that all ash samples dissolved in 4% HF were enriched in REY. The efficiency of REY enrichment varied, and its presence in the residue samples was found to be in similar proportions compared to the raw sample. All ash residue samples were enriched in critical elements. The obtained values of the Coutl prospective coefficient allowed for the classification of some of the analyzed ashes and their residues after dissolution in 4% HF as prospective REY raw materials.

Industrial solid residual waste (ISRW) generated during and/or due to the making of energy, heat, and raw materials poses a major threat to a sustainable future due to its large production quantities and complex characteristics. Especially improper disposal of ISRW (e.g., coal ashes, municipal waste residue, and biomass ashes) not only threatens human health but can also cause environmental hazards such as water, soil, and air pollution, upsetting the global balance. Given the environmental impacts as well as increasingly stringent disposal regulations, lack of landfills, and economic constraints, more sustainable and naturally friendly management strategies are being adopted for ISRW. While numerous studies in the literature have considered various characteristics of ISRW, a complete appraisal of the entire practice, from making to disposal, is still lacking. This paper presents an overview of the making, features, and traditional and innovative managing tactics of ISRW within the context of a general legal framework. This paper provides a scientific review of the various production types, global production quantities, and characteristics of ISRW. Additionally, the orthodox management strategies of ISRWs are scrutinized from a sociological and ecological standpoint, and diverse techniques for more viable and secure management are elucidated. This review culminates in an examination of the global impact and advantages of ISRW management policies based on legislation and regulations. Consequently, this paper seeks to elucidate the extant practices and a few recent advancements pertaining to ISRWs. Additionally, it underscores the ecological, sociological, and economic issues engendered by ISRWs and proposes innovative applications and production technologies.

To develop a practical alternative to classic cement materials, alkali-activated materials were manufactured from industrial wastes (fly and bottom ash). Microstructural behavior of these blends was investigated through X-ray diffraction, scanning electron microscope, thermal analysis, Fourier-transform infrared spectroscopy and surface response methodology. Natrolite, phillipsite, and calcium aluminum silicate hydrate and sodium carbonate newly formed after alkali activation. Empirical ternary diagrams as well as modeling equations were united to predict the physico-mechanical evolution of the prepared specimens. The used model described well the evolution of the studied properties against the processing factors; temperature, NaOH concentration and curing time. The weight of the effect of each parameter was estimated and factor to factor interaction was considered. NaOH concentrations and ageing temperature had a considerable positive effect on density and mechanical strength, respectively. Water absorption and electrical conductivity were influenced differently by the factors, the electrical conductivity increases as the NaOH concentrations increase, and time and temperature decrease. The response surfaces and their results were correlated with the microstructure of the hardened samples. Overall, alkali activated binders with good engineering properties could be synthesized in the considered conditions. The optimal alkali activation conditions were ∼12 M and the corresponding final properties were as follows: 50 MPa for the compressive strength and 20% for water absorption while density was recorded at a 1.75 g/cm3 value. [ABSTRACT FROM AUTHOR]

The amount of medical waste generated has increased enormously since the COVID-19 outbreak. An incineration process is the main method that is usually used to treat this waste, causing an increase in both medical waste bottom ash (MWBA) and medical waste fly ash (MWFA). In this work, the physical and chemical characteristics of MWFA and MWBA were reviewed. This ash contains high levels of polychlorinated dibenzo-p-dioxin (PCDD), dibenzofurans (PCDFs), and heavy metals. Furthermore, medical waste ash appears to have high leachability in the toxicity characteristics leaching procedure (TCLP) test and the European standard test (EN 12457). Owing to its toxicity, medical ash can be treated using various methods prior to disposal based on the covered review. These techniques include chemical, supercritical fluid, cement-based, melting, microwave, and mechanochemical techniques. The shortcomings of some of these treatment methods have been identified, such as the emission of high levels of chlorine from the melting technique, limited applications of the flotation method on the industrial scale, long-term stability of leachate treated by cement-based methods that have not been confirmed yet, and high energy consumption in the supercritical technique. This review also covers possible applications of medical waste ash in cement production, agriculture, and road construction. HIGHLIGHTS Medical waste ash contains high concentrations of dioxins.; Heavy metals in medical waste ash have a high leachability in the soil and groundwater.; Further investigations to solve multiple problems in treatment techniques of medical waste ash are required.; Medical waste ashes have been found to be beneficial in concrete production.;

