1. High‐Performance 3D Pinecone‐Like LiNi1/3Co1/3Mn1/3O2 Cathode for Lithium‐Ion Batteries.
- Author
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Shao, Yijia, Huang, Bin, Lu, Zhiyuan, Liu, Yanchen, Meng, Xiangbo, Du, Li, Song, Huiyu, and Liao, Shijun
- Subjects
LITHIUM-ion batteries ,CATHODES ,ION migration & velocity ,ETHYLENE glycol ,LITHIUM ions - Abstract
A high‐performance LiNi1/3Co1/3Mn1/3O2 cathode with a uniform pinecone‐like morphology is reported, which is prepared by a solvothermal process, using urea to tune the pH of a mixed solvent of ethylene glycol and water, and a subsequent calcination process. The material has uniform, well‐defined pinecone‐like particles with lengths of 3–4 μm and widths of 1–2 μm. It exhibits a significantly enhanced cathodic performance in a Li‐ion battery, with a reversible discharging capacity of up to 199 mAh g−1 when it is charged to 4.6 V at a charge/discharge rate of 0.2 C and of 159.2 mAh g−1 at a rate of 2 C. After 100 charge/discharge cycles, the capacity retention is 91%, demonstrating its superior capacity and stability in comparison with a sample prepared via the coprecipitation method. The cyclic voltammetry and electrochemical impendence spectroscopy results reveal that the pinecone‐like LiNi1/3Co1/3Mn1/3O2 material has markedly lower polarization and lower resistance to the migration of lithium ions than the coprecipitation sample. The material's high performance, especially its outstanding capacity at a high discharge rate and its significantly enhanced cyclability, makes the synthesized pinecone‐like LiNi1/3Co1/3Mn1/3O2 a promising high‐performance cathode material for lithium‐ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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