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Liquid crystal variable retarders (LCVRs) will be used for the first time in a space instrument, the Solar Orbiter mission of the European Space Agency, as polarization states analyzers (PSAs). These devices will determine the Stokes parameters of the light coming from the Sun by temporal polarization modulation, using the so-called modulation matrix O. This is a matrix constituted by the first rows of properly selected PSA Mueller matrices. Calibrating a space instrument, in particular, finding O, is a critical point because in a spacecraft there is no possibility of physical access. Due to the huge difficulty in calibrating the complete instruments in all possible scenarios, a more complete calibration of the individual components has been done in ground in order to make extrapolations to obtain O in-flight. Nevertheless, apart from the individual calibrations, the experimental errors and nonideal effects that inhibit the system to reach the designed and theoretical values must be known. In this work, description and study of these effects have been done, focusing on the nonideal effects of the LCVRs and the azimuthal misalignments between the optical components of the PSA during the mechanical assembly. The Mueller matrix of a representative LCVR has been measured and mathematically decomposed by logarithm decomposition, looking for values of circular birefringence and fast axis angle variations as a function of voltage. These effects, in the absence of other nonidealities, affect the polarimetric performance, reducing the polarimetric efficiencies in some cases until 11%. Nevertheless, in this case, they are negligible if compared to the other nonideality studied, which are the azimuthal misalignments between the PSA optical components. The study presented in this work is key to extrapolate the PSA O matrix if the expected instrumental set-point temperatures are not reached in flight and can be used for the design and implementation of other polarimetric instruments. [ABSTRACT FROM AUTHOR]

Liquid crystal variable retarders (LCVRs) have been extensively used as light polarization modulators for ground-based polarimetric applications. Shortly, LCVRs will be used as polarization state analyzers in two instruments onboard the Solar Orbiter mission of the European Space Agency. Both ground- and space-based polarimeters require LCVR response time values that fulfill the required image acquisition rate of the polarimetric measurements. Therefore, it is necessary to have a reliable method to measure the LCVR optical retardance response times. Response times are usually estimated via optical methods using crossed or parallel polarizers. Nevertheless, these methods measure light intensity transitions to infer the response time instead of directly measuring the changes in the optical retardance. In this work, an experimental setup that uses a Soleil-Babinet variable compensator is proposed. On one hand, this allows one to study the effect of the nonlinear dependence of the light intensity on the optical retardance in the response time determination, which is neglected in most works. On the other hand, the use of the variable compensator allows one to measure the LCVR response times in the highest sensitivity areas of the system that minimizes the uncertainty of the measurement. The six transitions for the Polarimetric and Helioseismic Imager instrument modulation scheme of a representative LCVR have been measured. Based on the results, the optimized conditions to measure response times are found, which can be achieved by using the variable compensator and an IR wavelength (λ = 987.7 nm) as proposed in the experimental setup. [ABSTRACT FROM AUTHOR]