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Aiming at understanding the source of the fluids that mineralizing within seismically active fault zones, we investigate the noble gas isotopes (i.e., helium (He), neon (Ne), and argon (Ar)) in the fluid inclusions (FIs) trapped in the calcite veins sampled along high‐angle fault zones of the Contursi hydrothermal basin, southern Italy. The latter basin lies in close vicinity of the MW = 6.9, 1980 Irpinia earthquake and exposes numerous fault scarps dissecting Mesozoic shallow‐water carbonates. The analyses of noble gases (He, Ne, Ar) are conducted to identify the origin of the volatiles circulating along the faults at the time of calcite precipitation. Then, outcomes of this discussions are compared with currently outgassing of deep‐sourced CO2 coupled to mantle‐derived He in that area, whose output is larger than those from some volcanic areas worldwide. The results indicate that He in FIs is dominated by a crustal radiogenic component (4He), and by an up to 20% of a mantle‐derived component (3He), with a highest isotopic signature of 1.38 Ra. This value is consistent with the highest percentage of mantle‐derived He associated to high‐flux CO2 gas emission in the investigated area (1.41 Ra). We propose that the variability of the He isotopic signature measured in primary FIs can result from early trapping of fluid inclusions or post trapping processes and seismic activity that modify the pristine He isotopic signature (i.e., derived from the crust and/or mantle) in groundwater along the faults during periods of background seismicity. Such investigations are fundamental to understand fluid migration in fault systems and the role of fluids in processes of earthquake nucleation. Key Points: Paleofluids in the studied seismogenic fault derive from the mixing between crustal and mantle (∼20%) derived fluidsThe variability of the He isotopic signature registered in fluid inclusions results from either early trapping processes (due to past possible earthquakes events) or post trapping processes by addition of radiogenic 4He produced within fractured calcite veins over time (vein aging)The pristine mantle source has been active in the Irpinia area (southern Italy) for at least 1 Ma based on the post trapping process [ABSTRACT FROM AUTHOR]

Abstract Aiming at understanding the source of the fluids that mineralizing within seismically active fault zones, we investigate the noble gas isotopes (i.e., helium (He), neon (Ne), and argon (Ar)) in the fluid inclusions (FIs) trapped in the calcite veins sampled along high‐angle fault zones of the Contursi hydrothermal basin, southern Italy. The latter basin lies in close vicinity of the MW = 6.9, 1980 Irpinia earthquake and exposes numerous fault scarps dissecting Mesozoic shallow‐water carbonates. The analyses of noble gases (He, Ne, Ar) are conducted to identify the origin of the volatiles circulating along the faults at the time of calcite precipitation. Then, outcomes of this discussions are compared with currently outgassing of deep‐sourced CO2 coupled to mantle‐derived He in that area, whose output is larger than those from some volcanic areas worldwide. The results indicate that He in FIs is dominated by a crustal radiogenic component (4He), and by an up to 20% of a mantle‐derived component (3He), with a highest isotopic signature of 1.38 Ra. This value is consistent with the highest percentage of mantle‐derived He associated to high‐flux CO2 gas emission in the investigated area (1.41 Ra). We propose that the variability of the He isotopic signature measured in primary FIs can result from early trapping of fluid inclusions or post trapping processes and seismic activity that modify the pristine He isotopic signature (i.e., derived from the crust and/or mantle) in groundwater along the faults during periods of background seismicity. Such investigations are fundamental to understand fluid migration in fault systems and the role of fluids in processes of earthquake nucleation.