The more economically viable and environmentally sustainable approach for treating the by-products of coal combustion from thermal power plants entails their collective disposal as opposed to individual disposal methods. This aligns with pertinent EU directives and domestic regulations, ensuring compliance with established standards while optimizing resource utilization and minimizing environmental impact. This study evaluated the resistance to wind erosion of the binding properties of a mixture (fly ash (FA), bottom ash (BA), and additives) using an indoor wind tunnel under simulated ambient conditions. Investigations of the mutual impact of ash, bottom ash, and additives (CaO and Ca(OH)2) with a certain percentage of water were carried out with eighteen samples. The samples consisted of the water at six addition rates 5, 8, 10, 15, 20, and 25% (w/w), and additive at three addition rates (1, 2, and 3% (w/w). Based on the obtained results, the optimal ratios of additives (3% (w/w)) and water (15% (w/w)) were determined. Prior to the wind tunnel experiments, and according to the different addition rates of additives and water, eight samples were prepared with different addition rates of ash. The mass concentrations of suspended particles (PM10) and total suspended particles (TSPs) in these samples were measured at three distinct wind velocities: 1 m/s, 3 m/s, and 5 m/s, respectively. The results indicate that the samples containing the optimal content of additives and water demonstrate a maximum increase in PM10 emission zero values of no more than 1.9 times. This finding can be considered satisfactory from the standpoint of environmental protection.

The amount of medical waste generated has increased enormously since the COVID-19 outbreak. An incineration process is the main method that is usually used to treat this waste, causing an increase in both medical waste bottom ash (MWBA) and medical waste fly ash (MWFA). In this work, the physical and chemical characteristics of MWFA and MWBA were reviewed. This ash contains high levels of polychlorinated dibenzo-p-dioxin (PCDD), dibenzofurans (PCDFs), and heavy metals. Furthermore, medical waste ash appears to have high leachability in the toxicity characteristics leaching procedure (TCLP) test and the European standard test (EN 12457). Owing to its toxicity, medical ash can be treated using various methods prior to disposal based on the covered review. These techniques include chemical, supercritical fluid, cement-based, melting, microwave, and mechanochemical techniques. The shortcomings of some of these treatment methods have been identified, such as the emission of high levels of chlorine from the melting technique, limited applications of the flotation method on the industrial scale, long-term stability of leachate treated by cement-based methods that have not been confirmed yet, and high energy consumption in the supercritical technique. This review also covers possible applications of medical waste ash in cement production, agriculture, and road construction. [ABSTRACT FROM AUTHOR]

Background: Through combustion, a coal-fired power plant produces by-products, such as fly ash and bottom ash, which contain significant concentrations of radionuclides that cause environmental contamination, leading to health problems. Materials and Methods: This study investigated the specific activity and radiological impacts of naturally occurring radioactive materials (NORMs) in the coal, fly ash, and bottom ash at a coal-fired power plant. Samples were collected from a coal-fired power plant in Malaysia. Results: Gamma spectrometry was used to determine the specific concentrations of NORMs, namely 40K, 232Th, 238U, in each sample. The radioactivity ranges for 238U, 232Th, and 40K in the soil were 22.7-150.7 Bq/kg, 20.7-153.6 Bq/kg, and 68.6-1594.4 Bq/kg, respectively. The coal, fly, and bottom ash samples contained 67.54-189.18 Bq/kg of 238U, 50.2-134.57 Bq/kg of 232Th, and 327.54-1114.40 Bq/kg of 40K. The radium equivalent activities (Raeq) in the samples were 164.55, 467.42, and 429.09 Bq/kg, respectively. Meanwhile, the absorbed dose rate (ADR) in the air ranged from 76.04 to 217.44 nGy/h. Internal and external hazards ranged from 0.44 to 1.26 and 0.63 to 1.77, respectively. The annual gonadal dose equivalent (AGDE) value fluctuated between 521.28 and 1,496.99 µSv. Conclusion: The excess lifetime cancer risk (ELCR) oscillated from 1.30×10-3 to 3.75×10-3 indoors and 0.32×10-3 to 0.95×10-3 outdoors. [ABSTRACT FROM AUTHOR]

