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Many paper-related products are in daily use all over the world. Although paper is one of the most recycled materials in the European Union, no end-of-waste criteria have been defi ned. Typical paper and cardboard should be recycled, but paper materials with impurities, such as cooking oil, sand, or plastic, are much more problematic. In particular, paper contaminated with cooking oil or butter (e.g., pizza boxes) is diffi cult waste. Also baking parchment paper cannot be stored as waste paper after use. Composting could be a solution, but in many municipal solid waste collection systems, this waste types are collected with the mixed waste stream, what fi nally leads this material to landfi lling or incinerating processes. Parchment paper and pizza box cardboard contain a lot of cellulose and in landfi lls are a source of CO2 and CH4. Incineration of these materials also leads to CO2 emission. The aim of this study was to investigate the degradation of cooking-oil-contaminated paper in media with a low inorganic nitrogen content. Cardboard usually used for packaging purposes was used as pre-test material. Two types of paper usually used in the kitchen were used: pizza box cardboard and parchment paper highly contaminated with cooking oil. Two types of low inorganic nitrogen media were tested: mature municipal waste compost (MSWC) and leaf mold (LM). The decrease of mass of both paper sample types was correlated with process time. Both tested sample types: dry cellulose materials and paper with cooking oil added, were partly or completely decomposed after 6 weeks of bioprocessing in aerobic conditions without an additional dose of inorganic nitrogen. According to waste separation rules, wet paper or paper contaminated with cooking oil have to be stored with other wastes which are „not possible for further use”. This work show possibility to change these rules.

Rationale: Rapid on‐site detection of persistent organic pollutants (POP) is highly desirable for environmental protection. Methods: Herein, a rapid on‐site analytical workflow was developed for the investigation of polycyclic aromatic hydrocarbons and perfluorinated compounds using multiwalled carbon nanotube–modified paper spray ionization (PSI) coupled with a miniature ion trap mass spectrometer. Critical parameters regarding PSI and miniature mass spectrometry analysis were optimized. Results: The analytical performance of the developed method was evaluated under optimized conditions, obtaining a short analysis duration of less than 1 min, sufficient linearity with correlation coefficients greater than 0.99, acceptable recovery rates of 93.1%–105.8% with relative standard deviations of between 3.5% and 10.3%, and reasonable sensitivity with limits of detection and quantitation of 2–200 and 5–500 μg/L, respectively. Conclusions: Considering these aspects, it was concluded that the present approach demonstrated a promising solution for rapid on‐site detection of emerging POPs. [ABSTRACT FROM AUTHOR]

The utilization of agriculture waste-based adsorbents in the treatment of real industrial wastewater represents an unexplored frontier with significant potential. In this study, the cobalt ferrite-supported activated carbon derived from orange peels (CF40-AC) was used as a magnetic adsorbent for the treatment of real pulp and paper mill effluent (PPME). Detailed insights into the properties and functionalities of the CoFe2O4-AC adsorbent were obtained through an accurate characterization analysis that included X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), BET and pore size histogram techniques. Both pure activated carbon (AC) and CF40-AC displayed excellent textural properties with surface area (SBET) equal 2014 and 1345 m².g-1, respectively. TEM and SEM images display that the magnetic ferrites were well dispersed on the surface of AC. Following the characterization process, the CoFe2O4-AC adsorbent was evaluated for its ability to remove several key pollutants from PPME, including chemical oxygen demand (COD), total dissolved solids (TDS) and turbidity. Moreover, various operational parameters, such as pH, adsorbent dosage, contact time, and stirring rate, were investigated to achieve optimal contaminants removal rates. Remarkably, the CoFe2O4-AC adsorbent demonstrated highly efficient removal rates, with 86.9%, 59,9% and 93.1% for COD, TDS and turbidity, respectively, under optimal conditions (pH 7, adsorbent dose 0.4 gm, contact time 60 min, and stirring rate 150 rpm). The CoFe2O4-AC composite material exhibits promising potential for multiple applications reached 5 cycles without a significant loss in its adsorption or functional properties over successive uses. These results favor the promising potential of CoFe2O4-AC as a sustainable and efficient solution for addressing was- tewater treatment challenges in the pulp and paper industry, contributing to both environmental protection and resource conservation. [ABSTRACT FROM AUTHOR]