The Middle Permain Maokou Formation (P2m) is a new region of natural gas exploration in the Sichuan Basin, is characterized by bioclastic limestone with localized dolomitization, and karst fractured-vuggy reservoirs. Currently, on the gas source, hydrocarbon accumulation process and control factors in the Sichuan Basin during the Permian are lacking. To bridge this gap, herein, we identified the filling sequence minerals inside the pores/vugs, along with the oil charge of the Maokou Formation using drill cores, thin sections, oil inclusion analysis, and U-Pb dating of calcite cements. The results showed that the reservoir space of the Maokou Formation was predominated by the residual dissolved pores/vugs, fractures, and dissolved fractures. The pores/vugs underwent four stages of mineral filling by very fine-fine (-crystalline, CC1) calcite ^ fine-medium calcite (CC2: from 256.4 ± 1.7 to 244.1 ± 6.3 Ma) ^ fibrous calcite (FC; -183.9 ± 8.2 Ma) ^ coarse-macro calcite (CC3; -171.5 ± 5.3 Ma). Combined with the homogenization temperature and salty of fluid inclusion, we considered that three stages of oil charge were present in the Maokou Formation reservoirs. The first stage involved the formation of paleo-oil reservoirs during the Late Permian to Early Triassic, corresponding to the high-maturity aqueous inclusions in CC2, with a homogenization temperature of 106.7°C-137.8°C. At that time, the oil generation from the Lower Cambrian Qiongzhusi Formation rocks peaked, and the generated hydrocarbons migrated upward into the Maokou Formation through the strike-slip faults in the basin center. The second stage involved the formation of paleo-oil reservoirs during the Early Jurassic. The Permian source rocks reached the oil generation window with hydrocarbon expulsion, which was consistent with the oil inclusions in FC. The third stage involved the formation of paleo-gas reservoirs during the Middle Jurassic to Early Cretaceous, corresponding to the high-density methane inclusions and bitumen inclusions occurring in CC3, with the homogenization temperature peaking at 151.9°C-178°C. The natural gas in the Middle Permian of the Central Sichuan Basin is predominantly sourced from the Lower Cambrian Qiongzhusi Formation mudstone and partially from the source rocks of the Middle Permian, indicating a significant source-reservoir conduit of the strike-slip faults in the basin center. The findings provide considerable baseline data to advance further research in the Sichuan Basin. [ABSTRACT FROM AUTHOR]

The Middle Permain Maokou Formation (P2m) is a new region of natural gas exploration in the Sichuan Basin, is characterized by bioclastic limestone with localized dolomitization, and karst fractured-vuggy reservoirs. Currently, on the gas source, hydrocarbon accumulation process and control factors in the Sichuan Basin during the Permian are lacking. To bridge this gap, herein, we identified the filling sequence minerals inside the pores/vugs, along with the oil charge of the Maokou Formation using drill cores, thin sections, oil inclusion analysis, and U-Pb dating of calcite cements. The results showed that the reservoir space of the Maokou Formation was predominated by the residual dissolved pores/vugs, fractures, and dissolved fractures. The pores/vugs underwent four stages of mineral filling by very fine-fine (-crystalline, CC1) calcite → fine-medium calcite (CC2: from 256.4 ± 1.7 to 244.1 ± 6.3 Ma) → fibrous calcite (FC; ∼183.9 ± 8.2 Ma) → coarse-macro calcite (CC3; ∼171.5 ± 5.3 Ma). Combined with the homogenization temperature and salty of fluid inclusion, we considered that three stages of oil charge were present in the Maokou Formation reservoirs. The first stage involved the formation of paleo-oil reservoirs during the Late Permian to Early Triassic, corresponding to the high-maturity aqueous inclusions in CC2, with a homogenization temperature of 106.7°C–137.8°C. At that time, the oil generation from the Lower Cambrian Qiongzhusi Formation rocks peaked, and the generated hydrocarbons migrated upward into the Maokou Formation through the strike-slip faults in the basin center. The second stage involved the formation of paleo-oil reservoirs during the Early Jurassic. The Permian source rocks reached the oil generation window with hydrocarbon expulsion, which was consistent with the oil inclusions in FC. The third stage involved the formation of paleo-gas reservoirs during the Middle Jurassic to Early Cretaceous, corresponding to the high-density methane inclusions and bitumen inclusions occurring in CC3, with the homogenization temperature peaking at 151.9°C–178°C. The natural gas in the Middle Permian of the Central Sichuan Basin is predominantly sourced from the Lower Cambrian Qiongzhusi Formation mudstone and partially from the source rocks of the Middle Permian, indicating a significant source-reservoir conduit of the strike-slip faults in the basin center. The findings provide considerable baseline data to advance further research in the Sichuan Basin.