The purpose of this research is to assess the yield and reaction rate potential of carbon dioxide (CO2) sequestration through mineralisation using readily available and inexpensive resources by exploiting waste materials. In this case, a blend of four different kinds of ashes and combustion by-products were used, namely, coal fly ash (CFA), flue gas desulphurization (FGD) residues, municipal solid waste incineration fly ashes (MSWI FA) and bottom ash (MSWI BA), produced at the same location. To highlight the impact of these materials on the carbonation process, various factors were analysed, including particle size distribution, immediately soluble contents, mineralogy, particles' detailed structure, and chemical composition. After preparing the samples, two carbonation processes were tested: natural carbonation and accelerated carbonation. To evaluate the impact of the water content on the reaction rate and yield of the mineral carbonation, various liquid-to-solid (L/S) ratios were used. The results demonstrate that the water content and pressure play a significant role in the CO2 sequestration during the accelerated carbonation, the higher the L/S, the greater the yields, which can reach up to 152 g CO2/kg with MSWI FA, while no substantial difference seems to emerge in the case of the natural carbonation. [ABSTRACT FROM AUTHOR]

High amounts of coal combustion products, such as fly ash and bottom ash, are generated every year; however, only 64% are used, which means that a significant part is landfilled despite containing valuable materials such as ferrospheres, which may be used as catalysts, substituting critical raw materials (e.g., platinoids). In commercial coals, pyrite contents are reduced as a pre-combustion S-emissions control measure, so low amounts of ferrospheres are expected in the respective ashes. However, given the large amounts of ash being generated from these coals, it may provide a reliable source of catalysts, with ferrospheres being easily recovered via magnetic separation. Several studies have been conducted regarding these morphotypes; however, there is a lack of investigation considering the ash derived from highly beneficiated coals and the variations with location and time. In this study, bottom ash, economizer grits, and fly ash samples from a Portuguese power plant burning Colombian commercial coal were fractionated using ferrite (Fe-MC fraction) and Nd (Nd-MC fraction) magnets, and a multi-technique approach was used to assess their properties (magnetic parameters, particle size distribution, mineralogy, particle morphology, microtexture, and chemical composition). The Fe-MC presented higher Fe concentrations (up to 44 wt.% Fe2O4) than the Nd-MC (up to 7 wt.% Fe2O4). Once it was a sequential process, Nd magnets essentially collected Fe-bearing aluminosilicate glass, and Fe-bearing minerals were residual when compared to the Fe-MC, where magnetite, magnesioferrite, hematite, and maghemite accounted for up to 30 wt.%. Among the Fe-MC, the sample collected from electrostatic precipitator fly ash (ESP FA), despite having a lower yield, presented higher Fe concentrations than the ones from bottom ash and economizer grits, which was related to the mode of occurrence of Fe-bearing phases: in the Fe-MC from ESP FA, discrete ferrospheres predominated, while in the remaining Fe-bearing phases, they were often embedded in aluminosilicate glass. All Fe-MC samples showed an increase of Fe-substituting elements (e.g., Mn and Ni) and their concentration tended to increase with decreasing particle size along with Fe. The integrated study of cross-sections enabled the identification of oxidation rims, martitization aspects, and the co-existence of hematite and magnesioferrite. [ABSTRACT FROM AUTHOR]