Paper, which is in fact a very complex cellulose-based product derived from different lignocellulosic resources, is usually regarded as a simple omnipresent commodity in our lives. Wood fibers derived from trees are the most employed sources for papermaking purposes. From an environmental protection perspective, and for their essential role in our life (they give us the life itself through their foliar system supporting the photosynthesis process), trees should not be extensively cut down and they should be used less and less for papermaking. Thus, employment of non-woody alternative sources for papermaking could be exploited more as an attractive and feasible option. [ABSTRACT FROM AUTHOR]

Having the South American Amazon as our spatial cut, this paper aims to discuss it as a space of physical, environmental and socioeconomic relevance to regional rearticulation, highlighting the issue of transport infrastructure and the importance of Brazil to boost this process in contemporary times. With the end of the Union of South American Nations (Unasur) in 2019, several of its councils were paralyzed and discontinued, such as the Infrastructure and Planning Council (Cosiplan), reflecting the abandonment of efforts built since the beginning of the 21st century. In addition, relations between national preferences and the indispensable search for development, and mechanisms of cooperation and regional integration, which are fundamental instruments to meet such demands, were stressed. In turn, a scenario of discredited institutions made room for greater action by multiple public and private, internal and increasingly international and multinational actors who, in a way disconnected from regional arrangements, directed infrastructure investments focusing on their own interests, resulting in expiation of the the socio-environmental vulnerability in the Amazonian territories. We argue that it is necessary to integrate to preserve and develop. Regional governance and institutionality are central pillars for the resumption of a more resilient South American integration process, aimed at protecting and developing the Amazon, in which Brazil has an important driving role to be exercised and a directive leadership to retrieve.

The profile of microbial diversity in a NABR digesting RPMW was investigated using phylogeneticanalysis of partial 16S rRNA sequences by a neighbor-joining-tree, supported by microbial morphology analysis by SEM. The results showed that microorganism inside NABR consisted of dominant Bacillus (25 strains) and Bacterium (1 strain) which were isolated from the settled sludge at the bottom of the reactor, whilst Bacillus (2 strains), Pseudomonas (2 strain) and Chryseobacterium (2 strain) were isolated from the biofilm formed on the packing material. It revealed that the microbial community strains, function, and structure changed simultaneously throughout the reactor system. The microscopic results showed rich biofacies, while the dominant microorganisms have various morphologies in every compartment of the system. It consisted of a long rod-shaped and filamentous bacterium composed majorly of bacilli of different sizes. Although the study successfully analyzed the microbial diversity and morphology in the system, the microbial communities reported in this study were different from other similar studies. This may be caused by the application of a culture-based technique that usually provides limited information due to the number of barely cultivated or uncultured strains

Surface characteristics of printing substrates are of the utmost importance to all types of paper that interact with ink. During all types of printing processes, the behaviour of the liquid phase (ink or dye) on the paper is directly defined by the paper cellulose-based surface. The printed ink spreads and penetrates more into paper fibres when the paper surface is rougher and more permeable. Contact angle measurements by sessile drop method are considered the most appropriate for determining the paper sheet surface energy. Paper as hydrophilic material has a high absorption rate resulting in a low contact angle. The objective of this study was to evaluate the surface free energy of laboratory-made papers containing straw pulp obtained from residues after the harvest of the most cultivated cereals in Croatia (wheat, barley and triticale). The obtained surface free energy results are promising for straw pulp usage in the manufacture of printing paper.

