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This study provides scientific evidence for the process of denim biodegradation and the viability of including denim waste in large scale composting facility feedstock streams. Fourteen samples of denim using different dyes and dye processes provided by Cotton Incorporated as well as worn and unworn whole and scrap denim fabric were incorporated into a manure/bedding and food scrap windrow at the Cornell composting facility and in a bench scale laboratory trial. Grab samples of compost were analyzed for compost parameters, metals and PFAS. Visual observation of decomposition of denim showed polyester blended denim degraded at a slower rate than non-blended denim. However, after four months of hot composting, most of the denim had decomposed into organic matter, leaving only small pieces of the polyester thread, labels, and pockets. Bench scale degradation, tracked by carbon dioxide evolution and mass difference showed significant degradation at the macro and microscopic levels at day 75. Composting denim fabric has no detrimental effect on the composting process, nor on the quality of the resulting compost and thus can be used to grow cotton and other crops, reducing the carbon footprint, and contributing to the circular economy. [ABSTRACT FROM AUTHOR]

Chemical production from crude oil represents a substantial percentage of the yearly fossil fuel use worldwide, and this could be partially offset by renewable feedstocks such as woody biomass and energy crops. Past techno-economic and environmental analyses have been conducted for isolated feedstocks on a regional or national scope. This study encompasses complete supply chain logistics analysis, delivered cost financial analysis, national availability, and environmental life cycle assessment (LCA) for 18 selected cellulosic feedstocks from around the world. A biochemical conversion route to monomeric sugars is assumed for estimated sugar yields and biosugar feedstock cost analysis. US corn grain was determined to have the highest delivered cost, while rice hulls in Indonesia resulted in the lowest cost of the feedstocks studied. Monomeric sugar yields from literature ranged from 358 kg BDMT-1 for US forest residues to 700 kg BDMT-1 for corn syrup. Environmental LCA was conducted in SimaPro using ecoinvent v2.2 data and the TRACI 2 impact assessment method for mid-point impacts cradle-to-incoming biorefinery gate. Carbon absorption during biomass growth contributed most substantially to the reduction of net global warming potential. Rice hulls and switchgrass resulted in the highest global warming potential, followed closely by corn and Thai sugarcane bagasse. Contribution analysis shows that chemical inputs such as fertilizer use contribute substantially to the net environmental impacts for these feedstocks. [ABSTRACT FROM AUTHOR]

There has been great attention focused on the effects of first and second generation biofuels on global warming. The Energy Independence and Security Act (EISA) and the Renewable Fuel Standard (RFS) have mandated production levels and performance criteria of biofuels in the United States. The thermochemical conversion of biomass to ethanol shows potential as a biofuel production pathway. The objective of this research was to examine the alcohol yields and GHG emissions from the thermochemical conversion process for six different feedstocks on a gate-to-gate basis. GHG analyses and life cycle assessments were performed for natural hardwood, loblolly pine, eucalyptus, miscanthus, corn stover, and switchgrass feedstocks using a NREL thermochemical model and SimaPro. Alcohol yield and GHG emission for the hybrid poplar baseline feedstock conversion were 105,400 L dry metric ton-1 and 2.8 kg CO2 eq. per liter, respectively. Compared with the baseline, loblolly pine produced the highest alcohol yields, an 8.5% increase, and the lowest GHG emissions per liter of ethanol, a 9.1% decrease. Corn stover, due to its high ash content, had the lowest yields and the highest GHG emissions per liter of ethanol. The results were highly sensitive to the ash and water content of the biomass, indicating that biomass properties can significantly affect the environmental impact of the thermochemical ethanol conversion process. [ABSTRACT FROM AUTHOR]