This article presents the influence of ashes generated in the combustion processes of various types of biomasses on the durability (resistance to freezing and thawing after 25 cycles) of cement mortars. Three types of ashes were used for the tests: two fly ashes and one bottom ash. These differ in chemical composition and microstructure in the amounts of 10%, 20%, and 30% of the cement mass and are used as a substitute for standard sand. The ashes are characterized in terms of microstructure and chemical composition. The research shows that, regardless of the type of ash used, all the cement mortars containing ash are characterized by higher durability than the control mortars. Among the modified mortars, the smallest decrease in resistance (by 0.54%) to the process of freezing and thawing is shown by cement mortars containing 10% fly ash from the combustion process of biomass with the addition of sunflower, and the largest (by 7.56%) show mortars containing 30% bottom ash from the combustion of biomass with the addition of sunflower. These findings suggest that the incorporation of biomass ashes, particularly fly ash, into the cement matrix mixes has the potential to improve their durability for road infrastructure applications. [ABSTRACT FROM AUTHOR]

Waste incineration in Europe has been increasing in the past few decades as there is a need to reduce the burden on landfills and their associated environmental concerns. While incineration reduces the volume of the waste, the volume of slag and ash is still substantial. To find out potential radiation risks that incineration residues could set to workers or the public, the levels of radioactive elements in these residues were investigated from nine waste incineration plants in Finland. Natural and artificial radionuclides were detected in the residues, but in general the activity concentrations were low. This study shows that the level of Cs-137 in the fly ash from municipal waste incineration follows the pattern of 1986 fallout zones in Finland, although the levels are significantly lower than in ash from bioenergy production from the same areas. Am-241 was also detected in many samples, although the activity concentrations were very low. Based on the findings in this study, the typical ash and slag residues from municipal waste incineration do not need radiation protection measures for workers or the public even in regions that received up to 80 kBq m−2 of Cs-137 fallout in 1986. The further use of these residues need not be restricted due to radioactivity. Hazardous waste incineration residues and other special cases need to be considered separately, depending on the original waste composition. [ABSTRACT FROM AUTHOR]

FABA is a by-product of coal combustion in power plants comprising fly ash (FA) and bottom ash (BA) in ratios of 80/20. Fly ash has great potential as a mineral ingredient in concrete, while bottom ash compromises its strength and durability. However, both materials are used to improve the strength and durability of structures in sulfate, chloride, and acidic environments. This research evaluated the properties of blended and high-volume FABA concrete, such as the strength, porosity, weight loss, and sorptivity in organic acidic peat water. OPC (Ordinary Portland Cement) was compared to the blended concrete containing 25% FABA and its high-volume containing 50% and 75% FABA with target strengths of 15, 21, and 29 MPa. The compressive strength of blended and high volume FABA increased during the immersion period, while the porosity and sorptivity rates decreased. Furthermore, the strength of the OPC concrete declined at 28 days, with a gradual marginal weight loss of 5% observed in all mixes. This research suggested that blended and high-volume FABA has potential as a construction material in an acidic peatland environment.

Residue concentrations of heavy metals, including As, Cd, Cr, Cu, Ni, Pb, and Zn, were determined in bottom ash, fly ash, and particulate matter (PM10) samples collected from five municipal incinerators in northern Vietnam to assess their occurrence, distribution characteristics, and potential risks. Concentrations and profiles of heavy metals are presented, showing the dominance of Zn in all types of samples. Highly volatile elements (Cd, Pb, and Zn) were found at elevated proportions in PM10 but not fly ash. The large difference in the heavy metal profiles could be explained by the variation of input raw materials, the absence of an appropriate cycle for the material feeding process, and post-combustion technology applied. Mass balance of heavy metals in the bottom ash, fly ash, and PM10 varied significantly between the investigated incinerators, largely due to the difference in incineration technology and air pollution control system. Emission factors and annual emissions were also estimated, indicating the highest value and amount in bottom ash, followed by PM10 and fly ash. Our results are among the first studies reporting contents and emissions of toxic elements in incinerated solid wastes in Vietnam. [ABSTRACT FROM AUTHOR]