The 8# coal seam in the Benxi Formation of the southeastern margin of the Ordos Basin is a deep coal seam with abundant coalbed methane resources. Calcite veins are commonly developed within the 8# coal seam, and their formation processes and mechanisms have significant implications for the enrichment of deep coalbed methane. Genesis of the calcite veins was analyzed to reveal the impact of the calcite veins formation on coalbed methane accumulation, with an integrated application of petrographic study by thin section, cathodoluminescence analysis, carbon-oxygen isotope analysis, and homogeneous temperature measurements of fluid inclusions. The research findings indicate that the calcite veins in the 8# coal seam can be classified into three stages: C1, C2, and C3. The diagenetic fluids of C1 primarily originated from contemporaneous seawater. The fluids responsible for the formation of C2 primarily consist of organic fluids enriched in biogenic gas, whereas the fluids contributing to the formation of C3 are primarily associated with liquid hydrocarbons originated form decarboxylation of organic matter. Furthermore, the development of both C2 and C3 is influenced by deep hydrothermal fluids resulting from tectonic heating events during the Early Cretaceous. By combining analysis of the hydrocarbon accumulation history and burial history in the study area, it has been established that C2 formation occurred during the Late Triassic to Early Jurassic, while C3 formation took place during the Late Jurassic to Early Cretaceous. The exploration and production practices in the study area have firmly established the crucial significance of the formation and evolution of calcite veins within the 8# coal seam for the migration and accumulation of coalbed methane. The research outcomes provide valuable insights for the exploration of deep coalbed methane enrichment areas. [ABSTRACT FROM AUTHOR]

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The distribution of oxygen isotopes between calcite and fluid inclusions has demonstrated utility for reconstructing near-surface calcite precipitation temperatures. For calcite that formed at depth, however, the resilience of this paleothermometer to diagenetic oxygen isotope alteration is poorly constrained. Clumped isotopes also document calcite precipitation temperatures and are similarly vulnerable to diagenetic alteration. Post-entrapment isotope exchange between calcite and fluid-inclusions could alter the calcite-fluid oxygen isotope distribution (α c-fi), as well as the clumped isotope composition (Δ 47) of calcite, and therefore these two seemingly independent paleo-thermometers are potentially linked via the same alteration process. Using closed-system batch fractionation equations, we have modelled various scenarios of oxygen isotope exchange between water and host-rock during burial, as well as internal oxygen isotope exchange between calcite and fluid inclusions during exhumation. Assuming both paleo-thermometers record concordant temperatures at the time of vein formation, our models predict that if a fraction of calcite is available for isotopic interaction with fluid inclusions, the fluid inclusion and clumped isotope-derived paleothermometers yield discrepant temperature estimates after exhumation. We show that the fluid inclusion thermometer is more sensitive to isotopic alteration than the clumped isotope thermometer and that the mass balance of oxygen between calcite and fluid inclusions determines the sensitivity of both paleothermometers as well as the vulnerability of fluid inclusions (δ18O fi) to diagenetic overprinting. We applied coupled clumped isotope and fluid inclusion measurements on calcite veins from the External Albanides (Albania), which were formed at depth and subsequently exhumed, in order to compare natural samples to our isotope exchange model. These veins show strongly discrepant calcite-water equilibrium temperatures and clumped isotope temperatures, suggesting the fraction of calcite available for isotope exchange with internal fluids may indeed be a key parameter of diagenetic alteration during exhumation. Even though the clumped isotope temperatures of our samples appear to be insensitive towards internal oxygen isotope exchange, our model predicts that at low burial temperatures, the carbonate clumped isotope thermometer may be susceptible to alteration by diagenetic isotope exchange with fluid inclusions under certain conditions. [ABSTRACT FROM AUTHOR]

