1. A stable mesoporous metal‐organic framework as highly efficient sorbent of dispersive micro solid‐phase extraction for the determination of polycyclic aromatic hydrocarbons by HPLC
- Author
-
Jinmao You, Yanan Dou, Lijie Liu, Lian Xia, Guoliang Li, Lan Guo, and Zhiwei Sun
- Subjects
Materials science ,Sorbent ,010401 analytical chemistry ,Extraction (chemistry) ,Analytical chemistry ,Filtration and Separation ,02 engineering and technology ,Microporous material ,021001 nanoscience & nanotechnology ,01 natural sciences ,High-performance liquid chromatography ,0104 chemical sciences ,Analytical Chemistry ,Adsorption ,Metal-organic framework ,Solid phase extraction ,0210 nano-technology ,Mesoporous material - Abstract
Owing to the large molecular sizes of polycyclic aromatic hydrocarbons, their adsorption using microporous sorbents leads to a low adsorption capacity. Here, to increase the extraction capacity and detection sensitivity of polycyclic aromatic hydrocarbons, a highly efficient dispersive micro solid-phase extraction method was developed based on a stable mesoporous metal-organic framework named Jilin University China 48. Jilin University China 48 is a super hybrid with large one-dimensional hexagonal nanotube-like channels of 24.5 × 27.9 A, which exhibits high potential to be an efficient sorbent of dispersive micro solid-phase extraction to adsorb polycyclic aromatic hydrocarbons. By combining with high-performance liquid chromatography, a sensitive method was developed for the determination of seven polycyclic aromatic hydrocarbons. The synthesized Jilin University China 48 exhibited excellent characteristics of stability, good morphology, large surface area, and open adsorption sites. Under the optimized extraction conditions, better extraction results were obtained than that of other methods reported previously. The proposed method exhibited high sensitivity with the limit of detections in the range of 0.021-0.13 ng/mL, good linearity in the range of 0.068-50 ng/mL with related coefficients of >0.9988, satisfactory precision with relative standard deviation of
- Published
- 2018