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The fatigue mechanics and mechanisms of cemented carbides (composites usually referred to as hardmetals) are reviewed. The influence of microstructure on strength lessening and subcritical crack growth for these ceramic-metal materials when subjected to cyclic loads are highlighted. The simultaneous role of the ductile metallic binder as a toughening and fatigue-susceptible agent for hardmetals results in a tradeoff between properties measured under monotonic and cyclic loading: fracture strength and toughness on one hand, as compared to fatigue strength and crack growth resistance on the other one. Toughness/fatigue−microstructure correlations are analyzed and rationalized on the basis of specific crack−microstructure interactions, documented by the effective implementation of advanced characterization techniques. As a result, it is concluded that the fatigue sensitivity of cemented carbides may be reduced if either toughening mechanisms beyond ductile ligament bridging, such as crack deflection, are operative, or strain localization within the binder is suppressed. In this regard, grades exhibiting metallic binders of a complex chemical nature and/or distinct microstructural assemblages are proposed as options for effective microstructural tailoring of these materials.

There is a major interest in replacing cobalt binder in hardmetals (cemented carbides) aiming for materials with similar or even improved properties at a lower price. Nickel is one of the materials most commonly used as a binder alternative to cobalt in these metal-ceramic composites. However, knowledge on mechanical properties and particularly on fatigue behavior of Ni-base cemented carbides is relatively scarce. In this study, the fatigue mechanics and mechanisms of a fine grained WC–Ni grade is assessed. In doing so, fatigue crack growth (FCG) behavior and fatigue limit are determined, and the attained results are compared to corresponding fracture toughness and flexural strength. An analysis of the results within a fatigue mechanics framework permits to validate FCG threshold as the effective fracture toughness under cyclic loading. Experimentally determined data are then used to analyze the fatigue susceptibility of the studied material. It is found that the fatigue sensitivity of the WC–Ni hardmetal investigated is close to that previously reported for Co-base cemented carbides with alike binder mean free path. Additionally, fracture modes under stable and unstable crack growth conditions are inspected. It is evidenced that stable crack growth under cyclic loading within the nickel binder exhibit faceted, crystallographic features. This microscopic failure mode is rationalized on the basis of the comparable sizes of the cyclic plastic zone ahead of the crack tip and the characteristic microstructure length scale where fatigue degradation phenomena take place in hardmetals, i.e. the binder mean free path. [ABSTRACT FROM AUTHOR]

In this study, we prepared WC-CoNiFe and WC-Co with different grain sizes by sintering-hot isostatic pressing (SHIP) and evaluated their fracture behavior. The results showed that WC-CoNiFe has a higher fracture toughness (between 13.16 and 17.82 MPam1/2) than WC-Co (between12.08 and 16.21MPam1/2). Moreover, fracture toughness and fatigue crack growth (FCG) were closely related to the corresponding microstructural characteristics. The fracture toughness increased via ductile ligament bridging and crack deflection as the mean free path of the binder phase (λ Co) increased, or the contiguity of the carbide phase (C WC) decreased. The fatigue fracture mode showed a transition from a cleavage-like brittle fracture to a ductile dimple-like fracture. The fatigue sensitivity of cemented carbides was positively related to the fracture toughness. As the fracture toughness increased, cemented carbides exhibited a transition from ceramic-like material to metal-like material. Considering two important controlling parameters of FCG behavior, the effect of maximum stress intensity factor (K max) on FCG was dominant compared to the stress intensity factor range (∆K). However, the difference in the relative influence of these two parameters diminished as the fracture toughness increased. Moreover, with the rise in K max value, we defined three stages of the FCG process: crack initiation, stable crack growth, and unstable crack growth. The results suggest that CoNiFe medium entropy alloy is a promising material for application as a binder phase of cemented carbides with high toughness. • WC-CoNiFe and WC-Co with different particle sizes (from fine grain to ultra-coarse grain) were prepared by sintering-hot isostatic pressing (SHIP) to evaluate the fracture behavior. • WC-CoNiFe has higher fracture toughness and fatigue sensitivity compared to WC-Co. • As the toughness increases, the material's fatigue sensitivity increases, showing a transition from ceramic to metal-like material. [ABSTRACT FROM AUTHOR]

The fatigue mechanics and mechanisms of cemented carbides (composites usually referred to as hardmetals) are reviewed. The influence of microstructure on strength lessening and subcritical crack growth for these ceramic-metal materials when subjected to cyclic loads are highlighted. The simultaneous role of the ductile metallic binder as a toughening and fatigue-susceptible agent for hardmetals results in a tradeoff between properties measured under monotonic and cyclic loading: fracture strength and toughness on one hand, as compared to fatigue strength and crack growth resistance on the other one. Toughness/fatigue–microstructure correlations are analyzed and rationalized on the basis of specific crack–microstructure interactions, documented by the effective implementation of advanced characterization techniques. As a result, it is concluded that the fatigue sensitivity of cemented carbides may be reduced if either toughening mechanisms beyond ductile ligament bridging, such as crack deflection, are operative, or strain localization within the binder is suppressed. In this regard, grades exhibiting metallic binders of a complex chemical nature and/or distinct microstructural assemblages are proposed as options for effective microstructural tailoring of these materials. [ABSTRACT FROM AUTHOR]