Based on the published data of pillow lava-hosted mineralized veins, this study compares post-magmatic fracturing, fluid flow, and secondary mineralization processes in the Troodos and Izu–Bonin supra-subduction zone (SSZ) and discusses the crucial factors for the development of distinct vein types. Thin section and cathodoluminescence petrography, Raman spectroscopy, fluid inclusion microthermometry, and trace element and isotope (87Sr/86Sr, δ18O, δ13C, Δ47) geochemistry indicate that most veins consist of calcite that precipitated from pristine to slightly modified seawater at temperatures < 50 °C. In response to the mode of fracturing, fluid supply, and mineral growth dynamics, calcites developed distinct blocky (precipitation into fluid-filled fractures), syntaxial (crack and sealing), and antitaxial (diffusion-fed displacive growth) vein microtextures with vein type-specific geochemical signatures. Blocky veins predominate in all study areas, whereas syntaxial veins represent subordinate structures. Antitaxial veins occur in all study areas but are particularly abundant in the Izu–Bonin rear arc where the local geological setting was conducive of antitaxial veining. The temporal framework of major calcite veining coincides with the onset of extensional faulting in the respective areas and points to a tectonic control on veining. Thus, major calcite veining in the Troodos SSZ began contemporaneously with volcanic activity and extensional faulting and completed within ~ 10–20 Myr. This enabled deep seawater downflow and hydrothermal fluid upflow. In the Izu–Bonin forearc, reliable ages of vein calcites point to vein formation > 15 Myr after subduction initiation. Therefore, high-T mineralization (calcite, quartz, analcime) up to 230 °C is restricted to the Troodos SSZ. [ABSTRACT FROM AUTHOR]

Many low-permeability, hydrocarbon-bearing rocks are productive for petroleum because natural fractures enhance hydrocarbon delivery to wellbores. Exploration and development decisions often must be made in the face of uncertainty about the presence and properties of natural fractures at scales of beds, field and plays, and how they contribute to production. Fractures patterns in subsurface rocks are challenging to predict or characterize owing to the difficulty in obtaining representative samples of fractures and the sparse set of tools for reconstructing how and when fractures grow during sedimentary basin evolution. In this study, we investigate bed-parallel fracture diagenesis in the Vaca Muerta shales (Argentina) based on a set of calcite vein collected from core across a thermal maturity sequence that ranges from the oil to dry gas window. We characterize these samples using secondary ions mass spectrometry (SIMS) measurements of stable isotope ratios, carbonate clumped isotope geothermometry and fluid inclusion analysis. These measurements precisely reconstruct the evolution of fluid geochemistry, temperature and pore fluid pressure during fracture opening. Here we show that within each studied site, all bedding parallel fibrous veins calcite formed at similar ranges of temperature. The fracture mineralization temperature increases substantially at the basin scale, from 90 °C to 120 °C, correlated with host-rock thermal maturity. We compare our constraints on carbonate and fluid temperature with apatite fission track thermal models and find that most of the fractures of the Vaca Muerta shales have formed in a relatively early stage of subsidence of the basin (c.a. 90 to 70 Ma). These ages estimations are consistent with recently published U–Pb ages on calcite veins from the outcropping area (117–61 Ma). The presence of petroleum inclusions (oil, condensate, and gas) in most of the vein's calcite fibers from cores also provides clear evidence that fracture formation was contemporaneous or posterior with petroleum generation, constraining the timing of catagenesis in the Vaca Muerta. Reconstructed paleo pressures conditions of veins formation from fluid inclusion analysis highlight significant fluid overpressure in the shale interval, which likely contributed to fracture initiation and growth. Preserved apparent Δ 47 temperatures in fibrous veins carbonates mineralization evolves gradually from 130 °C to 175 °C with increasing host rock thermal maturity. These clumped-isotope-based temperatures are systematically higher than trapping temperatures of associated fluid inclusions; one interpretation of this observation is that carbonate clumped isotope compositions re-equilibrated to near maximum burial conditions by solid-state isotopic re-ordering, yielding a record of the maximum burial temperature the shale unit experienced. The combination of paleothermometry techniques used in this study illustrates the importance of simultaneously exploring several independent geothermometers, particularly the informative combination of fluid inclusion and clumped isotope constraints, which provides a means of understanding the complex diagenesis of old sedimentary rocks that have experienced burial temperatures in the oil and gas thermal windows. • Paired clumped isotope paleothermometry and fluid inclusion analyses for time–temperature evaluation for natural fractures in the VMF. • Direct relationship between hydraulic fracturing intensity and the level of organic catagenesis (maturity) • PVT modelling of aqueous-HC fluid inclusions indicate that calcite precipitation under fluid overpressure. • Combination of FI and Δ 47 geothermometry indicate altered (reset) Δ 47 compositions during burial. [ABSTRACT FROM AUTHOR]

