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Thanks to good mechanical performances, high availability, low cost and low weight, the agave sisalana fiber allows to obtain biocomposites characterised by high specific properties, potentially very attractive for the replacement of synthetic materials in various industrial fields. Unfortunately, due to the low strength versus transversal damage processes mainly related to the matrix brittleness and/or to the low fiber/matrix adhesion, the tensile performance of random short fiber biocomposites are quite low, and to date most of the fiber treatments proposed in literature to improve the fiber-matrix adhesion, have not led to very satisfactory results. In order to overcome such a drawback, this work in turn proposes the proper introduction of low fractions carbon nanotubes to activate advantageous improvements in matrix toughness as well as fiber-matrix bridging effects, that can both lead to appreciable increments of the tensile strength.Systematic experimental static and fatigue tests performed on high quality biocomposites obtained by an optimized compression molding process, have shown that the introduction of 1% of carbon nanotubes is sufficient to gives significant improvement in both stiffness and static tensile strength, respectively by approximately 28% and 30%. Furthermore, toughening the biocomposite with 1% of nanotubes results in an appreciable enhancement in lifetime of at least 3 orders of magnitude. Biocomposites with 2% of CNTs show instead more limited improvement of 13% in stiffness, 6% in strength and 150% in lifetime. Also, a thorough analysis of the damage processes by SEM micrographs, as well as of the main fatigue data, has allowed to determine the model that can be used to predict the fatigue performance of such biocomposites.

The present work performs a systematic experimental analysis of the translaminar fracture behavior of high performance biocomposites constituted by green epoxy reinforced by sisal fibers, by varying the main influence parameters as fiber concentration and lay-up. Despite the corrective function properly introduced to take into account the anisotropy as well as the use of the equivalent crack length, the study shows that the LEFM does not give accurate estimations of the fracture toughness, because the extension of the near tip damaged zone is higher than the singular dominated one. Accurate estimations can be obtained instead by the proposed modified area method that takes into account both the local damage and the fiber bridging that occurs during crack propagation, that lead to R-curves whose asymptotic values constitute the true fracture toughness of the biocomposites examined. The constancy of the damage mechanisms observed by varying the fiber concentration, allows the user to compute the fracture toughness of a generic laminate from the specific fracture energy of the unidirectional lamina. Finally, the relatively high fracture toughness of the examined laminates allows to state that they can advantageously replace not only other composites having lower toughness, but also metals as steel, aluminum and titanium.

Biocomposites are increasingly used in the industry for the replacement of synthetic materials, thanks to their good mechanical properties, being lightweight, and having low cost. Unfortunately, in several potential fields of structural application their static strength and fatigue life are not high enough. For this reason, several chemical treatments on the fibers have been proposed in literature, although still without fully satisfactory results. To overcome this drawback, in this study we present a procedure based on the addition of a carbonaceous filler to a green epoxy matrix reinforced by Agave sisalana fibers. Among all carbon-based materials, biochar was selected for its environmental friendliness, along with its ability to improve the mechanical properties of polymers. Different percentages of biochar, 1, 2, and 4 wt %, were finely dispersed into the resin using a mixer and a sonicator, then a compression molding process coupled with an optimized thermomechanical cure process was used to produce a short fiber biocomposite with Vf = 35%. Systematic experimental tests have shown that the presence of biochar, in the amount 2 wt %, has significant effects on the matrix and fiber interphase, and leads to an increase of up to three orders of magnitude in the fatigue life, together with an appreciable improvement in static tensile strength.

Due to its good mechanical characteristics, low cost and high availability in the current market, sisal fiber is one of the most used for the manufacturing of biocomposites in various industrial fields (automotive, marine, civil construction etc.). The particular sub-fibrillar structure of the sisal fiber (similar to aramid fibers) and the corresponding anisotropic behavior detected by recent research activities, suggest that such biocomposites should exhibit also high impact strength, in such a way to permit their advantageously use also for the manufacturing of crashworthy components (bumpers, helmets, protection systems etc.), that are at the same time also eco-friendly, lightweight and cheap. Through a low-velocity impact tests campaign, integrated by computer tomography (CT) and carried out on various “green epoxy”/sisal laminates, by varying the main influence parameters such as reinforcement distribution, fiber volume fraction and lay-up, it has been detected that angle-ply laminates exhibits specific impact performances superior to those of biocomposites reinforced by other natural fibers (flax, hemp, jute, etc.), and comparable with those of the best composites specially reported in literature, so that they can be actually used to substitute the synthetic materials for the manufacture of interesting eco-friendly energy absorbing devices, that are also lighter and cheaper.