1. Nitroglycerin stabilisation in a polyester matrix synthesized by the polymerization of an epoxidized vegetable oil.
- Author
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Schwartz, Cédric, Comet, Marc, Lemiègre, Loïc, Audic, Jean‐Luc, Lallemand, Bastien, Bonnet, Benjamin, Schnell, Fabien, Ott, Anna K., and Spitzer, Denis
- Subjects
VEGETABLE oils ,NITROGLYCERIN ,GLUTARIC acid ,POLYMERIZATION ,IGNITION temperature ,ACTIVATION energy ,EXPLOSIVES ,POLYESTERS ,POLYMERS - Abstract
Nitroglycerin (NG) is a high explosive that is difficult to handle in its liquid form, where the entrapment of gaseous NG bubbles results in its high sensitivity to impact (<0.25 J). NG‐based materials are traditionally prepared by complex mixing processes where desensitisation is of major concern. Instead of using a mixing procedure here we demonstrate the successful synthesis of dynamite‐like materials by using a single step bottom‐up approach to form a polymeric host matrix (PM) for NG from a solution which contains the explosive and the matrix precursors. For this purpose, an epoxidized vegetable oil mixed with nitroglycerin (oil to NG mass ratio of 60/40) is polymerized at 100 °C for 30 h by using glutaric acid as crosslinking agent. No degradation of NG under these conditions is observed. The activation energy of NG desorption from the PM (51.9 kJ/mol) is of the same order of magnitude as the one reported in literature for a double‐base powder (81.9 kJ/mol). An accelerated NG desorption is observed as temperature increases. This can be attributed to a slow diffusion mechanism of the explosive from the volume to the surface of the material, where it evaporates. The ignition of NG/PM in air by an open flame leads to a self‐sustained combustion, in which a part of nitroglycerin decomposes in the polymer matrix. Conversely, NG/PM monolithic and granular loads are not ignited by the explosion of the primer in a 9 mm calibre casing. The shockwave released by a detonator on a small NG/PM cylindrical charge (≈1.5 g) does not detonate it, but only makes it deflagrate. Our results show that this novel single‐step synthesis of NG trapped in a polymeric matrix is a very effective approach for desensitizing it to any form of stress. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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