The extensional Val Roveto Fault, which is the longest exhumed potentially-seismogenic structure of central Apennines, Italy, is examined to constrain earthquake-related fluid circulation and fluid sources within shallow carbonate-hosted faults. The study focuses on fault-related comb and slip-parallel veins that are calcite-filled and cut through the principal surface of the Val Roveto Fault. We observe multiple crack-and-seal events characterized by several veining episodes, probably related to different slip increments along the fault plane. We show that vein calcite precipitated in Late Pleistocene time below the present-day outcrop level at a maximum depth of ∼350 m and temperatures between 32 and 64 °C from meteoric-derived fluids modified by reactions with crustal rocks and with a mantle contribution (up to ∼39%). The observed warm temperatures are not compatible with a shallow (≤∼350 m) precipitation depth, which, in this region, is dominated by circulation of cold meteoric water and/or shallow groundwater. Based on structural–geochemical data, we propose that deep-seated crust–mantle-derived warm fluids were squeezed upward during earthquakes and were hence responsible for calcite precipitation at shallow depths in co-seismic comb and slip-parallel fractures. As comb- and slip-parallel veins are rather common, particularly along seismogenic extensional faults, we suggest that further studies are necessary to test whether these veins are often of co-seismic origin. If so, they may become a unique and irreplaceable tool to unravel the seismic history of hazardous active faults. [ABSTRACT FROM AUTHOR]

The Jabal Qusaybah Anticline, in north Oman, is affected by syn-folding strike-slip and extensional fault zones developed during foreland deformation ahead of the Northern Oman Mountains thrust wedge, in Cenozoic times. Migration of fluids in fault-damage zones is recorded in complex calcite vein networks. By employing the microthermometric and compositional microanalysis of the fluid inclusions (crush-leach), two distinct generations of veins have been studied. The aim was to determine the source of elevated salinity in fluids involved in their cementation and explain their compositional evolution through fluid-rock interactions. The ionic ratios (Na/Br and Cl/Br) obtained from crush-leach analysis give supporting evidence that the elevated salinity of fluid inclusions in both vein groups originated from an evaporated seawater beyond the onset of halite precipitation (residual brines). The results reveal a gradual increase in salinity of the fluids, F/Cl molar ratios, as well as Li/Cl molar ratios. These results imply the progressively increasing contribution of evaporitic residual brines and fluids that interacted with, or were derived from siliciclastic rocks. We suggest that the most likely origin of the former fluids is provided by residual brines associated with precipitation of the Ara evaporites (Cambrian). The regional driving mechanism for such a significant fluid migration is believed to be compaction-driven upward flow that was channeled into faults and fractures during major deformational events. [ABSTRACT FROM AUTHOR]

