1. Ultrafast dynamics in acetylene clocked in a femtosecond XUV stopwatch.
- Author
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Y. H. Jiang, Senftleben, A., Kurka, M., Rudenko, A., Foucar, L., Herrwerth, O., Kling, M. F., Lezius, M., Tilborg, J. V., Belkacem, A., K. Ueda, Rolles, D., Treusch, R., Y. Z. Zhang, Y. F. Liu, Schröter, C. D., Ullrich, J., and Moshammer, R.
- Subjects
ACETYLENE ,FEMTOSECOND lasers ,PHOTONS ,SYMMETRY breaking ,ISOMERIZATION ,FREE electron lasers - Abstract
Few-photon induced ultrafast dynamics in acetylene (C
2 H2 ) leading to several dissociation channels--deprotonation (H+ +C2 H+ and H+ +C2 H2+ ), symmetric break-up (CH+ +CH+ ) and isomerization (C+ +CH2 + )--were investigated employing the (XUV; extreme ultra-violet)-pump-(XUV; extreme ultra-violet)-probe scheme at the free-electron laser in Hamburg, combined with multi-hit coincidence detection. The kinetic energy releases and fragment-ion momentum distributions for various decay channels are presented. The C+ +CH2 + and H+ +C2 H2+ channels reveal clear signatures of ultrafast molecular mechanisms, demonstrating potential applications of our pump-probe technique to complex systems in order to study a large variety of ultrafast phenomena in the XUV regime. [ABSTRACT FROM AUTHOR]- Published
- 2013
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