The growing demand for rare-earth elements and yttrium (REY) in modern technologies has resulted in the systematic depletion of primary ores. For this reason, research is being conducted around the world on alternative sources of rare-earth elements, e.g., on the possibilities of recovering REY from coal waste or coal combustion. The article presents the results of comprehensive tests of the fuel—hard coal, and high-temperature HTA ash, fly ash, and bottom ash. Examined samples were taken from a Polish power plant. In the tests, fuel quality parameters were determined in accordance with the standards; microscopic observations in reflected and transmitted light, as well as a scanning electron microscope (SEM/EDS), were used, and chemical and phase composition were determined using ICP-MS and XRD methods, respectively. The distribution of REY between these ashes was analyzed. Their suitability as alternative sources of REY was assessed. The obtained results showed that the process of hard coal combustion in pulverized coal boilers influenced the geochemical differentiation of REY elements in energy waste. This differentiation is manifested by higher concentrations of REY and critical elements in the fly ash than in the bottom ash. The obtained values of the Coutl prospective coefficient made it possible to classify the analyzed fly and bottom ashes as prospective REY raw materials. [ABSTRACT FROM AUTHOR]

The concentrations and profiles of 18 polycyclic aromatic hydrocarbons (PAHs) in particulate matter (PM10), fly ash (FA), and bottom ash (BA) were examined in three incineration residues. Samples were collected from different municipal and industrial solid waste incinerators in Northern Vietnam. The average concentrations of total PAHs in PM10, fly ash, and bottom ash were 9.55 × 103 ng/Nm3, 215 × 103 ng/g, and 2.38 ng/g, respectively. Low-molecular-weight PAHs (2 to 3 rings) were predominant in most samples. The emission factor of total PAHs decreased in the order of FA > BA > PM10. A higher concentration of total PAHs was found in industrial facilities than that in municipal ones. The high carcinogenic proportion of PAHs together with significantly high annual emissions reflect the high pollution risk to the ecosystem by PAHs in the case of reuse of incineration ashes (e.g., brick production). Regarding the carcinogenic risk of PAH-bounded ashes or particles, calculations from this study imply the significant threat for workers who have been manipulated in the incineration facilities, directly exposed to fly and bottom ashes. Meanwhile, the risk from PAH-bound particulate was not considered a significant threat for both normal adults and children. Further study on PAHs contained in incinerator waste dumps should be conducted in Vietnam to assess the potential contamination risk of these incineration by-products. [ABSTRACT FROM AUTHOR]

Primary metal production operates with large tonnages and takes advantage of economies of scale. Metal recycled from low-value waste streams, competing in the same global metal market as primary production, will be more competitive by also taking advantage of up-scaling. However, an overview of metal tonnages in low-value waste streams to see upscaling potential needs to be provided in the literature. In response, this study provides estimates of copper, zinc, and lead metal tonnages in waste incineration ash—A major waste stream going to landfills. Metal concentrations and tonnages are compared to tonnages and concentration grades found in ores. Copper, zinc, and lead concentration averages are about 3–5 times lower in ash compared to the worldwide average head grade of ores. Tonnages of metal in the ash generated from waste incineration in European countries bordering the Baltic and the North Sea are about 1/3 of mining metal output from Sweden, a leading mining country in the region. Therefore, incineration ash should be considered a significant potential Cu, Zn, and Pb metal source. [ABSTRACT FROM AUTHOR]

This study used thermal power plant fly ash (FA) and bottom ash (BA) as fill materials and investigated the thermal properties of composites made of cement and pine tree resin binders. For each ash group, 36 samples were prepared by adding 50% cement and 1% to 2% resin as binders. i) FA samples had 23.18%, 22.99%, and 77.01% lower density, thermal conductivity, and compressive strength than BA samples, respectively. FA samples had 9.42% higher porosity than BA samples. ii) FA (0.177 W/mK) and BA (0.221 W/mK) samples with resin and cement had the lowest heat transfer coefficients. iii) FA (14.46 MPa) and BA (36.96 MPa) samples (resin + cement binder) had the highest compressive strength values. [ABSTRACT FROM AUTHOR]