Calcite veins in carbonate fracture have been investigated by petrographic, fluid inclusion, geochemical analyses and coupled with basin modeling techniques to provide useful insights into fluid activity and deformation conditions of the Cambrian to Triassic Shizhu synclinorium from the western region of Mid-Yangtze, central China. The results of the fluid inclusion microthermometry show a wide range of homogenization temperatures (78.6-215.5 °C) and salinities (0.18-23.11 wt.% NaCl equivalent), indicating the formation under diverse fluid conditions. All the calcite veins have negative Ce anomalies, which are the typical characteristic of marine carbonate sediments; it is therefore plausible that calcite veins were precipitated from the marine basin fluid. The stable carbon iso-topic compositions of calcites ( δ C=-2.5‰-4.26‰) and host limestones ( δ C=-3.56‰-5.80‰) are very similar with a correlation coefficient of 0.86, however, four calcites from the Lower Permian and Lower Triassic show lower δ C values relative to the host limestones, and they are depleted in total REE concentrations (ΣREE ratio varies from 0.74 to 2.06), suggesting the derivation of dissolved carbon from marine carbonates hosting the calcite veins and, less commonly, from the degradation of organic matter. Calculated δ O of the fluids-precipitating calcites ( δ O=-0.41‰-14.42‰), Sr/Sr ratios varying in the range of coeval seawater and the distinct REE pattern simultaneously suggest calcite-forming fluids in each stratigraphic unit could have formed from the involvement of fluids that originated from coeval seawater and evolved through different degrees of water rock interaction. However, the presence of more radiogenic Sr/Sr ratios than coeval seawater and pronounced positive Eu anomalies in calcites of Lower to Middle Ordovician rocks indicate that terrestrial input from upper strata mudstone and siliciclastic rocks could be involved in the precipitation of the Ordovician calcite. Fluid-inclusion data combined with burial and thermal history modeling indicate there was large-scale flow of evolved basinal fluids through the carbonate formation fractures spanning a time frame from 135 to 50 Ma (Early Cretaceous-Eocene). Therefore, the geochemical characteristics of calcite veins can provide the basis for deformation events in Late Yanshanian and Early Himalayan orogeny. [ABSTRACT FROM AUTHOR]

Calcite veins hosted in the Triassic Stockton, Lockatong and Passaic formations of the Newark Basin are investigated to reconstruct the fluid evolution. To constrain the parameters of calcite precipitation, a microthermometry study was carried, which reveals precipitation of calcite from a low to moderate saline H 2 O-NaCl fluid (0.4 to 13.2 wt% NaCl equiv.) under low to moderate hydrothermal (137 °C to 232 °C) conditions. This fluid composition is interpreted to reflect mixing between a deep basement-derived heated diluted fluid and relatively low to moderate saline diagenetic formation waters hosted in the different Triassic formations. Carbon and strontium isotope analysis on the vein calcites suggests that these elements are derived from the pre-Triassic basement and the sedimentary cover through fluid-rock interactions. The aforementioned geochemical findings are supported by Rare Earth Elements and Yttrium (REY) systematics and oxygen isotope data. The Late Triassic extensional activity and gravity-driven fluid flow mechanism facilitated the infiltration of meteoric waters to deeper lithostratigraphic units (i.e., Precambrian-Paleozoic basement-Triassic Stockton Formation) where they became heated. In response to the extensional tectonics, the deep-seated hydrothermal basement-derived diluted fluids migrated upward along the tectonic-related fractures and the major faults to upper shallow crustal levels. Here, the heated, diluted meteoric waters were mixed with low, moderately saline, and relatively cooler formation waters, leading to calcite precipitation. The pH increase is suggested to be a contributing factor in the precipitation of calcite. [Display omitted] • During Late Triassic extensional activity, the meteoric waters descended to deep parts of the Newark basin. • Cross-basinal migration of these deep-seated hydrothermal fluids was ensured primarily by the topographically-driven flow mechanism • During Early Jurassic, extension tectonics facilitated the upward migration of the deep-seated fluids to shallow crustal levels • Fluid mixing occured between the basement-derived diluted fluids and shallowformational waters, leading to calcite precipitation. [ABSTRACT FROM AUTHOR]

