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In acoustic cavitation, the relationship between the bubble dynamics on the microscale and the flow properties on the macroscale is critical in determining sonochemical reaction kinetics. A new technique was developed to measure the void fraction and estimate water mobility in the vicinity of cavitating bubbles using phase-encoded magnetic resonance imaging with short characteristic measurement timescales (0.1-1 ms). The exponential behavior of the NMR signal decay indicated the fast diffusion regime, with the relationship between local mechanical dispersion D and the average bubble radius R, $$D_{\rm mix}\gg \frac{2R^2}{10^{-4}\hbox{s}}, $$ resulting in dispersion of orders of magnitude greater than diffusion in quiescent water. For two different samples (water and a surfactant solution), the independent measurements of three-dimensional void fraction and velocity fields permitted the calculation of compressibility, divergence and vorticity of the cavitating medium. The measured dynamics of the dissolved gas, compared with that of the surrounding liquid, reflected the difference in the bubble coalescence and lifetimes and correlated with the macroscopic flow parameters. [ABSTRACT FROM AUTHOR]