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This paper reports an innovative study that aims to address key issues in the efficient recycling of wastepaper cellulose. The research team utilized the temperature-responsive upper critical solution temperature (UCST) polymer P(NAGA-b-DMA) in combination with the LytA label's affinity for choline analogs. This innovative approach enabled them to successfully develop a novel soluble immobilized enzyme, P(NAGA-b-DMA)-cellulase. This new enzyme has proven highly effective, significantly enhancing the degradation of wastepaper cellulose while demonstrating exceptional stability. Compared with the traditional insoluble immobilized cellulase, the enzyme showed a significant improvement in the pH, temperature stability, recycling ability, and storage stability. A kinetic parameter calculation showed that the enzymatic effectiveness of the soluble immobilized enzyme was much better than that of the traditional insoluble immobilized cellulase. After the immobilization reaction, the Michaelis constant of the immobilized enzyme was only increased by 11.5%. In the actual wastepaper degradation experiment, the immobilized enzyme was effectively used, and it was found that the degradation efficiency of wastepaper cellulose reached 80% of that observed in laboratory conditions. This novel, thermosensitive soluble immobilized cellulase can efficiently catalyze the conversion of wastepaper cellulose into glucose under suitable conditions, so as to further ferment into environmentally friendly biofuel ethanol, which provides a solution to solve the shortage of raw materials and environmental protection problems in the paper products industry. [ABSTRACT FROM AUTHOR]

This paper describes the role of the bioeconomy concept started in the Cologne paper and initiated by Christian Patermann for bioeconomy strategies in Germany and around the world. Patermann is and has been an important actor and a highly appreciated colleague in the first German Bioeconomy Council and the International Advisory Council on Global Bioeconomy (IACGB). IACGB is a think tank with the mission to promote the Global Bioeconomy as a sustainable and future looking movement for the benefit of planet and people. The Global Bioeconomy Summits (GBS) series initiated in 2015 by the German Bioeconomy Council and perpetuated by the IACGB has become a truly global meeting and conference event that gathers bioeconomy experts and high level politicians from all areas and hemispheres. The IACGB provides leadership for setting the themes of GBS. Communiques and reports on national strategies are signature outcomes.

The study attempted to assess the water quality around paper mill effluents discharge areas. Several physicochemical parameters and the Canadian Council of Ministers of the Environment (CCME) Water Quality Index (WQI) were considered to determine the pollution level of surface and groundwater in the selected paper mills areas located in Saidpur, Gobindaganj, and Dupchanchia Upazilas of Bangladesh. Physicochemical characterization of the surface water around the paper mills areas showed that the concentration of EC, TSS, BOD5, COD, phenols, NO3−-N, and K+ were exceeded the surface water standard, whereas the DO level ranged from 1.63 to 3.5 were found below the Environmental Conservation Rules (ECR), 1997 standard. Besides, the BOD, COD, and Mn ion concentrations of groundwater exceeded the drinking water standard. In most sampling sites, the WQI of the surface water showed ‘marginal’ category, and the groundwater quality showed 'fair' category. The study observed that the toxic effluents discharged from the paper mills caused harm to the aquatic ecosystem. [ABSTRACT FROM AUTHOR]

Waste management is the protection of the environment and the health of the population. Paper waste sludge is produced during paper production and sepiolite is a natural clay mineral. The aim of the study was to investigate the usability of sepiolite-added paper waste sludge as a bedding material in the broiler production. Two hundred eighty-eight 1-day old male broiler chicks were divided into the 6 bedding material groups (wood shavings (control), paper waste sludge, sepiolite, mix of 25% paper waste sludge and 75% sepiolite, mix of 50% paper waste sludge and 50% sepiolite, and mix of 75% paper waste sludge and 25% sepiolite) with 6 replicate pens per group. Litter quality, performance, and some welfare parameters of broilers were assessed during the 6 weeks' period. Body weight at 42 days of age and body weight gain from 0 to 42 days of broilers reared on the wood shavings and mix of 50% paper waste sludge and 50% sepiolite were found higher than those of the sepiolite and paper waste sludge groups. Feed consumption and feed to gain ratio from 0 to 42 days, yields of carcass and carcass parts, percentages of organs and abdominal fat, IgG, percentage of bursa Fabricius, burns of foot pad and breast, litter pH and meat properties of broilers reared on the wood shavings, paper waste sludge, and sepiolite litter groups were not found to be statistically different. Litter moisture was found higher in the paper waste sludge group than that in the sepiolite group at the 42 days of rearing. As a conclusion, usage of mix of 50% paper waste sludge and 50% sepiolite as a litter does not have any negative effects on performance, welfare, and litter quality. This result is important in terms of utilizing a waste product. [ABSTRACT FROM AUTHOR]