Structures in Cretaceous strata in the Devils River Uplift of west Texas include folds, thrust faults, and bedding-parallel veins indicative of contractional deformation in a thrust faulting stress regime. In this study we analyze a series of small-wavelength (meters to tens of meters) folds in roadcut exposures northwest of Del Rio, Texas. The folds have WNW-ESE dominant trends, gently plunging axes, and are gentle to tight with upright to inclined axial surfaces of variable vergence. These structures are interpreted as detachment folds, with detachments within volcanic ash or mudrock beds. Observed thickening in anticline cores was by ductile flow of volcanic ash or mudrock, small-scale folding, and thrust or reverse faulting. Bed-perpendicular calcite veins are common and in some cases are offset by flexural slip on fold limbs, indicating that folding occurred after brittle failure and extension vein formation in lithified rock. Although rare, bed-parallel calcite veins are also present in the exposure and indicative of a thrust faulting stress regime. Occasional normal and reverse or thrust faults are also present in the exposures. Fluid inclusion analysis of vein cements from extension fractures and faults yielded homogenization temperatures of 71–101 °C, and estimated trapping depths of 2.2–3.5 km prior to and coeval with folding. We interpret these folds as having formed during NNE-SSW directed Laramide shortening (∼80–40 Ma) in a thrust-faulting stress regime with >2 km of overburden, rather than as either penecontemporaneous with deposition or after exhumation by caliche formation, as previously interpreted. • Analyses of small-wavelength folds in Devils River Uplift, west Texas. • Folds are typically detached above volcanic ash or mudrock beds. • Calcite veins offset by flexural-slip on fold limbs – bed-parallel veins rare. • Vein fluid inclusions trapped at 71–101 °C, and depths of 2.2–3.5 km. • Folds record NNE-SSW directed Laramide shortening. [ABSTRACT FROM AUTHOR]

We analyzed from meso-to microscale the chemical interaction (e.g., bleaching) between deep fluids and carbonate rocks in pelagic limestones exposed along the seismically active Gubbio normal fault (Northern Apennines), exhumed from ca. 2 km depth. Bleaching is enhanced by the exploitation of inherited stylolitic seams by fluids and is favored by the progressive leaching and mobilization of primary components (i.e., Ca, Fe, Pb, and Cu) and the precipitation of authigenic baryte due to temperature and/or redox potential contrast. Analysis of fluid inclusions trapped in calcite veins in the damage zone precipitated from a H 2 O–NaCl-bearing fluid(s), with low salinity (1.22–2.57 wt%NaCleq) and a range of trapping temperature between 107 °C and 185 °C, higher than the host rock peak T conditions. Analysis of fluid inclusions and noble gases from syn-kinematic calcite and mineralogy of altered rocks suggests a mixed contribution between crustal-derived fluids with diagenetic fluids containing sulphates and CO 2. We speculate that bleaching is a by-product of the circulation of such aggressive fluids with mixed contributions, likely mobilized during seismic event(s) and injected into the damage zone at shallow depths. Such processes, affecting the chemical-physical properties of limestones, are generally underestimated and should be considered when modelling hydraulic connectivity in fractured carbonate reservoirs. • Fault-rocks heterogeneity in carbonate-bearing faults forms structural domains with distinct permeability. • Bleaching of carbonates in the Gubbio fault is tectonically controlled. • Host rock alteration occurs by dissolution of calcite and hematite and precipitation of authigenic baryte at the reaction front. • Bleaching as exhumed evidence of circulation of deep-derived CO 2 -rich fluids in seismic faults. [ABSTRACT FROM AUTHOR]