Coal ash, such as fly ash (FA) and bottom ash (BA) is mostly generated from a Coal-fired Steam Power Generation (PLTU) process. An increase in the number of PLTUs in Indonesia is proportional to the high volume of FA and BA generated, causing adverse environmental impacts if not properly treated. Various studies have highlighted the potential valorization of FA and BA, including building materials, cement ingredients, concrete, and growing media. This study aimed to evaluate the potential use of FA and BA as a growing media and to explore the potential future application for reclamation of heavy-metal-contaminated (or ex-mining) land. The results showed that composting FA with blackwater sludge (BWS) and rice straw (RS) produced compost that complied with the targeted standard. The addition of FA, BA, and composted FA in the growing media impact the growth and Zn adsorption ability of the dwarf elephant grass (Pennisetum purpureum cv. Mott). However, the composted FA has superior performance in general as a growing media. The future estimation of the application FA and BA combined with domestic waste (blackwater and greywater) for reclamation of ex-mining land is proposed. By integrating the phytoremediation ability of the grass plants and the biorefinery approach, the proposed future estimation may provide a sustainable valorization pathway of FA and BA for heavy metal-contaminated or ex-mining land reclamation. Thus, transforming FA and BA as a component of growing media could reduce the potential risk of heavy metals distribution into the food chain and the surrounding environment.

[Display omitted] • MSWI thermal energy recovery greatly benefits FA vitrification sustainability. • Vitrification of incineration residues makes them safe to produce new products. • Glass cullet as silica source most sustainable option among studied scenarios. • Silica source type affects all analyzed impacts more than energy requirement. • Despite some drawbacks, sensitivity scenarios could lead to new studies. Municipal solid waste (MSW) production in the world has increased by 60 % in recent years. Incineration of MSW reduces their volume in conjunction with energy recovery. Incineration produces two residues, namely bottom ash (BA) and fly ash (FA), with high concentration of heavy metals and organic pollutants, especially for FA, making them an environmental concern. Vitrification is a costly, highly safe high temperature treatment, ensuring encapsulation of heavy metals. FA vitrification requires a source of silica to be able to get vitrified. In this study, we have proposed valorizing treated (vitrified) FA through the production of porous glass-ceramics, subsequently to MSWI. The entire process, from incineration to glass-ceramics production, was evaluated for several scenarios by Life Cycle Assessment (LCA) using Sima Pro 9.0. Three main scenarios were analysed; each one considering a different silica source: bottom ash (BA), glass cullet (G) and silica sand (S), and for each scenario, three thermal recovery subscenarios were assumed: no thermal recovery used to heat FA prior to vitrification (N), heating FA prior to vitrification using incineration gases thermal recovery (T) and methane-combustion-aided thermal recovery, which exploits methane combustion to further increase the gases temperature (M). Results proved that vitrification was a technically feasible and environmentally-energetically sustainable technology. The result indicates that the most eco-sustainable scenario was using bottom ashes as a silica source together with methane-combustion-aided recovery: 0.467 kgCO 2,eq , 5.83 × 10-8 carcinogenic-CTUh and 9.26 MJ required per kg of glass-ceramics produced. [ABSTRACT FROM AUTHOR]

FABA is a by-product of coal combustion in power plants comprising fly ash (FA) and bottom ash (BA) in ratios of 80/20. Fly ash has great potential as a mineral ingredient in concrete, while bottom ash compromises its strength and durability. However, both materials are used to improve the strength and durability of structures in sulfate, chloride, and acidic environments. This research evaluated the properties of blended and high-volume FABA concrete, such as the strength, porosity, weight loss, and sorptivity in organic acidic peat water. OPC (Ordinary Portland Cement) was compared to the blended concrete containing 25% FABA and its high-volume containing 50% and 75% FABA with target strengths of 15, 21, and 29 MPa. The compressive strength of blended and high volume FABA increased during the immersion period, while the porosity and sorptivity rates decreased. Furthermore, the strength of the OPC concrete declined at 28 days, with a gradual marginal weight loss of 5% observed in all mixes. This research suggested that blended and high-volume FABA has potential as a construction material in an acidic peatland environment. [ABSTRACT FROM AUTHOR]