Once printed, books are always accompanied by the smells of volatile organic compounds (VOCs) which are continuously emitted not only by inks but also by papers themselves throughout their lives. Although the VOCs from papers may bring mild discomfort to readers, they are considered as very important factors that feature the degradation of papers and show potential applications in cultural relic appraisal. In this study, an analytical approach based on solid phase microextraction combined with gas chromatography-mass spectrometry (SPME-GC/MS) was proposed for the evaluation of volatile organic compounds (VOCs) emitted by Chinese traditional handmade papers. The VOCs evaluations and artificial aging processes were both applied to recent-made papers and naturally aged papers from a traditional Chinese calligraphy and painting scroll (collected by the National Museum of China). To be noticed, a large number of aliphatic acids, aldehydes, ketones, furan derivatives, benzene series and terpenoid substances indicated that the VOCs signals not only reveal the degradation of paper but also tentatively reflect the storage environment along hundreds of years ago. The semi-quantitative evaluation of markers indicated that the historical paper is under a serious degradation due to the high capacity it releases. Our results provided a path way to get the degradation information of ancient paintings as well as potential realistic applications such as the conservation of paper-based relics and the environmental protection in libraries and museums. [ABSTRACT FROM AUTHOR]

As acetonitrile is a widely used solvent for the chemical industry, the recovery of acetonitrile from acetonitrile wastewater is significant for both industrial cost reduction and environmental protection. In this article, a simple, low‐energy, and low‐cost strategy is proposed for the effective separation of acetonitrile from high‐concentration acetonitrile wastewater. The approach is based on a sequential combination of two steps: salt‐induced phase separation and hydrophobic filtration. The acetonitrile wastewater was first induced to split into two phases by salt, that is, the acetonitrile‐rich phase and the water‐rich phase, then the above two phases were poured into the hydrophobic filter paper funnel for the separation. It was shown that NaCl is a suitable salting‐out reagent, and that hydrophobic filter papers—obtained from modification by butyltrichlorosilane and octyltrichlorosilane were the optimal choice for hydrophobic filtration. The salt‐induced phase separation process is able to increase the volume fraction of acetonitrile in the acetonitrile‐rich phase up to 92%. The acetonitrile‐rich phase can pass through the hydrophobic filter paper, whereas the water‐rich phase was intercepted. The hydrophobic filter paper retained strong hydrophobicity and high acetonitrile‐separating capacity after 3 months storage, or upon immersion in acetonitrile‐water mixtures for 12 h, or applied for 25 consecutive separations. [ABSTRACT FROM AUTHOR]

This article presents the development of a method to prepare nanocrystalline cellulose (NCCs) from laser-printed waste paper using factorial design 2³ experiments by controlled acid hydrolysis of the waste paper. The method applies high gain ultrasound and subsequent flotation, washing, and bleaching stages. Characterization of the raw material, prepared pulp, test sheets, and NCCs is presented. Optimum conditions to obtain high quality NCCs were found to be 65% acid, for 40 min time of treatment, and residual load in the range of 130 to 570 mmol/kg of NCCs. The obtained NCCs were 80 to 700 nm long depending on the acid hydrolysis conditions. They exhibited high values of whiteness (90.3% Elrepho), α-cellulose contents (95%), degree of polymerization (731), viscosity (9.59 cP), and chemical compositions similar to that of Whatman paper. [ABSTRACT FROM AUTHOR]