A low-angle extensional fault system affecting the non metamorphic rocks of the carbonate dominated Tuscan succession is exposed in the Lima valley (Northern Apennines, Italy). This fault system affects the right-side-up limb of a kilometric-scale recumbent isoclinal anticline and is, in turn, affected by superimposed folding and late-tectonic high-angle extensional faulting. The architecture of the low-angle fault system has been investigated through detailed structural mapping and damage zone characterization. Pressure-depth conditions and paleofluid evolution of the fault system have been studied through microstructural, mineralogical, petrographic, fluid inclusion and stable isotope analyses. Our results show that the low-angle fault system was active during exhumation of the Tuscan succession at about 180°C and 5 km depth, with the involvement of low-salinity fluids. Within this temperature - depth framework, the fault zone architecture shows important differences related to the different lithologies involved in the fault system and to the role played by the fluids during deformation. In places, footwall overpressuring influenced active deformation mechanisms and favored shear strain localization. Our observations indicate that extensional structures affected the central sector of the Northern Apennines thrust wedge during the orogenic contractional history, modifying the fluid circulation through the upper crust and influencing its mechanical behavior. [ABSTRACT FROM AUTHOR]

The Paraná Basin, southern Brazil, has an atypical thermal and fluid history due to the occurrence of an episodic continental flood volcanism during the Early Cretaceous. So far, there are few data about the influence of this volcanic event on the paleotemperatures and paleofluids of the Paraná Basin sedimentary rocks. The Teresina Formation in the northern flank of the Ponta Grossa dyke swarm hosts high concentration of subsurface igneous rock bodies (sills and dykes), besides its covering by a hundreds meter thick volcanic rock cap. In this study, we used fluid inclusion analysis performed in horizontal and vertical calcite veins from the Teresina Formation and from a Late Cretaceous basic dyke to estimate paleotemperatures and to characterize the composition of diagenetic paleofluids. Homogenization temperatures of requilibrated fluid inclusions show that the Teresina Formation reached temperatures above 200 °C. Horizontal parallel bedding calcite veins from the Teresina Formation record low to high salinity (2–26 wt.% NaCl eq.) aqueous paleofluids. The prevalence of high salinity fluid inclusions associated with light hydrocarbon fluid inclusions indicates deep buried fluids. Fluid inclusions in vertical calcite vein from basic dyke comprise only low salinity aqueous fluids (0–3 wt.% eq.NaCl) interpreted as dominated by meteoric water. The recorded paleotemperatures are attributed to the heating by the Paraná volcanic event during the Early Cretaceous, with the thermal effect of the volcanic rock cap surpassing the effect of nearby sills and dykes. Estimated paleotemperatures higher than 200 °C would allow the generation of light liquid and gaseous hydrocarbons. Overpressured compartments in the Teresina Formation allowed the expulsion of buried pore fluids (high salinity aqueous fluids and hydrocarbons) to fracture systems, where they mixed with meteoric water. The input of meteoric water through fracture systems connected with the surface favored hydrocarbons degradation in the early stages of source rock maturation during the Early Cretaceous. [ABSTRACT FROM AUTHOR]

The high-angle, structural genetic calcite veins of the Ordovician in Shunnan-Gucheng area in Tarim Basin provide a convenient to study the fluid properties and hydrocarbon migration to accumulation events in fault zone of this area. Based on detailed core investigation, studies of fluid inclusions in calcite veins and comparison of geochemical characteristics of limestone matrix and calcite veins were carried out. Multiple types of hydrocarbons inclusion, including dry asphalt inclusion, three-phase hydrocarbon inclusion, oil and water inclusion, gas-rich inclusion, were found in calcite veins. And the coexisted aqueous inclusions with gas-liquid phase had high homogenization temperature (130-160 °C). The distribution characteristics of 18O-depleted (δ18O: -13.1‰ to - 8.7‰), 87Sr-enriched (87Sr/86Sr: 0.708 879 to 0.710 432), relatively high total Rare Earth Elements and positive Europium Anomalies indicated that the structural origin of calcite veins were mainly derived from the dissolution of surrounding rocks and diagenetic-hydrocarbon fluids. Participation signs of meteoric water were not proved. The rich hydrocarbon inclusions in the calcite veins indicated that the north-east strike-slip fault zone in Shunnan- Gucheng area is an important channel for hydrocarbon migration and accumulation. [ABSTRACT FROM AUTHOR]