Using fly ash in hard coal mines may lead to an increase in hydrogen concentrations in the mine atmosphere. This may result in incorrect fire risk assessment based on changes in hydrogen concentrations and fire indicators determined on their basis. The paper presents the results of changes in the concentrations of hydrogen and other gaseous components obtained from water–ash mixtures generated from the ash obtained from a coal-fired boiler and a coal- and biomass-fired boiler. As a result of the experiment, it was found that the only gas evolving from mixtures in large quantities was hydrogen. Other gaseous components, important from the point of view of fire hazard assessment (ethylene, propylene, acetylene, carbon monoxide), were released in very small amounts. Several dozen times higher amounts of hydrogen were released from fly ash obtained from a boiler in which biomass is co-fired together with coal, than from the ash from a coal-fired boiler. The highest intensity of hydrogen evolution was observed within the first 24 h from the moment of producing water–ash mixtures. At a subsequent time, hydrogen evolution was clearly smaller. Hydrogen was also released from water–ash mixtures made from bottom ash. However, the determined values of hydrogen concentration were several hundred times lower than the concentrations of hydrogen released from fly ash. [ABSTRACT FROM AUTHOR]

Data on the elemental and radionuclide (40K, 137Сs, and U- and Th-series radionuclides) composition of the samples of coal, bottom ash, and fly ash from the largest thermal power plant TPP-4 located in Ulaanbaatar (Mongolia) and soil and plants samples in the area of this TPP are reported. Analytical determinations were carried out using X-ray fluorescence, gamma-activation, and gamma-spectrometric analysis. It was found that the coals used were enriched in toxic trace elements; elements such as V, Zn, As, Pb, Bi, Th, U, and natural radionuclides, including 210Pb, were significantly concentrated in the ash fractions, as compared to the initial fuel. The degree of soil contamination, the radiation hazard of the TPP impact for the population, and the level of potential hazard (material's hazard class) of ash and slag waste were evaluated. It was recommended to perform regular monitoring. [ABSTRACT FROM AUTHOR]

Clay soil has a characteristic that is wet, it will be soft and plastic and cohesive. To overcome this problem, clay soil with high plasticity needs stabilization. The stabilization method using additives such as chalk, fly ash and bottom ash can be used as a stabilization material to increase the carrying capacity of high plasticity clay. This study is commended to know the behavior of high plasticity clay which is stabilized with lime, fly ash and bottom ash. Increased crease of the stabilized clay soil is seen from the CBR test. CBR testing is done under curing conditions for 0, 14, and 28 days and soaking for 0 and 4 days. The results showed that the CBR value increased with duration of curing and decreased throughout the duration of immersion. Then the CBR value increases with the addition of lime percentage and each mixture in a mixture variation. The highest CBR value occurred in soil L 5% + MS5 95% with a CBR value of 75.37% under conditions for 28 days of curing and 4 days of immersion. The lowest CBR value occurs in soil L 5% + MS2 95% with a CBR value of 12.85% in conditions without curing and without immersion.

Abstract In Canada, the combustion of forest biomass for bioenergy production has been increasing with an associated increase in residual wood ash. Wood ash is typically landfilled as waste but there is growing interest in applying wood ash to the soils of commercial forests. Ideally, wood ash supplies nutrients that may have been removed through biomass harvesting, increases soil pH, which improves nutrient availability, and potentially improves site productivity, but there is also potential for detrimental effects, such as toxicity, that impair soil functions. The objective of this study was to investigate the effects of wood ash application on soil organic matter attributes at eight experimental sites across Canada that are examining the effects of wood ash application on site fertility, productivity, and soil biodiversity. Wood ash application had an effect on total carbon (TC) and total nitrogen, microbial biomass carbon (MBC), hot water extractable carbon (HWEC), mineralizable C, sand size C, and HWEC and MBC normalized to TC, but changes were typically restricted to single sites or differed in their direction, that is, positive or negative. Based on the limited and inconsistent effects of ash on established indictors of soil quality measured in this study, there does not appear to be any advantageous or detrimental effects of adding wood ash to forest soil quality.