Fluoroquinolones (FQs) are widely used for their excellent antimicrobial properties, yet their release into aquatic environments pose risks to ecosystems and public health. The accurate monitoring and analysis of FQs present challenges due to their low concentrations and the complex matrices found in actual environmental samples. To address the need for auto-pretreatment and on-line instrumental analysis, developing new microextraction materials and protocols is crucial. Such advancements will provide better analytical assurance for the effective extraction and determination of FQs at trace levels, which is of great significance to environmental protection and human health. In this work, we presented a Co2+ mediated paper-based molecularly imprinted polymer chip (CMC@Co-MIP), combined with UPLC analysis, to develop an effective analytical method for identifying and quantifying trace amounts of ciprofloxacin (CIP) and enrofloxacin (ENR) in water samples. Notably, the addition of Co2+ in CMC@Co-MIP helped to capture the template molecule CIP through coordination before imprinting, which significantly improved the ordering of the imprinted cavities. CMC@Co-MIP exhibited a maximum adsorption capacity up to 500.20 mg g−1 with an imprinting factor of 4.12, surpassing previous reports by a significant margin. Furthermore, the enrichment mechanism was extensively analyzed by various characterization techniques. The developed method showed excellent repeatability and reproducibility (RSD < 13.0 %) with detection limits ranging from 0.15 to 0.21 μg L−1 and recoveries ranging from 64.9 % to 102.3 % in real spiked water samples. We developed a novel microextraction paper-based chip based on Co2+ mediation, which effectively improved the selectivity and convenience of extracting FQs. This breakthrough allowed the chip to have a high enrichment efficiency as well as provide a robust on-line instrumental program. It also confirms that the imprinting scheme based on metal ion coordination is a high-performance strategy. [Display omitted] • A novel paper-based molecularly imprinted polymer chip (CMC@Co-MIP) was synthesized. • The imprinting protocol based on metal coordination was a high-performance strategy. • The chip showed excellent adsorption of fluoroquinolones, reaching 500.20 mg g−1. • The chip exhibited potentiality for environmental water samples pretreatment. [ABSTRACT FROM AUTHOR]

Honey peach (Prunus persica) is easy to rot after picking because of its special property, and the damage of traditional preservation method to the ecological environment is unacceptable. Therefore, chitosan as a kind of environmental protection material with excellent performance has attracted people's attention. Though chitosan has good practicability, its application in practical production is limited due to its poor water solubility. In this study, we prepared phenolic acid- g -chitosan using two synthesis methods of carbodiimide-mediated coupling reaction and free radical-mediated grafting procedure. After comparing the grafting rates of these conjugates, the results showed that using the synthetic method of carbodiimide-mediated coupling reaction through NHS and EDC as the coupling agent to graft phenolic acid onto chitosan had a good grafting ratio at a molar ratio of 1.5:1. Therefore, six phenolic acids were used for the first time to prepare conjugates through this method, and these conjugates were characterized by UV and NMR. It can significantly improve the water solubility and DPPH scavenging activity of chitosan, thus releasing its good properties and meeting the application of post-harvest preservation of honey peaches. The results indicate the antisepsis and fresh-keeping effects of six conjugates showed that preservative paper containing 2-Hydroxyphenylacetic acid- g -CS has the best effect of inhibited decay index and weight loss when peach fruits were stored at 20 ± 5 °C under 40%–60% humidity for 8 days. Thus, the water-soluble conjugate prepared by grafting phenolic acid onto chitosan can enhance the market application range of chitosan. [ABSTRACT FROM AUTHOR]

We document the "good-on-paper effect," whereby people make more virtuous decisions on paper than on a digital device (e.g., tablet). In a series of 10 studies, we find that people are more likely to make virtuous decisions on paper than on a digital device because they perceive choices on paper as more real (i.e., tangible, actual, and belonging to the physical rather than the virtual world) and hence as more self-diagnostic (i.e., representative of who they are). We first show people express more interest in donating and volunteering (Studies 1a and 1b), are more likely to donate (Study 2), and put more effort into helping a charitable cause (Study 3) when these choices occur on paper (versus tablet)—a pattern of decision making we label the good-on-paper effect. Study 4 extends these findings to book choices (highbrow versus lowbrow) and to a device interaction that closely mimics writing on paper (i.e., tablet with digital pen). In the context of volunteering decisions, we then provide evidence for the sequential mediating roles of perceptions of realness and self-diagnosticity in the good-on-paper effect (Study 5 and Studies 6a and 6b). Finally, we show that chronic (Study 7) and situational (Study 8) perceptions of self-diagnosticity moderate this effect in the contexts of environmental protection and food choices (healthy versus indulgent), respectively. We discuss the theoretical and practical implications of these findings. [ABSTRACT FROM AUTHOR]